Na- and K-Iminophosphorane-Phosphine Oxide Complexes as Catalysts for ROP of rac-Lactide [0.03%]
手性内消旋乳酸酯的开环聚合反应中的催化体系的研究——烷基金属配合物催化剂的开发
Dolores-Judith Caballero-Jiménez,Omar-Jorge García-de-Jesús,Nazario Lopez et al.
Dolores-Judith Caballero-Jiménez et al.
Two novel crown-ether complexes of sodium (compound 1) and potassium (compound 2) featuring iminophosphorane-phosphine oxide ligands are reported. The catalytic activity of these compounds toward the ring-opening polymerization (ROP) of rac...
The Role of Cyclic Diketopiperazine in the Formation of Polypeptides on Silica Surfaces [0.03%]
环二肽酮在硅胶表面多肽形成中的作用
Ola El Samrout,Rita Arnesi,Samuele Mistrali et al.
Ola El Samrout et al.
Diketopiperazine (DKP), a recurring product of silica-catalyzed amino acid polymerization, is a molecule of interest in the origin of life studies, as well in the industrial medicinal chemistry. Its role in the peptide bond formation reacti...
Recent Advances and Perspectives of Metal Clusters for Electrochemical Nitrogen Reduction [0.03%]
金属团簇电化学氮还原研究进展与展望
Khalid Aljohani,Terigelema Hao,Irshad Ahamd et al.
Khalid Aljohani et al.
The rapid intensification of anthropogenic nitrogen cycle perturbations and the energy-intensive nature of Haber-Bosch process have motivated the pursuit of sustainable routes for ammonia synthesis. Electrocatalytic nitrogen reduction react...
Brave New Frameworks: Synthesis and Structural Properties of Novel Covalent Triazine Frameworks From Commercial Dicyanobenzenes for Photocatalytic Applications [0.03%]
新颖共价三嗪框架的合成及其光催化性能研究
Mads Lund Nygaard Nielsen,Ronghui Lu,Melissa Jane Marks et al.
Mads Lund Nygaard Nielsen et al.
Covalent triazine frameworks (CTFs) have promising photocatalytic applications including water treatment and the conversion of CO2. This study investigates the utilization of the commercially available precursors 1,2-dicyanobenzene (1,2-DCB...
Harnessing Mechanical Energy for Catalysis: Mechanisms, Materials, and Applications of the Emerging Piezocatalysis Frontier [0.03%]
利用机械能的催化作用：压电催化的机制、材料及应用前景
Yue Zhang,Yifan Chi,Tingting Li et al.
Yue Zhang et al.
Driven by the urgent global water remediation demands, piezocatalysis, as an emerging green tech, has quickly become a massive research hotspot. Piezocatalysis breaks free from the high energy costs and strict operating conditions that ofte...
Rhenium-Doped Antimony Trioxide for Biomass Sucrose Upcycling to Generate Formic Acid Coupling Hydrogen Evolution [0.03%]
掺杂铼的三氧化二锑催化生物质蔗糖升级制备甲酸耦合产氢反应
Jiaqi Xiong,Yating Li,Jingjing Yang et al.
Jiaqi Xiong et al.
It is of significance that abundant biomass sucrose is converted into the high-value-added formic acid (FA) through the sucrose oxidative reaction (SOR). Herein, the high melting point metal rhenium (Re) is doped into the Sb2O3 to form Re-S...
Peptide-Based Pseudo[2]- and [3]rotaxanes Assembled via Square-Planar Palladium Coordination [0.03%]
基于肽的伪[2]和[3]旋转体通过平面正方形钯配位组装而成
Takuma Shinoda,Chouma Kurihashi,Akio Miyazato et al.
Takuma Shinoda et al.
Interlocked peptide molecules exhibit peptidase resistance as well as enzyme inhibitory activity, making them promising candidates for peptide-based drugs. Lasso peptides possess a [1]rotaxane structure, in which a peptide chain threads thr...
Design and Development of Solvent-Sensitive Zn(II)/Al(III) Responsive Chemosensor: Extension to the Real-World Application [0.03%]
一种溶剂敏感型Zn(II)/Al(III)化学传感器的设计、开发及其在实际应用中的拓展
Manik Das,Mousumi Giri,Soumik Laha et al.
Manik Das et al.
In this work, we have synthesised and spectroscopically characterised an acyl hydrazone-based chemosensor, H2L, through two intermediate steps. Remarkably, this chemosensor exhibits selective recognition of Zn(II) and Al(III) ions in 9:1 Et...
Aggregation Induced Emission-Active Ferrocene Appended Naphthalimide and Phthalimide Chromophores for Mechanochromic and Non-Linear Optical Applications [0.03%]
用于机械力学着色和非线性光学应用的菲咯啉附烯萘啶和苯甲酰芳胺发光聚集激活发光分子
P P Sanak Archana,Abdul Rafeek Hiba,Eldose Elsa et al.
P P Sanak Archana et al.
A new ferrocene (Donor) phenyl (π) conjugated phthalimide and naphthalimide (Acceptors) chromophores, Fc-Ph-PI (1) and Fc-Ph-NI (2), were synthesized and characterized. Single-crystal X-ray diffraction studies revealed that chromophore 2 c...
Multifunctional Peroxidase-Mimicking Ag2S/NiS/Reduced Graphene Oxide Nanozyme for Hydrogen Peroxide Determination and Dye Degradation [0.03%]
用于过氧化氢测定和染料降解的多功能模拟过氧化物酶的Ag2S/NiS/rGO纳米酶
Monica Singh,Mukul Das,Abhishek Srivastava et al.
Monica Singh et al.
Hydrogen peroxide (H2O2) is an environmentally beneficial intermediate essential to human biological metabolism. However, the human body may suffer serious cellular damage because of the overproduction and buildup of excess H2O2. For the de...