Pseudo rotary resonance relaxation dispersion effects in isotropic samples [0.03%]
各向同性样品中的伪旋转共振弛豫展宽效应
Evgeny Nimerovsky,Jonas Mehrens,Loren B Andreas
Evgeny Nimerovsky
Enhanced transverse relaxation near rotary resonance conditions is a well-documented effect for anisotropic solid samples undergoing magic-angle spinning (MAS). We report transverse signal decay associated with rotary resonance conditions f...
Electron-spin decoherence in trityl radicals in the absence and presence of microwave irradiation [0.03%]
无微波和有微波情况下三联吡啶自由基的电子自旋退相干
Gunnar Jeschke,Nino Wili,Yufei Wu et al.
Gunnar Jeschke et al.
Trityl radicals feature prominently as polarizing agents in solid-state dynamic nuclear polarization experiments and as spin labels in distance distribution measurements by pulsed dipolar EPR spectroscopy techniques. Electron-spin coherence...
ih-RIDME: a pulse EPR experiment to probe the heterogeneous nuclear environment [0.03%]
一种用于探测异质核环境的脉冲EPR实验(IH-ridme)
Sergei Kuzin,Victoriya N Syryamina,Mian Qi et al.
Sergei Kuzin et al.
The intermolecular hyperfine relaxation-induced dipolar modulation enhancement experiment (ih-RIDME) is a pulse electron paramagnetic resonance (EPR) experiment that can be used to probe the properties of a nuclear spin bath in the vicinity...
Analytical expressions for the time evolution of spin systems affected by two or more interactions [0.03%]
受两种或多种相互作用影响的自旋系统的时间演化分析表达式
Günter Hempel
Günter Hempel
Analytical expressions for the description of the time evolution of spin systems beyond product-operator formalism (POF) can be obtained if a low-dimensional subspace of the Liouville space has been found in which the time evolution of the ...
Workflow for systematic design of electrochemical in operando NMR cells by matching B 0 and B 1 field simulations with experiments [0.03%]
基于B0和B1场的模拟与实验匹配的电化学原位核磁共振电池系统设计的 workflow 研究
Michael Schatz,Matthias Streun,Sven Jovanovic et al.
Michael Schatz et al.
Combining electrochemistry (EC) and nuclear magnetic resonance (NMR) techniques has evolved from a challenging concept to an adaptable and versatile method for battery and electrolysis research. Continuous advancements in NMR hardware have ...
Luzian Thomas,Matthias Ernst
Luzian Thomas
Heteronuclear low-power decoupling using the solution-state wideband alternating-phase low-power technique for zero-residual splitting (WALTZ) sequences has become quite popular in solid-state protein NMR and seems to work well. However, th...
PRESERVE: adding variable flip-angle excitation to transverse relaxation-optimized NMR spectroscopy [0.03%]
改进的翻转角可变TROPNMR谱法
Bernhard Brutscher
Bernhard Brutscher
We introduce the "Polarization Restoring Excitation SEquence foR Versatile Experiments" (PRESERVE) pulse sequence element, allowing variable flip-angle adjustment in 2D 1 H- 15 N and 1 H- 13 C transverse-relaxation-optimized-spectro...
Design and performance of an oversized-sample 35 GHz EPR resonator with an elevated Q value [0.03%]
高性能35GHz EPR谐振腔的设计与性能研究( Oversized样品)
Jörg Wolfgang Anselm Fischer,Julian Stropp,René Tschaggelar et al.
Jörg Wolfgang Anselm Fischer et al.
Continuous-wave electron paramagnetic resonance (EPR) spectroscopy at 35 GHz is an essential cornerstone in multi-frequency EPR studies and is crucial for differentiating multiple species in complex systems due to the improved g -tensor res...
NMR side-chain assignments of the Crimean-Congo hemorrhagic fever virus glycoprotein n cytosolic domain [0.03%]
克里米亚-刚果出血热病毒糖蛋白胞质结构域的核磁共振侧链指认
Louis Brigandat,Maëlys Laux,Caroline Marteau et al.
Louis Brigandat et al.
We assigned the side-chain resonances of the Crimean-Congo hemorrhagic fever virus (CCHFV) glycoprotein n (Gn) cytosolic domain that is 69 amino acids long to complete the backbone resonances previously published by Estrada et al. (2011). T...
1H-enhanced 103Rh NMR spectroscopy and relaxometry of 103Rh(acac)3 in solution [0.03%]
溶液中103Rh(acac)3的1H增强的103Rh NMR光谱和弛豫度研究
Harry Harbor-Collins,Mohamed Sabba,Markus Leutzsch et al.
Harry Harbor-Collins et al.
Recently developed polarisation transfer techniques are applied to the 103 Rh nuclear magnetic resonance (NMR) of the 103 Rh ( acac ) 3 coordination complex in solution. Four-bond 1 H - 103 Rh J couplings of around 0.39 Hz are...