Synthesis, crystal structure and thermal properties of poly[[μ-1,2-bis-(pyridin-4-yl)ethene-κ2N: N'-μ-bromido-copper(I)] 1,2-bis-(pyridin-4-yl)ethene 0.25-solvate] [0.03%]
聚[双(4-吡啶基)乙烯- κ2N:N'-二溴化铜(Ι)]·双(4-吡啶基)乙烯 0.25-溶剂化合物的合成、晶体结构和热性能研究
Christian Näther,Asmus Müller-Meinhard,Inke Jess
Christian Näther
The reaction of copper(I) bromide with 1,2-bis-(pyridin-4-yl)ethene in aceto-nitrile leads to the formation of the title compound, {[CuBr(C12H10N2)]·0.25C12H10N2}n or CuBr(4-bpe)·0.25(4-bpe) [4-bpe = 1,2-bis-(pyridin-4-yl)ethene]. The asy...
Crystal structures of five halido gold complexes involving piperidine or pyrrolidine as ligands or (protonated) as cations [0.03%]
五种含卤素金配合物的晶体结构，涉及作为配体或(质子化)阳离子的哌啶或吡咯烷
Cindy Döring,Peter G Jones
Cindy Döring
In bromido-(pyrrolidine-κN)gold(I) bis-(pyrrolidine-κN)gold(I) bromide, [AuBr(pyr)]·[Au(pyr)2]Br (pyr = pyrrolidine, C4H9N), 2, alternating [AuBr(pyr)] mol-ecules and [Au(pyr)2]+ cations are connected by aurophilic contacts to form infin...
Synthesis and crystal structure of bis-(9-mesityl-9,10-di-hydro-10-aza-9-borabenzo[ h]quinolinato-κ2N1, N10)zinc(II) [0.03%]
二锌(II)双(9-甲基异丙苯基-9,10-氢-10氮杂-9-硼菲苯并喹啉-N1,N10- κ2）的合成及晶体结构
Yannik Appiarius,Pim Puylaert,Anne Staubitz
Yannik Appiarius
The title compound, [Zn(C20H18BN2)2] (Zn L 2), is an overall uncharged chelate that consists of two units of an NH-deprotonated 10-aza-9-borabenzo[h]quinoline ligand (L) per ZnII center. It was synthesized in two steps by treating the proto...
Carbon dioxide capture from air leading to bis-[ N-(5-methyl-1 H-pyrazol-3-yl-κ N2)carbamato-κ O]copper(II) tetra-hydrate [0.03%]
从空气中捕获二氧化碳生成双[N-(5-甲基-1H-咪唑-3-基-κN2)卡巴姆酸盐-κO]铜(II)四水合物
Valerii Y Sirenko,Iryna S Kuzevanova,Oleksandr S Vynohradov et al.
Valerii Y Sirenko et al.
A mononuclear square-planar CuII complex of (5-methyl-1H-pyrazol-3-yl)carbamate, [Cu(C5H6N3O2)2]·4H2O, was synthesized using a one-pot reaction from 5-methyl-3-pyrazolamine and copper(II) acetate in water under ambient conditions. The adso...
Synthesis and crystal structure of silicon pernitride SiN2 at 140 GPa [0.03%]
140Gpa下硅双氮化物SiN2的合成与晶体结构
Pascal L Jurzick,Georg Krach,Lukas Brüning et al.
Pascal L Jurzick et al.
Silicon pernitride, SiN2, was synthesized from the elements at 140 GPa in a laser-heated diamond anvil cell. Its crystal structure was solved and refined by means of synchrotron-based single-crystal X-ray diffraction data. The title compoun...
Crystal structure and Hirshfeld surface analysis of cyclo-tetra-bromido-1κ2Br,3κ2Br-tetra-kis-(μ2-2-{[(pyridin-2-yl)meth-yl]amino}-ethane-1-thiol-ato-κ3N, S: S)tetra-mercury(II) [0.03%]
环四溴合-1κ2Br，3κ2Br-四-[双((2-吡啶甲基)氨基)乙烷-1-硫代硫酸根]-四汞(II)的晶体结构和Hirshfeld面分析
Isla D Thomas,Kathryn R Kocher,Julie A Viehweg et al.
Isla D Thomas et al.
The macrometallacyclic title compound, [Hg4Br4(C8H11N2S)4] or [((HgL 2)(HgBr2))2] (1) where HL = 2-{[(pyridin-2-yl)meth-yl]amino}-ethane-1-thiol, was prepared and structurally characterized. The Hg2+ complex crystallizes in the P21/c space ...
Crystal structure, Hirshfeld surface analysis, inter-action energy and energy framework calculations, as well as density functional theory (DFT) com-putation, of methyl 2-oxo-1-(prop-2-yn-yl)-1,2-di-hydro-quinoline-4-carboxyl-ate [0.03%]
甲基 2-氧代-1-丙-2-烯-1,2-二氢喹啉-4-羧酸酯的晶体结构、Hirshfeld面分析、相互作用能及能量体系计算以及密度泛函理论(DFT)计算
Ayoub El-Mrabet,Amal Haoudi,Samira Dalbouha et al.
Ayoub El-Mrabet et al.
In the title mol-ecule, C14H11NO3, the di-hydro-quinoline core deviates slightly from planarity, indicated by the dihedral angle of 1.07 (3)° between the two six-membered rings. In the crystal, layers of mol-ecules almost parallel to the b...
Synthesis and crystal structure of catena-poly[cobalt(II)-di-μ-chlorido-μ-pyridazine-κ2N1: N2] [0.03%]
二氯桥联吡嗪桥联四水合钴(II)的合成及晶体结构研究
Christian Näther,Inke Jess
Christian Näther
The reaction of cobalt dichloride hexa-hydrate with pyridazine leads to the formation of crystals of the title compound, [CoCl2(C4H4N2)]n. This compound is isotypic to a number of compounds with other divalent metal ions. Its asymmetric uni...
Synthesis, crystal structure, and Hirshfeld surface analysis of 3-ferrocenyl-1-(pyridin-2-yl)-1 H-pyrazol-5-amine [0.03%]
3-ferrocen基-1-(吡啶-2-基)-1H-异噻唑-5-胺的合成、晶体结构及 Hirshfeld 表面分析
Delara Joekar,Lana K Hiscock,Louise N Dawe
Delara Joekar
A key step towards utilizing polynuclear metal-based systems in magnetic device applications involves the careful design of ligands. This strategic planning aims to produce metal assemblies that exhibit some kind of 'switch' mechanism. Towa...
Synthesis, crystal structure and Hirshfeld surface analysis of 3-(4-fluoro-phen-yl)-2-formyl-7-methyl-imidazo[1,2- a]pyridin-1-ium chloride monohydrate [0.03%]
3-(4-氟苯基)-2-甲醛-7-甲基咪唑[1,2- a]吡啶inium氯化物一水合物的合成、晶体结构和Hirshfeld面分析
Firudin I Guseinov,Viacheslav O Ovsyannikov,Pavel V Sokolovskiy et al.
Firudin I Guseinov et al.
In the title salt, C15H12FN2O+·Cl-·H2O, the imidazo[1,2-a]pyridin-1-ium ring system of the cation is almostly planar [maximum deviaition = -0.047 (2) Å for the ring C atom with the attached arene ring] and forms a dihedral angle of 61.81...