Dioxidomolybdenum(VI) complex featuring a 2,4-di-fluoro-substituted amine bis-(phenolate) ligand [0.03%]
含有2,4-二氟代取代胺双(苯氧基)配体的六价钼二氧配合物
Christina L Bowen,Bradley M Wile
Christina L Bowen
Synthetic complexes containing a cis-[MoO2]2+ core are well-established models for the molybdenum co-factor (Moco). Here we report the crystal structure of such a model complex bearing a tetra-dentate amine bis-(phenolate) ligand with fluor...
8-Hy-droxy-6-meth-oxy-7-(3-methyl-but-2-en-yloxy)coumarin (capensine) [0.03%]
8-羟基-6-甲氧基-7-(3-甲基丁-2-烯氧基）香豆素（kapensin）
Azimjon Mamadrakhimov,Luqmonjon Mutalliyev,Sirojiddin Abdullaev et al.
Azimjon Mamadrakhimov et al.
The title coumarin derivative, C15H16O5, was isolated from the roots of Sophora japonica. The coumarin (2H-chromen-2-one) fragment is almost planar, with an r.m.s. deviation of 0.0356 Å. The carbon atom of the meth-oxy substituent is copla...
catena-Poly[[bis-(1 H-indole-5-carboxyl-ato-κ2 O, O')zinc(II)]-μ-4,4'-azobi-pyridine-κ2 N 1: N 1'] [0.03%]
聚[双(异烟酸根-κ2O,O')二锌(II)-μ-4,4'-偶氮吡啶-κ2N1:N1']
Udhayasuriyan Sathya,Jeyaraman Selvaraj Nirmal Ram,Sundaramoorthy Gomathi et al.
Udhayasuriyan Sathya et al.
The asymmetric unit of the title coordination polymer [Zn(C9H6NO2)2(C10H8N4)] n , consists of one ZnII cation, one bidentate 1H-indole-5-carboxyl-ate (I5C) anion and half of a 4,4'-azobi-pyridine (Abpy) neutral ligand. In the coordination p...
Ethyl 2-cyano-2-{(Z)-2-[2,2-di-cyano-1-(4-methyl-phen-yl)eth-yl]cyclo-hexyl-idene}acetate [0.03%]
乙基 2-氰基-2-{(Z)-2-[2,2-二氰基-1-(4-甲基苯基)乙基]环己烯基亚基}醋酸酯
S Sivapriya,S Priyanka,M Gopalakrishnan et al.
S Sivapriya et al.
In the title compound, C22H23N3O2, the cyclo-hexane ring adopts a chair conformation. The methyl-phenyl ring is oriented at an angle of 36.2 (1)° with respect to the best plane of cyclo-hexane moiety. In the crystal, mol-ecules associate v...
Bis(1-methyl-imidazole)[ meso-α,α,α,α-tetra-kis(o-nicotinamido-phen-yl)porphinato]iron(II)-1-methyl-imidazole-tetra-hydro-furan (1/1/1.5) [0.03%]
二(1-甲基咪唑)(meso-α,α,α,α-四酮(o-烟酰基苯基)卟啉)铁(II)与1-甲基咪唑及四氢呋喃的复合物(1/1/1.5)比例
Yingying Fan,Jianfeng Li
Yingying Fan
In the title compound, [FeII(C68H44N12O4)(C4H6N2)2]·C4H6N2·1.5C4H8O, the central FeII ion is coordinated by four pyrrole N atoms of the porphyrin core and two N atoms of the 1-methyl-imidazole ligands in the axial sites. One 1-methyl-imid...
Diethyl 4-(1 H-imidazol-2-yl)-2,6-dimethyl-1,4-di-hydro-pyridine-3,5-di-carboxyl-ate [0.03%]
二乙酯 4-(1H-咪唑-2-基)-2,6-二甲基-1,4-二氢吡啶-3,5-二羧酸酯
Miri Yoo,Dongsoo Koh
Miri Yoo
In the title compound, C16H21N3O4, the 1,4-di-hydro-pyridine ring adopts a flattened boat conformation, with the imidazole substituent in an axial orientation [dihedral angle between ring planes = 82.9 (6)°]. In the crystal structure, pair...
[4-(4-Meth-oxy-phen-yl)-8-oxo-3-(phenyl-selan-yl)spiro-[4.5]deca-3,6,9-trien-2-yl]methyl-cyanamide [0.03%]
[4-(4-甲氧基苯基)-8-氧代-3-(苯基硒基)螺[4.5]癸-3,6,9-三烯-2-基]甲基氰胺
LaQuze L Morris,Clarisa A Alvarado,Julia M Goncalves et al.
LaQuze L Morris et al.
The title compound, C25H22N2O2Se, crystallizes in the space group P21/c with one mol-ecule in the asymmetric unit. The compound was synthesized by the addition of phenyl-selenyl bromide to a cyanamide. The phenyl-selenyl portion and the cya...
Di-chlorido-bis-[2-(pyridin-2-yl-κ N)-1 H-benzimidazole-κ N 3]nickel(II) monohydrate [0.03%]
二氯·双[2-(吡啶-2-基)-1H-苯并咪唑]镍(II)一水合物
Connor S MacNeil,Aloice O Ogweno,Stephen O Ojwach et al.
Connor S MacNeil et al.
In the title complex, [NiCl2(C12H9N3)2]·H2O, a divalent nickel atom is coordinated by two 2-(pyridin-2-yl)-1H-benzimidazole ligands in a slightly distorted octa-hedral environment defined by four N donors of two N,N'-chelating ligands, alo...
Raven Dean,Chelsea N Miller,Sarah K Zingales et al.
Raven Dean et al.
In the title compound, C19H13IO2, the dihedral angle between the naphthyl ring system and the pendant iodo-phenyl ring is 72.48 (11)°. In the crystal, C-H⋯π inter-actions and I⋯O [3.293 (2) Å] halogen bonds are observed, which combine ...
N'-(2-Hy-droxy-3-meth-oxy-benzyl-idene)pyrazine-2-carbohydrazide monohydrate [0.03%]
2-吡嗪甲酰肼(2-羟基-3-甲氧基苯亚甲基)单水合物
Zhaodong Wang
Zhaodong Wang
In the title hydrated Schiff base, C13H12N4O3·H2O, the dihedral angle between the aromatic rings is 5.06 (11)° and an intra-molecular O-H⋯N hydrogen bond closes an S(6) ring. In the crystal, Ow-H⋯O and Ow-H⋯N (w = water) hydrogen bonds...