Reaction of 4-vinylpyridine with AgClO(3) yields a crystalline solid that supports a stereospecific and quantitative [2+2] photodimerisation of two terminal olefins. Structural dynamics of the -CH[double bond, length as m-dash]CH(2) group, nature of the counterion, and extended packing influence the photoreactivity.
Chemical communications (Cambridge, England). 2010 Jul 21;46(27):4956-8. doi: 10.1039/c0cc01184c Q24.22025
Stereospecific and quantitative photodimerisation of terminal olefins in the solid state
固态末端烯烃的立体专一性及定量光二聚反应 翻译改进
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DOI: 10.1039/c0cc01184c PMID: 20517572
摘要 Ai翻译
Keywords：terminal olefins; photodimerization; solid state
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