Selective Oxidation of Glycolaldehyde to Glyoxal Using Ruthenium Complex Catalysts [0.03%]
钌配合物催化剂选择性氧化甘醛制乙二醛
Takuya Sagawa,Atsushi Kondo,Mineo Hashizume
Takuya Sagawa
Cellulose comprises glucose units, and therefore glucose and its derivatives have received attention as a carbon source replacing fossil fuels. In particular, glyoxal, which is obtained from glucose by retro-aldol reaction and subsequent ox...
Cyrene Dimethyl Acetal: Potential Alternative Solvent for Pd-Catalyzed Homogeneous Aminocarbonylation of Iodo(hetero)arene Compounds [0.03%]
环酰胺的二甲基乙缩醛：钯催化芳基碘𬭩盐与伯胺均相氨基甲酰化反应潜在的新一代溶剂研究
Attila Takács,Nuray Uzunlu Ince,Zoltán Medgyesi et al.
Attila Takács et al.
Two potential biomass-derived Cyrene-based reaction media, i.e., Cyrene dimethyl and diethyl acetals, were synthesized and tested as potential polar aprotic alternatives to fossil-based common N,N-dimethylformamide in aminocarbonylation pro...
Synthesis and Electrochemical Characterization of Nickel Germanate as an Electrode Material for Lithium-Ion Batteries [0.03%]
用作锂离子电池电极材料的镍锗酸的合成及电化学性能表征
Darina A Krasilina,Anna A Grushina,Ekaterina K Khrapova et al.
Darina A Krasilina et al.
Here, we report on a study of nickel germanate formation in the Ni(OH)2-GeO2 system under solid-phase synthesis conditions in the 500-800°C temperature range and on the research of electrochemical performance of Ni2GeO4-based electrodes. I...
Carbamate and Sulfamate Bioisosteres of N,N-Dimethyl-3β-Hydroxycholenamide as Ligands of the Liver X Receptors [0.03%]
N,N-二甲基-3β-胆醇胺的 карбамат和硫代карбамат生物等同物作为肝脏X受体配体的研究
Malena Pegenaute,Micaela B Pugliese,Facundo Perez et al.
Malena Pegenaute et al.
Modulating activity of liver X receptors (LXR) has garnered increasing interest, as its principal endogenous ligands, oxysterols, are implicated in diverse disorders, including atherosclerosis and metabolic syndrome. N,N-dimethyl-3β-hydrox...
Modular Molecular Editing for Polymer-to-Polymer Recycling of Postconsumer Plastics [0.03%]
用于消费后塑料聚合物到聚合物回收的模块化分子编辑法
Huilin Xie,Guang Xiao,Lihong Liu et al.
Huilin Xie et al.
Global plastic production has far outpaced recycling capacity, leading to persistent environmental pollution and highlighting the urgent need for efficient end-of-life management. Mechanical recycling suffers from feedstock limitations and ...
Facile Synthesis of Silica Nanowires Using a Sodium Tripolyphosphate Emulsion Template [0.03%]
采用钠三聚磷酸乳状液模板简易合成二氧化硅纳米线
Hai Y Li,Qing Li,Huan H He et al.
Hai Y Li et al.
Despite the advantages of the emulsion template method for silica nanowire synthesis, the potential of inorganic salts as templates remains largely untapped beyond conventional citrate systems. Herein, we report a facile and efficient emuls...
Peculiarities of Mercuration-Iododemercuration of Propargyl Derivatives [0.03%]
propargyl衍生物的汞化-碘代去汞化的特殊性研究
Kristine Valerik Balyan,Lusine Aram Movsisyan,Haykanush Ruben Pogosyan et al.
Kristine Valerik Balyan et al.
The mercuration-iododemercuration reactions of some propargyl systems were explored. In the presence of mercury (II) acetate, propargyl derivatives reacted facilely with iodine. These interactions proceeded by two possible pathways included...
Recent Advances in Heterogeneous Copper(0) Catalysis: Strategies for Cycloaddition, C-B Bond Formation, and Selective Reduction [0.03%]
近期杂原子促进的铜催化研究进展：环加成、C-B键形成及选择性还原反应中的铜(0)催化剂策略研究
Aishwarya Prakash,Sanjay Jagannatha,K Pramoda et al.
Aishwarya Prakash et al.
The development of synthetic procedure for the metallic copper nanoparticles (NPs) has been of great interest in recent years due to their applications in various fields of science and technology, particularly in catalysis. The synthetic me...
Efficient Sulfonation of Syndiotactic Polystyrene Membranes Assessed by Small-Angle Neutron Scattering [0.03%]
基于小角中子散射的立构规整性聚苯乙烯膜的高效磺化性能研究
Aurel Radulescu,Hiroki Iwase,Shin-Ichi Takata
Aurel Radulescu
The selectivity of the δ-form of syndiotactic polystyrene (sPS) toward small organic molecules enables homogeneous functionalization by sulfonation of sPS membranes via soaking in a chloroform solution of a bulky sulfonating agent such as ...
Duc Tai Nguyen,Nayoung Kim,Sang Yeong Han et al.
Duc Tai Nguyen et al.
Single-cell nanoencapsulation (SCNE) enables the direct integration of synthetic materials with living cells, forming cell-in-shell structures that augment native cellular functions without genetic modification. While SCNE has advanced appl...