Programmable and Chemically Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation [0.03%]
通过瞬时液-液相分离实现可编程和化学燃料驱动的DNA凝聚滴
Jie Deng,Andreas Walther
Jie Deng
Multivalency-driven liquid-liquid phase separation (LLPS) is essential in biomolecular condensates to facilitate spatiotemporal regulation of biological functions. Providing programmable model systems would help to better understand the LLP...
Managing research throughout COVID-19: Lived experiences of supramolecular chemists [0.03%]
新冠肺炎疫情期间的科研管理：超分子化学家的生活体验
Jennifer S Leigh,Jennifer R Hiscock,Sarah Koops et al.
Jennifer S Leigh et al.
The international Women in Supramolecular Chemistry network believes that taking an area-specific approach effectively supports equality, diversity, and inclusion. Science lacks diversity, and this is intersectional. We share effects of cor...
Daniel Lee,Sean P Ross,Xiao Xiao et al.
Daniel Lee et al.
Polycyclic, highly fused and, perforce, highly conjugated aromatic organic compounds (PACs) have been of interest to chemists since the discovery of naphthalene in 1821. In modern decades these have attracted ever-growing attention because ...
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses [0.03%]
结合机器学习的模拟黏蛋白糖链阵列用于分析流感病毒受体识别模式
Taryn M Lucas,Chitrak Gupta,Meghan O Altman et al.
Taryn M Lucas et al.
Influenza A viruses (IAVs) exploit host glycans in airway mucosa for entry and infection. Detection of changes in IAV glycan-binding phenotype can provide early indication of transmissibility and infection potential. While zoonotic viruses ...
Establishing design principles for emissive organic SWIR chromophores from energy gap laws [0.03%]
基于能量带隙法则的有机SWIR发光发色团的设计原则研究
Hannah C Friedman,Emily D Cosco,Timothy L Atallah et al.
Hannah C Friedman et al.
Rational design of bright near and shortwave infrared (NIR: 700-1000 SWIR: 1000- 2000 nm) emitters remains an open question with applications spanning imaging and photonics. Combining experiment and theory, we derive an energy gap quantum y...
Breaking the trade-off between selectivity and adsorption capacity for gas separation [0.03%]
打破气体分离中选择性和吸附容量之间的权衡关系
Naveen Kumar,Soumya Mukherjee,Nathan C Harvey-Reid et al.
Naveen Kumar et al.
The trade-off between selectivity and adsorption capacity with porous materials is a major roadblock to reducing the energy footprint of gas separation technologies. To address this matter, we report herein a systematic crystal engineering ...
Asymmetric Radical Cyclopropanation of Dehydroaminocarboxylates: Stereoselective Synthesis of Cyclopropyl α-Amino Acids [0.03%]
脱氢氨基羧酸的不对称自由基环丙化反应：环丙基α-氨基酸的立体选择性合成
Wan-Chen Cindy Lee,Duo-Sheng Wang,Congzhe Zhang et al.
Wan-Chen Cindy Lee et al.
A catalytic radical process has been developed for asymmetric cyclopropanation of dehydroaminocarboxylates with in situ-generated α-aryldiazomethanes via Co(II)-based metalloradical catalysis (MRC). Through fine-tuning the environments of ...
Zirconium-Redox-Shuttled Cross-Electrophile Coupling of Aromatic and Heteroaromatic Halides [0.03%]
用于芳香族和杂环卤化物交叉偶联反应的氧化还原穿梭剂锆试剂
Ting-Feng Wu,Yue-Jiao Zhang,Yue Fu et al.
Ting-Feng Wu et al.
Transition metal-catalyzed cross-electrophile coupling (XEC) is a powerful tool for forging C(sp2)-C(sp2) bonds in biaryl molecules from abundant aromatic halides. While syntheses of unsymmetrical biaryl compounds through multimetallic XEC ...
A molecular communication channel consisting of a single reversible chain of hydrogen bonds in a conformationally flexible oligomer [0.03%]
由具有构象柔性寡聚物中的单一可逆的氢键链组成的分子通信信道
David T J Morris,Steven M Wales,David P Tilly et al.
David T J Morris et al.
Communication of information through the global switching of conformation in synthetic molecules has hitherto entailed the inversion of chirality. Here, we report a class of oligomer through which information may be communicated through a g...
Fabian Ebner,Lutz Greb
Fabian Ebner
The structure and reactivity of silicon(IV), the second most abundant element in our Earth's crust, is determined by its invariant tetrahedral coordination geometry. Silicon(IV) with a square-planar configuration (ptSi IV ) represents a tra...