Tzyy-Shyang Lin,Nathan J Rebello,Guang-He Lee et al.
Tzyy-Shyang Lin et al.
BigSMILES, a line notation for encapsulating the molecular structure of stochastic molecules such as polymers, was recently proposed as a compact and readable solution for writing macromolecules. While BigSMILES strings serve as useful iden...
Decoupling Ion Transport and Matrix Dynamics to Make High Performance Solid Polymer Electrolytes [0.03%]
解耦离子传输和基体动力学以制造高性能固体聚合物电解质
Seamus D Jones,James Bamford,Glenn H Fredrickson et al.
Seamus D Jones et al.
Transport of ions through solid polymeric electrolytes (SPEs) involves a complicated interplay of ion solvation, ion-ion interactions, ion-polymer interactions, and free volume. Nonetheless, prevailing viewpoints on the subject promote a si...
Gaining Structural Control by Modification of Polymerization Rate in Ring-Opening Polymerization-Induced Crystallization-Driven Self-Assembly [0.03%]
通过调节开环聚合速率获得结晶驱动自组装的结构控制方法研究
Paul Joshua Hurst,Annissa A Graham,Joseph P Patterson
Paul Joshua Hurst
Polymerization-induced self-assembly (PISA) has become an important one pot method for the preparation of well-defined block copolymer nanoparticles. In PISA, morphology is typically controlled by changing molecular architecture and polymer...
Abigail Mae Clapperton,Jon Babi,Helen Tran
Abigail Mae Clapperton
N-Substituted glycines (peptoids) are a class of peptidomimetic molecules used as materials for health, environmental, and drug delivery applications. Automated solid-phase synthesis is the most widely used approach for preparing polypeptoi...
Computational Study of Mechanochemical Activation in Nanostructured Triblock Copolymers [0.03%]
纳米结构三嵌段共聚物中机械化学活化的计算研究
Zijian Huo,Stephen J Skala,Lavinia R Falck et al.
Zijian Huo et al.
Force-driven chemical reactions have emerged as an attractive platform for diverse applications in polymeric materials. However, the microscopic chain conformations and topologies necessary for efficiently transducing macroscopic forces to ...
Modular Platform of Carbohydrates-modified Supramolecular Polymers Based on Dendritic Peptide Scaffolds [0.03%]
基于树状肽支架的碳水化合物修饰超分子聚合物的模块化平台
Long Li,Libin Wu,Moritz Urschbach et al.
Long Li et al.
Glycopeptide supramolecular polymers displaying multivalent carbohydrates are particularly suitable for immune-relevant biomaterials, due to the important functions of carbohydrates in mediating cell-cell communication and modulating immune...
Timothy P Lodge,Claire L Seitzinger,Sarah C Seeger et al.
Timothy P Lodge et al.
Self-assembly of block copolymers into interesting and useful nanostructures, in both solution and bulk, is a vibrant research arena. While much attention has been paid to characterization and prediction of equilibrium phases, the associate...
Synthesis of Poly(2-(methylsulfinyl)ethyl methacrylate) via Oxidation of Poly(2-(methylthio)ethyl methacrylate): Evaluation of the Sulfoxide Side Chain on Cryopreservation [0.03%]
聚(2-((甲硫基)乙基)甲基丙烯酸酯)通过氧化聚(2-((甲硫代)乙基)甲基丙烯酸酯)合成：评估冷冻保存中的亚砜侧链的作用
Toru Ishibe,Natalia Gonzalez-Martinez,Panagiotis G Georgiou et al.
Toru Ishibe et al.
Conventional cryopreservation solutions rely on the addition of organic solvents such as DMSO or glycerol, but these do not give full recovery for all cell types, and innovative cryoprotectants may address damage pathways which these solven...
Decoupling of Glassy Dynamics from Viscosity in Thin Supported Poly(n-butyl methacrylate) Films [0.03%]
支撑聚(丁基甲基丙烯酸酯)薄膜中玻璃化转变动力学与黏度的脱耦现象研究
Mithun Chowdhury,Xavier Monnier,Daniele Cangialosi et al.
Mithun Chowdhury et al.
We utilized fast scanning calorimetry to characterize the glass transition temperature (T g) and intrinsic molecular mobility of low-molecular-weight poly(n-butyl methacrylate) thin films of varying thicknesses. We found that the T g and in...
Glenn H Fredrickson,Shuyi Xie,Jerrick Edmund et al.
Glenn H Fredrickson et al.
The small specific entropy of mixing of high molecular weight polymers implies that most blends of dissimilar polymers are immiscible with poor physical properties. Historically, a wide range of compatibilization strategies have been pursue...