Davy Sinnaeve,Abir Ben Bouzayene,Emile Ottoy et al.
Davy Sinnaeve et al.
Proline homopolymer motifs are found in many proteins; their peculiar conformational and dynamic properties are often directly involved in those proteins' functions. However, the dynamics of proline homopolymers is hard to study by NMR due ...
Efficient polynomial analysis of magic-angle spinning sidebands and application to order parameter determination in anisotropic samples [0.03%]
高效分析魔术角旋转旁带的多项式以及在各向异性样品中确定序参数中的应用
Günter Hempel,Paul Sotta,Didier R Long et al.
Günter Hempel et al.
Chemical shift tensors in 13C solid-state NMR provide valuable localized information on the chemical bonding environment in organic matter, and deviations from isotropic static-limit powder line shapes sensitively encode dynamic-averaging o...
Florin Teleanu,Paul R Vasos
Florin Teleanu
Long-lived spin order-based approaches for magnetic resonance rely on the transition between two magnetic environments of different symmetries, one governed by the magnetic field of the spectrometer and the other where this strong magnetic ...
A novel multinuclear solid-state NMR approach for the characterization of kidney stones [0.03%]
一种用于肾结石表征的新型多核固态NMR方法
César Leroy,Laure Bonhomme-Coury,Christel Gervais et al.
César Leroy et al.
The spectroscopic study of pathological calcifications (including kidney stones) is extremely rich and helps to improve the understanding of the physical and chemical processes associated with their formation. While Fourier transform infrar...
Selective excitation enables encoding and measurement of multiple diffusion parameters in a single experiment [0.03%]
选择性激励使单次实验即可对多个扩散参数进行编码和测量
Neil MacKinnon,Mehrdad Alinaghian,Pedro Silva et al.
Neil MacKinnon et al.
Band selectivity to address specific resonances in a spectrum enables one to encode individual settings for diffusion experiments. In a single experiment, this could include different gradient strengths (enabling coverage of a larger range ...
Solid-state 1H spin polarimetry by 13CH3 nuclear magnetic resonance [0.03%]
固体物质的1H自旋极化核磁共振检测法（以13CH3为参考）
Stuart J Elliott,Quentin Stern,Sami Jannin
Stuart J Elliott
Dissolution dynamic nuclear polarization is used to prepare nuclear spin polarizations approaching unity. At present, 1H polarization quantification in the solid state remains fastidious due to the requirement of measuring thermal equilibri...
High-affinity tamoxifen analogues retain extensive positional disorder when bound to calmodulin [0.03%]
雌莫司通类似物与钙调蛋白结合时会保持很大的位置无序性
Lilia Milanesi,Clare R Trevitt,Brian Whitehead et al.
Lilia Milanesi et al.
Using a combination of NMR and fluorescence measurements, we have investigated the structure and dynamics of the complexes formed between calcium-loaded calmodulin (CaM) and the potent breast cancer inhibitor idoxifene, a derivative of tamo...
Rapid measurement of heteronuclear transverse relaxation rates using non-uniformly sampled R1 ρ accordion experiments [0.03%]
基于非均匀采样的R1ρAccordion实验快速测量异核横向弛豫率
Sven Wernersson,Göran Carlström,Andreas Jakobsson et al.
Sven Wernersson et al.
Multidimensional, heteronuclear NMR relaxation methods are used extensively to characterize the dynamics of biological macromolecules. Acquisition of relaxation datasets on proteins typically requires significant measurement time, often sev...
The relation between crystal structure and the occurrence of quantum-rotor-induced polarization [0.03%]
晶体结构与量子转子诱导极化现象之间的关系
Corinna Dietrich,Julia Wissel,Oliver Lorenz et al.
Corinna Dietrich et al.
Among hyperpolarization techniques, quantum-rotor-induced polarization (QRIP), also known as the Haupt effect, is a peculiar one. It is, on the one hand, rather simple to apply by cooling and heating a sample. On the other hand, only the me...
Spin noise gradient echoes [0.03%]
自旋噪声梯度回波
Victor V Rodin,Stephan J Ginthör,Matthias Bechmann et al.
Victor V Rodin et al.
Nuclear spin noise spectroscopy in the absence of radio frequency pulses was studied under the influence of pulsed field gradients (PFGs) on pure and mixed liquids. Under conditions where the radiation-damping-induced line broadening is sma...