Vibrationally excited molecule-metal surface reactions in heterogeneous and plasma catalysis: going beyond the Fridman-Macheret α model [0.03%]
异质和等离子体催化中振动激发分子-金属表面反应：超越弗里德曼-马切雷特α模型
Nick Gerrits,Annemie Bogaerts
Nick Gerrits
Vibrational excitation of reactants plays an important role in heterogeneous and plasma catalysis by increasing the reactivity of various rate-controlling steps. Therefore, state-of-the-art microkinetic models attempt to include this effect...
Joran Van Turnhout,Kevin Rouwenhorst,Leon Lefferts et al.
Joran Van Turnhout et al.
Plasma catalysis is gaining increasing interest for the synthesis of chemicals and fuels, but the underlying mechanisms are still far from understood. This hampers plasma-catalyst synergy. Indeed, there is not enough insight into the optima...
Two-step tandem electrochemical conversion of oxalic acid and nitrate to glycine [0.03%]
以草酸和硝酸为原料电化学两步法合成甘氨酸
Yuan-Zi Xu,Daniel F Abbott,Lok Nga Poon et al.
Yuan-Zi Xu et al.
This study presents a facile tandem strategy for improving the efficiency of glycine electrosynthesis from oxalic acid and nitrate. In this tandem electrocatalytic process, oxalic acid is first reduced to glyoxylic acid, while nitrate is re...
The dark side of metal exsolution: a combined in situ surface spectroscopic and electrochemical study on perovskite-type cathodes for high-temperature CO2 electrolysis [0.03%]
金属析相的阴暗面：高温CO2电解中钙钛矿型阴极的原位表面光谱和电化学研究
Christian Melcher,Andreas Nenning,Florian Schrenk et al.
Christian Melcher et al.
In solid oxide CO2 electrolysis cells, moderate activity and coking of the cathode are major issues that hinder commercialization of this important technology. It has been already shown that cathodes based on a mixed conducting oxide decora...
The role of Fe incorporation into Ni-MOF-74 derived oxygen evolution electrocatalysts for anion exchange membrane water electrolysis [0.03%]
Fe掺杂Ni-MOF-74衍生的阴离子交换膜水电解氧析出反应电催化剂的作用
Julia Linke,Thomas Rohrbach,Adam Hugh Clark et al.
Julia Linke et al.
The performance of Ni-based oxygen evolution reaction (OER) electrocatalysts is enhanced upon Fe incorporation into the structure during the synthesis process or electrochemical Fe uptake from the electrolyte. In light of the promising pote...
Selective catalytic hydrogenation of C2H2 from plasma-driven CH4 coupling without extra heat: mechanistic insights from micro-kinetic modelling and reactor performance [0.03%]
等离子体驱动的甲烷偶联选择性催化加氢制乙炔：基于微动力学模型和反应器性能的新见解
Eduardo Morais,Fabio Cameli,Georgios D Stefanidis et al.
Eduardo Morais et al.
We study the selective catalytic hydrogenation of C2H2, the main product from non-oxidative CH4 coupling in gas-phase plasmas, to C2H4, a cornerstone of the global chemical industry, by experiments and temperature-dependent micro-kinetic mo...
Jan-Willem Hurkmans,Henri M Pelzer,Tom Burdyny et al.
Jan-Willem Hurkmans et al.
Electrochemical CO2 reduction offers a promising method of converting renewable electrical energy into valuable hydrocarbon compounds vital to hard-to-abate sectors. Significant progress has been made on the lab scale, but scale-up demonstr...
Correction: High photocatalytic yield in the non-oxidative coupling of methane using a Pd-TiO2 nanomembrane gas flow-through reactor [0.03%]
关于甲烷非氧化偶联反应中钯掺杂二氧化钛纳米膜气体流动床反应器高光催化产量的更正通知
Victor Longo,Luana De Pasquale,Francesco Tavella et al.
Victor Longo et al.
[This corrects the article DOI: 10.1039/D4EY00112E.]. This journal is © The Royal Society of Chemistry.
Published Erratum
EES catalysis. 2024 Oct 15;2(6):1320. DOI:10.1039/d4ey90022g 2024
Active and highly durable supported catalysts for proton exchange membrane electrolysers [0.03%]
用于质子交换膜电解器的活性和高耐久性担载型催化剂
Debora Belami,Matthew Lindley,Umesh S Jonnalagadda et al.
Debora Belami et al.
The design and development of supported catalysts for the oxygen evolution reaction (OER) is a promising pathway to reducing iridium loading in proton exchange membrane water electrolysers. However, supported catalysts often suffer from poo...
Designing bifunctional perovskite catalysts for the oxygen reduction and evolution reactions [0.03%]
用于氧还原和析出反应的双功能钙钛矿催化剂的设计
Casey E Beall,Emiliana Fabbri,Adam H Clark et al.
Casey E Beall et al.
The development of unified regenerative fuel cells (URFCs) necessitates an active and stable bifunctional oxygen electrocatalyst. The unique challenge of possessing high activity for both the oxygen reduction (ORR) and oxygen evolution (OER...