Crystal structures of two SmIII complexes with dipicolinate [DPA]2- ligands: comparison of luminescent properties of products obtained at different pH values [0.03%]
两个Sm(III)与二乙酸吡啶并[5,6-d]嘧啶-2,4-二酮配体配合物的晶体结构及不同pH值下得到的产品发光性质比较
Sabina Svava Mortensen,Thomas Just Sørensen
Sabina Svava Mortensen
The formation of the two title compounds, Na3[Sm(DPA)3]·14H2O tris-odium tris-(pyridine-2,6-di-carboxyl-ato-κ3 O 2,N,O 6)samarate(III) tetra-deca-hydrate, Na3[Sm(C7H3NO4)3]·14H2O, and catena-poly[[[di-aqua-(6-carb-oxy-pyridine-2-carb-oxy...
3,5-Lutidine penta-aqua sulfate complexes of first-row transition metals: [ M(3,5-lutidine)(H2O)5]SO4, with M = Mn, Co, Ni, and Zn [0.03%]
第一过渡系金属的3,5-路啶五水合物硫酸盐配合物：[M(3,5-lutidine)(H2O)5]SO4，M=Mn、Co、Ni和Zn
James A Golen,David R Manke
James A Golen
The reactions of MnSO4·H2O, CoSO4·7H2O, NiSO4·6H2O and ZnSO4·7H2O with 3,5-lutidine (3,5-di-methyl-pyridine) yield crystals of penta-aqua-(3,5-di-methyl-pyridine-κN)manganese(II) sulfate, [Mn(C7H9N)(H2O)5]SO4, (1), penta-aqua-(3,5-di-m...
Crystal structure and Hirshfeld surface analysis of bis-{(Z)- N'-[(E)-(furan-2-yl)methyl-idene]carbamo-hydrazono-thio-ato}nickel(II) methanol disolvate [0.03%]
{(Z)-N'-[(E)-(呋喃-2-基)亚甲基]-碳二亚胺基肼基}镍(II)的晶体结构和Hirshfeld面分析及其甲醇溶剂化物
Asmet N Azizova,Gunay Z Mammadova,Sevim Türktekin Çelikesir et al.
Asmet N Azizova et al.
In the title complex, [Ni(C6H6N3OS)2]·2CH3OH, the NiII atom is coordinated by the S and N atoms of two N'-[(Z)-(furan-2-yl)methyl-idene]carbamohydrazono-thioic acid ligands in a distorted square-planar geometry. The two mutual ligands boun...
Synthesis, crystal structure and Hirshfeld surface analysis of tert-butyl 4-[4-(di-fluoro-meth-oxy)phen-yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate [0.03%]
4-(4-二氟甲氧基苯基)-2,7,7-三甲基-5-氧代-八氢异喹啉-3-羧酸叔丁酯的合成、晶体结构和Hirshfeld面分析
Ezgi Pehlivanlar,Sema Öztürk Yıldırım,Rahime Şimşek et al.
Ezgi Pehlivanlar et al.
The 1,4-di-hydro-pyridine ring of the title compound, C24H29F2NO4, adopts a distorted boat conformation, while the cyclo-hexene ring is in an almost twist-boat conformation. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds as well as C-H⋯...
Crystal structure of Ag3Dy2(NO3)9 and qu-anti-tative comparison to isotypic compounds [0.03%]
Ag3Dy2(NO3)9的晶体结构及其与同构化合物的定量比较研究
Wilhelm Klein
Wilhelm Klein
Single crystals of Ag3Dy2(NO3)9 (tris-ilver didysprosium nona-nitrate) were obtained from a mixture of AgNO3 and Dy(NO3)3·5 H2O. The new compound crystallizes in space group P4132 (No. 213) with a = 13.2004 (4) Å, V = 2300.2 (2) Å3, Z = ...
Synthesis and crystal structure of a bench-stable pyridinium ketene hemiaminal: 1-(1-eth-oxy-ethen-yl)-2-[meth-yl(phen-yl)amino]-pyridin-1-ium tri-fluoro-methane-sulfonate [0.03%]
一种长稳定性吡啶基酮烯半氨基亚胺
Zoe A Krevlin,Isabella C Bote,Maria Christina F Crespo et al.
