Stochasticity of poly(2-oxazoline) oligomer hydrolysis determined by tandem mass spectrometry [0.03%]
串联质谱测定聚氧唑啉寡聚体水解的随机性
Tomos E Morgan,Thomas G Floyd,Bryan P Marzullo et al.
Tomos E Morgan et al.
Understanding modification of synthetic polymer structures is necessary for their accurate synthesis and potential applications. In this contribution, a series of partially hydrolyzed poly(2-oxazoline) species were produced forming poly[(2-...
Stimuli-responsive and core cross-linked micelles developed by NiCCo-PISA of helical poly(aryl isocyanide)s [0.03%]
NiCCo-PISA法制备刺激响应型及核交联型螺旋聚芳基异氰胺胶束
Sètuhn Jimaja,Spyridon Varlas,Jeffrey C Foster et al.
Sètuhn Jimaja et al.
We report the synthesis of redox- and pH-sensitive block copolymer micelles that contain chiral cores composed of helical poly(aryl isocyanide)s. Pentafluorophenyl (PFP) ester-containing micelles synthesised via nickel-catalysed coordinatio...
3D printed elastomers with Sylgard-184-like mechanical properties and tuneable degradability [0.03%]
具有硅胶184样机械性能和可调降解性的3D打印弹性体
Nevena Paunović,Jean-Christophe Leroux,Yinyin Bao
Nevena Paunović
The 3D printing of biodegradable elastomers with high mechanical strength is of great interest for personalized medicine, but rather challenging. In this study, we propose a dual-polymer resin formulation for digital light processing of bio...
Thioanisole ester based logic gate cascade to control ROS-triggered micellar degradation [0.03%]
基于硫化物酯的逻辑门级联控制ROS触发的胶束降解
Irene Piergentili,Pepijn R Bouwmans,Luuk Reinalda et al.
Irene Piergentili et al.
In certain tumor and diseased tissues, reactive oxygen species (ROS), such as H2O2, are produced in higher concentrations than in healthy cells. Drug delivery and release systems that respond selectively to the presence of ROS, while mainta...
Gradient Copolymer Prepared from Alternating Ring-Opening Metathesis of Three Monomers [0.03%]
三单体交替环开元聚合制备梯度共聚物
Francis O Boadi,Nicole S Sampson
Francis O Boadi
Bicyclo[4.2.0]oct-6-ene-7-carboxamide is a simple but highly strained olefin monomer which forms an alternating copolymer with cyclohexene in the presence of N-heterocyclic carbene-ruthenium catalyst. [4.2.0] moiety with bulky substituent o...
Metallosupramolecular polymers as precursors for platinum nanocomposites [0.03%]
金属超分子聚合物作为制备铂基纳米复合材料的前驱体
Claudio Cappelletti,Luis M Olaechea,Alessandro Ianiro et al.
Claudio Cappelletti et al.
Nanocomposites comprising a polymer matrix and metallic nanoparticles (NPs) can merge the structural features of the matrix material with the functional characteristics of the NPs. While such materials are promising for a wide range of appl...
A disulfide-based linker for thiol-norbornene conjugation: formation and cleavage of hydrogels by the use of light [0.03%]
一种用于硫醇-环诺龙烯连接的二硫化物基链接剂：利用光形成和分解水凝胶
Markus Lunzer,Boris Maryasin,Tommaso Zandrini et al.
Markus Lunzer et al.
Photolabile groups are the key components of photo-responsive polymers, dynamically tunable materials with multiple applications in materials and life sciences. They usually consist of a chromophore and a labile bond and are inherently ligh...
Samuel P Bernhard,Mackenzie S Fricke,Rainer Haag et al.
Samuel P Bernhard et al.
Dendritic polyglycerols (dPGs) are emerging as important polymers for the study of biological processes due to their relatively low toxicity and excellent biocompatibility. The highly branched nature and high density of endgroups make the d...
Fluorinated nanotubes: synthesis and self-assembly of cyclic peptide-poly(vinylidene fluoride) conjugates [0.03%]
氟化纳米管：环肽-聚偏二氟乙烯缀合物的合成与自组装
Enrique Folgado,Qiao Song,Sebastien Perrier et al.
Enrique Folgado et al.
The synthesis of cyclic peptide-poly(vinylidene fluoride) (CP-PVDF) conjugates comprising (d-alt-l)-cyclopeptides as building blocks and their self-assembly into tube-like structures is described. By growing two PVDF polymeric chains from o...
One-pot construction of nitrogen-rich polymeric ionic porous networks for effective CO2 capture and fixation [0.03%]
用于有效CO2捕获和固化的富氮聚合物离子多孔网络的一锅法合成
Chenxiang Ai,Xinquan Ke,Juntao Tang et al.
Chenxiang Ai et al.
Facile preparation of ionic porous networks (IPNs) with large and permanent porosity is highly desirable for CO2 capture and transformation but remains a challenge. Here we report a one-pot base-mediated construction of nitrogen-rich IPNs t...