The self-assembly of colloidal building blocks into complex and hierarchical structures offers a versatile and powerful toolbox for the creation of new photonic and optoelectronic materials. However, well-defined and monodisperse colloids of semiconducting polymers, which would form excellent building blocks for such self-assembled materials, are not readily available. Here we report the first demonstration of a Suzuki-Miyaura dispersion polymerization; this method produces highly monodisperse submicrometer particles of a variety of semiconducting polymers. Moreover, we show that these monodisperse particles readily self-assemble into photonic crystals that exhibit a pronounced photonic stopgap.
Nature communications. 2012:3:1088. doi: 10.1038/ncomms2085 Q115.72025
Monodisperse conjugated polymer particles by Suzuki-Miyaura dispersion polymerization
分散聚合制备单分散共轭聚合物粒子 翻译改进
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DOI: 10.1038/ncomms2085 PMID: 23011142
摘要 Ai翻译
关键词：共轭聚合粒子; 铃木-MIYAURA聚合反应; 单分散性
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