Zoe A Krevlin et al.
The novel bench-stable N-quaternized ketene N,O-acetal, C16H19N2O+·CF3O3S-, was synthesized and its structure determined. The title compound is a rare example of a pyridinium ketene hemiaminal for which a crystal structure has been determi...
Crystal-structure determination and Hirshfeld surface analysis of two new thio-phene derivatives: (E)- N-{2-[2-(benzo[ b]thio-phen-2-yl)ethen-yl]-5-fluoro-phen-yl}benzene-sulfonamide and (E)- N-{2-[2-(benzo[ b]thio-phen-2-yl)ethen-yl]-5-fluoro-phen-yl}- N-(but-2-yn-1-yl)benzene-sulfonamide [0.03%]
两种新的噻吩衍生物的晶体结构测定与Hirshfeld面分析：(E)-N-{2-[2-(苯并[b]噻吩-2-基)乙烯基]-5-氟苯基}苯磺酰胺和(E)-N-{2-[2-(苯并[b]噻吩-2-基)乙烯基]-5-氟苯基}-N-(丁-1-炔-2-基)苯磺酰胺
S Madhan,M NizamMohideen,Vinayagam Pavunkumar et al.
S Madhan et al.
In the title compounds, C22H16FNO2S2 (I) and C26H20FNO2S2 (II), the benzo-thio-phene rings are essentially planar with maximum deviations of 0.009 (1) and 0.001 (1) Å for the carbon and sulfur atom in compounds I and II, respectively. In I...
Crystal structures and Hirshfeld surface analyses of N, N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol tribromide (1/1), N, N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol di-bromido-iodate (1/1) and N, N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol di-chlorido-iodate (1/1) [0.03%]
N，N-二甲基乙酰胺-1-（二甲基-λ4-亚氨代亚乙基） ethanol三溴化物（1/1），N，N-二甲基乙酰胺-1-（二甲基-λ4-亚氨代亚乙基） ethanol二溴化碘酸盐（1/1）和N，N-二甲基乙酰胺-1-（二甲基-λ4-亚氨代亚乙基） ethanol二氯化物碘酸盐（1/1）的晶体结构及Hirshfeld面分析
Gunay Z Mammadova,Dmitriy F Mertsalov,Dmitriy M Shchevnikov et al.
Gunay Z Mammadova et al.
In the title compounds, N,N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol tribromide (1/1), C4H9NO·C4H10NO+·Br3 - or [(C4H9NO)·(C4H10NO)](Br3), (I), N,N-di-methyl-acetamide-1-(dimethyl-λ4-aza-nyl-idene)ethan-1-ol di-bromi...
(NH4)2[UO2Cl4]·2H2O, a new uranyl tetra-chloride with ammonium charge-balancing cations [0.03%]
(NH4)2[UO2Cl4]·2H2O:一种新的含四氯合铀酸根和铵阳离子的化合物
Tsuyoshi A Kohlgruber,Robert G Surbella Iii
Tsuyoshi A Kohlgruber
A new uranyl tetra-chloride salt with chemical formula, (NH4)2[UO2Cl4]·2H2O, namely, di-ammonium uranyl tetra-chloride dihydrate, 1, was prepared and crystallized via slow evaporation from a solution of 2 M hydro-chloric acid. As confirmed...
Crystal structure and Hirshfeld surface analysis of (E)-1-(2,4-di-methyl-furan-3-yl)-3-phenyl-prop-2-en-1-one [0.03%]
(E)-1-(2,4-二甲基-3-呋喃基)-3-苯基丙-2-烯-1-酮的晶体结构及Hirshfeld面分析
Ali N Khalilov,Victor N Khrustalev,Aida I Samigullina et al.
Ali N Khalilov et al.
The title compound, C15H14O2, adopts an E configuration about the C=C double bond. The furan ring is inclined to the phenyl ring by 12.03 (9)°. In the crystal, pairs of mol-ecules are linked by C-H⋯O hydrogen bonds, forming dimers with R ...