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Inorganic chemistry. 2011 Dec 5;50(23):11862-4. doi: 10.1021/ic202013m Q14.72025

Chiral induction via the disassembly of diruthenium(II,III) tetraacetate by chiral diphosphines

手性二磷配体拆分双钌(Ⅱ, Ⅲ)四乙酸配合物实现手性诱导 翻译改进

Ramesh Vadavi  1, Eamonn D Conrad, D Ian Arbuckle, T Stanley Cameron, Ernest Essoun, Manuel A S Aquino

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  • 1 Department of Chemistry, St. Francis Xavier University, P.O. Box 5000, Antigonish, Nova Scotia B2G 2W5, Canada.
  • DOI: 10.1021/ic202013m PMID: 22034861

    摘要 Ai翻译

    [Ru(2)(μ-O(2)CCH(3))(4)(MeOH)(2)](PF(6)) reacts with chiral diphosphines (R,R)- and (S,S)-chiraphos, leading to disassembly and production of the enantiomers Λ-[Ru(η(2)-O(2)CCH(3))(η(2)-(R,R)-chiraphos)(2)](PF(6)) and Δ-[Ru(η(2)-O(2)CCH(3))(η(2)-(S,S)-chiraphos)(2)](PF(6)) in high yield and purity. X-ray crystallography and solid-state circular dichroism (CD) show that only the indicated isomers are present in the solid state. Solution CD measuremen... ...点击完成人机验证后继续浏览
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    期刊名:Inorganic chemistry

    缩写:INORG CHEM

    ISSN:0020-1669

    e-ISSN:1520-510X

    IF/分区:4.7/Q1

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    Chiral induction via the disassembly of diruthenium(II,III) tetraacetate by chiral diphosphines