Noble Gas Isotopes and Nitrogen Isotopologues Reveal Deep Sources and Subsurface Fractionation in Yellowstone Gases [0.03%]
贵重气体同位素和氮同位素揭示黄石地区的深部气源及地下分馏过程
Michael W Broadley,Peter H Barry,Rebecca L Tyne et al.
Michael W Broadley et al.
Nitrogen plays a critical role in maintaining Earth's hospitable surface environment over geological time. Despite our atmosphere being dominated by nitrogen, our understanding of how nitrogen was delivered to Earth and how subsequent plane...
Infrared Irradiation of H2O:CO2 Ice: A Combined Experimental and Computational Study of the Dissipation of CO2 Vibrational Excitations [0.03%]
红外辐射的H2O:CO2冰：CO2振动激发耗散的实验和计算联合研究
Johanna G M Schrauwen,Tobias M Dijkhuis,Sergio Ioppolo et al.
Johanna G M Schrauwen et al.
In interstellar ices, the ice matrix can have a great influence on the chemical reactions. The hydrogen-bonding network in pure water ices facilitates fast energy dissipation that, for example, stabilizes the HOCO complex, a crucial step in...
Updated in-cloud secondary aerosol production in the Northern Hemisphere predicted by the Community Multiscale Air Quality modeling system [0.03%]
社区多尺度空气质量模型中的二次气溶胶生成量预测（更新）(以北半球为例)
Kathleen M Fahey,Neha Sareen,Annmarie G Carlton et al.
Kathleen M Fahey et al.
Clouds are important physicochemical processors of atmospheric pollutants. Major contributors to secondary sulfate, clouds also provide media for the production and processing of secondary organic aerosol (SOA). Sulfate and organic compound...
Gas-Phase Nitrate Radical Production Using Irradiated Ceric Ammonium Nitrate: Insights into Secondary Organic Aerosol Formation from Biogenic and Biomass Burning Precursors [0.03%]
利用辐照的硝酸铈铵产生的气相硝酸盐自由基：源自生物源和生物质燃烧前体二次有机 aerosol 形成的新认识
Andrew T Lambe,Chase K Glenn,Anita M Avery et al.
Andrew T Lambe et al.
The importance of nitrate radicals NO 3 as a nighttime atmospheric oxidant is well-established. For decades, laboratory studies of multiphase NO 3 chemistry have used the same methods - either NO 2 + O 3 reactions or N 2 O 5...
Spontaneous Oxidation of Nitrous Acid to Nitric Acid in Supermicron Aqueous Droplets Is Acid-Accelerated [0.03%]
亚微米液滴中硝酸盐的自发氧化是被酸加速的
Luke W Monroe,Jack W Hall,Graham M Thornhill et al.
Luke W Monroe et al.
It is generally assumed that acidic submicron atmospheric aerosol particles do not constitute a significant sink for nitrous acid (HONO), as this weak acid would remain protonated and volatile, yet the uptake of HONO to larger less acidic p...
Gas-Phase Reactions of H2CS and H2CO with CN: Similarities and Differences from a Computational Study [0.03%]
基于理论计算的H2CS和H2CO与CN的气相反应：相似性和差异性分析
Silvia Alessandrini,Hexu Ye,Cristina Puzzarini
Silvia Alessandrini
The gas-phase reaction of H2CS with the CN radical has been investigated with the aim of understanding its evolution in the interstellar medium (ISM). After the detection of thioformyl cyanide in TMC-1, this process has been incorporated in...
Deciphering the Complexity in the Rotational Spectrum of Deuterated Ethylene Glycol [0.03%]
解 deutero-乙二醇旋转光谱复杂性的密码
Jordan A Claus,Mattia Melosso,Agathe Maillard et al.
Jordan A Claus et al.
Ethylene glycol (CH2OH-CH2OH) is an abundant "complex organic molecule" (COM) detected in different astronomical objects, but the steps of its interstellar synthesis are not yet fully understood. In this respect, the observation of deuterat...
Cosmic Ray Irradiation of Interstellar Ices on Sulfur-Rich Grains: A Possible Source of Sulfur-Bearing Molecules [0.03%]
硫质星际微粒的宇宙射线照射：含硫分子的一种可能来源
Duncan V Mifsud,Zuzana Kaňuchová,Olivier Auriacombe et al.
Duncan V Mifsud et al.
The major reservoir of sulfur in dense interstellar clouds is still largely unknown, although a growing body of evidence suggests that it may exist in a refractory form (i.e., as minerals or allotropes of the element). Therefore, it is poss...
Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition [0.03%]
异戊二烯衍生的环氧二醇在云雾条件下暗水反应生成有机硫酸酯的动力学、机理及反应环境对硫酸酯加成区域选择性的影响研究
Sarah S Petters,Tianqu Cui,Zhenfa Zhang et al.
Sarah S Petters et al.
Atmospheric oxidation of isoprene yields large quantities of highly water-soluble isoprene epoxydiols (IEPOX) that partition into fogs, clouds, and wet aerosols. In aqueous aerosols, acid-catalyzed ring-opening of IEPOX followed by nucleoph...
Rotationally Resolved Spectrum of the Degenerate Antisymmetric C-H Stretching Band of c-C3H3 [0.03%]
立方烷碳𬭩正离子(c-C₃H₃)反对称C-H伸缩带的转动态resolved光谱
Divita Gupta,Philipp C Schmid,Thomas Salomon et al.
Divita Gupta et al.
The rotationally resolved spectrum of the degenerate ν4 antisymmetric C-H stretching band of the cyclopropenyl cation, c-C3H3 +, the smallest aromatic hydrocarbon cation, has been recorded employing leak-out-spectroscopy (LOS) in a cryogen...