Parametrization of κ2- N, O-Oxazoline Preligands for Enantioselective Cobaltaelectro-Catalyzed C-H Activations [0.03%]
手性钴电催化C-H活化的κ2-N, O-噁唑啉前配体的参数化研究
Suman Dana,Neeraj Kumar Pandit,Philipp Boos et al.
Suman Dana et al.
Enantioselective electrocatalyzed C-H activations have emerged as a transformative platform for the assembly of value-added chiral organic molecules. Despite the recent progress, the construction of multiple C(sp3)-stereogenic centers via a...
Orkhan Abdullayev,Diego Garay-Ruiz,Berta Bori-Bru et al.
Orkhan Abdullayev et al.
Computational chemistry has become a fundamental part of the understanding and optimization of catalytic processes. Among these, the characterization of homogeneous organometallic catalysts, combining an active transition metal atom and set...
Catalysis in the Excited State: Bringing Innate Transition Metal Photochemistry into Play [0.03%]
激发态中的催化作用：利用内在的过渡金属光化学反应
Fabio Juliá
Fabio Juliá
Transition metal catalysis is an indispensable tool for organic synthesis that has been harnessed, modulated, and perfected for many decades by careful selection of metal centers and ligands, giving rise to synthetic methods with unparallel...
How Local Order Leads to Shape Selectivity in Disordered Materials: The Case of FAU-FER Interzeolite Transformation Intermediates [0.03%]
局部有序如何导致无序材料的形状选择性：FAU-FER沸石转化中间体的情况
Julia Telles de Souza,Alexandre Ferreira Young,Eduardo F Sousa-Aguiar et al.
Julia Telles de Souza et al.
This study presents a series of Interzeolite Transformation Intermediates (ITIs) derived from FAU-to-FER interconversion. These hybrid materials, obtained through precise control of the interconversion process, exhibit both large mesoporosi...
Electron-Withdrawing Effects in Cobalt Porphyrin Catalysts Boost Homogeneous Photocatalytic Hydrogen Evolution in Neutral Aqueous Solutions [0.03%]
具有吸电子效应的钴卟啉催化剂可促进中性水溶液中的均相光催化氢气进化
Chengyu Liu,Titus de Haas,Francesco Buda et al.
Chengyu Liu et al.
Molecular catalysts offer an ideal platform for conducting mechanistic studies of the hydrogen evolution reaction (HER) due to their electronic tunability. This study explores a series of anionic M=Co(III)- and M=Zn(II)-porphyrin complexes ...
Modulation of the Electronic Properties of Co3O4 through Bi Octahedral Doping for Enhanced Activity in the Oxygen Evolution Reaction [0.03%]
通过Bi八面体掺杂调节Co3O4的电子性质以增强氧进化反应中的活性
Damian Gorylewski,Filip Zasada,Grzegorz Słowik et al.
Damian Gorylewski et al.
Developing a highly active and stable electrocatalyst for the oxygen evolution reaction (OER) is essential for efficient hydrogen production through anion exchange membrane water electrolysis powered by renewable electricity. Recently, ther...
A General Amino-(Hetero)arylation of Simple Olefins with (Hetero)aryl Sulfonamides Enabled by an N-Triazinyl Group [0.03%]
简单烯烃与(杂)芳基磺胺的普遍氨基-((杂)芳基)化反应——通过N-三嗪基团实现
Jaxon L Barney,Andrew J Wolfram,Rose Litvak et al.
Jaxon L Barney et al.
(Hetero)arylethylamines are privileged substructures in pharmaceuticals, agrochemicals, and other bioactive compounds. In principle, the amino-(hetero)arylation of olefins represents an ideal strategy for the rapid preparation of these phar...
Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α-Halocarbonyl Compounds: Multiple Roles of Copper [0.03%]
三氯乙酸和α-卤代羰基化合物的可见光驱动催化脱卤反应：铜的多重作用
Abigail J Thillman,Erin C Kill,Alexander N Erickson et al.
Abigail J Thillman et al.
Herein, we report the reaction development and mechanistic studies of visible-light-driven Cu-catalyzed dechlorination of trichloroacetic acid for the highly selective formation of monochloroacetic acid. Visible-light-driven transition meta...
Alejandra Sophia Lozano-Pérez,Pavel Kulyabin,Amit Kumar
Alejandra Sophia Lozano-Pérez
This article gives a perspective on various types of catalytic dehydrogenative polymerization reactions (including organic and main group polymers) while introducing "hydrogen-borrowing polymerization" and "acceptorless dehydrogenative poly...
Correction to "Structural Effects of FeN4 Active Sites Surrounded by Fourteen-Membered Ring Ligands on Oxygen Reduction Reaction Activity and Durability" [0.03%]
《由十四元环配体包围的FeN4活性位点对氧还原反应活性和耐久性结构影响》的勘误
Zhiqing Feng,Soutaro Honda,Junya Ohyama et al.
Zhiqing Feng et al.
[This corrects the article DOI: 10.1021/acscatal.4c01122.]. © 2025 American Chemical Society.
Published Erratum
ACS catalysis. 2025 Feb 14;15(5):3699. DOI:10.1021/acscatal.5c00817 2025