Viscoelastic and Thermoreversible Networks Crosslinked by Non-covalent Interactions Between "Clickable" Nucleic Acids Oligomers and DNA [0.03%]
通过“可点击”核苷酸寡聚物与DNA之间的非共价相互作用交联的粘弹性及热可逆网络结构
Alex J Anderson,Heidi R Culver,Stephanie J Bryant et al.
Alex J Anderson et al.
An approach to efficient and scalable production of oligonucleotide-based gel networks is presented. Specifically, a new class of xenonucleic acid (XNA) synthesized through a scalable and efficient thiol-ene polymerization mechanism, "Click...
Self-assembly of oppositely charged polyelectrolyte block copolymers containing short thermoresponsive blocks [0.03%]
含有短温敏序列的带相反电荷的聚电解质嵌段共聚物的自组装行为研究
I A van Hees,P J M Swinkels,R G Fokkink et al.
I A van Hees et al.
The assembly of oppositely charged block copolymers, containing small thermoresponsive moieties, was investigated as a function of salt concentration and temperature. Aqueous solutions of poly-[N-isopropylacrylamide]-b-poly[dimethylaminoeth...
Renewable and recyclable covalent adaptable networks based on bio-derived lipoic acid [0.03%]
基于生物衍生的硫辛酸的可再生和可回收的共价自适应网络
Maher A Alraddadi,Viviane Chiaradia,Connor J Stubbs et al.
Maher A Alraddadi et al.
The modern materials economy is inefficient since most products are principally derived from non-renewable feedstocks and largely single-use in nature. Conventional thermoset materials are often inherently unreprocessable due to their irrev...
Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano- and microscopic vesicles [0.03%]
完全非晶态的无规立构和间同立构嵌段共聚物及其自组装成纳米和显微囊泡
Riccardo Wehr,Elena C Dos Santos,Moritz S Muthwill et al.
Riccardo Wehr et al.
The introduction of chirality into aqueous self-assemblies by employing isotactic block copolymers (BCPs) is an emerging field of interest as it promises special membrane properties of polymersomes not accessible by atactic BCPs. However, i...
Determining Michael Acceptor Reactivity from Kinetic, Mechanistic, and Computational Analysis for the Base-catalyzed Thiol-Michael Reaction [0.03%]
基于动力学、机理和计算分析确定Michael受体在碱催化硫醇-Michael加成反应中的反应活性
Sijia Huang,Kangmin Kim,Grant M Musgrave et al.
Sijia Huang et al.
A combined experimental and computational study of the reactivities of seven commonly used Michael acceptors paired with two thiols within the framework of photobase-catalyzed thiol-Michael reactions is reported. The rate coefficients of th...
Synthetic Approaches for Copolymers Containing Nucleic Acids and Analogues: Challenges and Opportunities [0.03%]
含核苷酸和类似物共聚物的合成方法：挑战与机遇
Hao Lu,Jiansong Cai,Ke Zhang
Hao Lu
A deep integration of nucleic acids with other classes of materials have become the basis of many useful technologies. Among these biohybrids, nucleic acid-containing copolymers has seen rapid development in both chemistry and application. ...
β-Methyl-δ-valerolactone-containing Thermoplastic Poly(ester-amide)s: Synthesis, Mechanical Properties, and Degradation Behavior [0.03%]
含β-甲基-δ-戊内酯结构的热塑性聚酯胺的合成、力学性能和降解行为
David M Guptill,Bhavani Shankar Chinta,Trinadh Kaicharla et al.
David M Guptill et al.
Poly(ester-amide)s (PEAs) have been prepared from (glucose-derived) β-methyl-δ-valerolactone (MVL) by reaction of MVL-derived diamidodiols with diacid chlorides in solution to form poly(ester-amide)s having alternating diester-diamide sub...
Lei Yang,Yuan Lu,Robert J Soto et al.
Lei Yang et al.
Hyperbranched polyesters with a range of exterior thiol modifications were synthesized through a Michael addition thiol-ene reaction. S-Nitrosothiol nitric oxide (NO) donors were subsequently introduced onto the scaffolds to yield NO-releas...
Yongjun Men,Tobias G Brevé,Huanhuan Liu et al.
Yongjun Men et al.
We present a new light cleavable polymer containing o-nitrobenzene thioacetal groups in the main chain. By conjugation to a PEG block, we synthesized block copolymers capable of forming nanoparticles in aqueous solution. We studied drug enc...
Higher-order interfiber interactions in the self-assembly of benzene-1,3,5-tricarboxamide-based peptides in water [0.03%]
基于苯胺-1,3,5-三甲酸酰胺的肽在水中的自组装中的高阶纤维间相互作用
Oleksandr Zagorodko,Tetiana Melnyk,Olivier Rogier et al.
Oleksandr Zagorodko et al.
Mimicking the complexity of biological systems with synthetic supramolecular materials requires a deep understanding of the relationship between the structure of the molecule and its self-assembly pattern. Herein, we report a series of wate...