Synthesis, Structure, and Antiproliferative Activity of Three Gallium(III) Azole Complexes [0.03%]
三个镓(III)唑配合物的合成、结构及抗增殖活性研究
Stergios Zanias,Giannis S Papaefstathiou,Catherine P Raptopoulou et al.
Stergios Zanias et al.
As part of our interest into the bioinorganic chemistry of gallium, gallium(III) complexes of the azole ligands 2,1,3-benzothiadiazole (btd), 1,2,3-benzotriazole (btaH), and 1-methyl-4,5-diphenylimidazole (L) have been isolated. Reaction of...
Use of the 2-Pyridinealdoxime/N,N'-Donor Ligand Combination in Cobalt(III) Chemistry: Synthesis and Characterization of Two Cationic Mononuclear Cobalt(III) Complexes [0.03%]
2-吡啶甲醛肟/N,N'-配体组合在钴(Ⅲ)化学中的应用：两个阳离子单核钴(Ⅲ)配合物的合成与表征
Konstantis F Konidaris,Catherine P Raptopoulou,Vassilis Psycharis et al.
Konstantis F Konidaris et al.
The use of 2-pyridinealdoxime (paoH)/N,N'-donor ligand (L-L) "blend" in cobalt chemistry has afforded two cationic mononuclear cobalt(III) complexes of the general type [Co(pao)(2)(L-L)](+), where L-L = 1,10-phenanthroline (phen) and 2,2'-b...
Spyridon Papazacharias,Vassiliki Magafa,Nicole Bernad et al.
Spyridon Papazacharias et al.
A series of 7 new human/rat Corticotropin Releasing Hormone (h/r-CRH) analogues were synthesized. The induced alterations include substitution of Phe at position 12 with D-Phe, Leu at positions 14 and 15 with Aib and Met at positions 21 and...
Tansir Ahamad,Saad M Alshehri
Tansir Ahamad
A series of metal-containing epoxy polymers have been synthesized by the condensation of epichlorohydrin (1-chloro-2,3-epoxy propane) with Schiff base metal complexes in alkaline medium. Schiff base was initially prepared by the reaction of...
Studies of the Antiproliferative Activity of Ruthenium (II) Cyclopentadienyl-Derived Complexes with Nitrogen Coordinated Ligands [0.03%]
研究氮配体螯合环戊二烯类配合物的抗增殖活性研究
Virtudes Moreno,Julia Lorenzo,Francesc X Aviles et al.
Virtudes Moreno et al.
Four cationic ruthenium(II) complexes with the formula [Ru(eta(5)-C(5)H(5))(PPh(3))(2)](+), with L = 5-phenyl-1H-tetrazole (TzH) 1, imidazole (ImH) 2, benzo[1,2-b;4,3-b'] dithio-phen-2-carbonitrile (Bzt) 3, and [5-(2-thiophen-2-yl)-vinyl]-t...
In Search for Titanocene Complexes with Improved Cytotoxic Activity: Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(eta-cyclopentadienyl)difluorotitanium(IV) [0.03%]
具有改善细胞毒性的 titanocene 复合物的探索：双环戊二烯基二氟钛(IV)的合成、X射线结构和光谱研究
Elias Koleros,Theocharis C Stamatatos,Vassilis Psycharis et al.
Elias Koleros et al.
The 1 : 2 reaction of [Ti(eta(5)-C(5)H(5))(2)Cl(2)] and AgF in CHCl(3)/H(2)O yielded the fluoro analog [Ti(eta(5)-C(5)H(5))(2)F(2)] (1) in almost quantitative yield (C(5)H(5) is the cyclopentadienyl group). The coordination about the Ti(IV)...
Diorganotin complexes of a thiosemicarbazone, synthesis: properties, x-ray crystal structure, and antiproliferative activity of diorganotin complexes [0.03%]
硫半卡bane配合物的二烃基tin配合物的合成、性能、x射线晶体结构及抗增殖活性
Joanna Wiecek,Dimitra Kovala-Demertzi,Zbigniew Ciunik et al.
Joanna Wiecek et al.
The synthesis and spectral characterization of novel diorganotin complexes with 3-hydroxypyridine-2-carbaldehyde thiosemicarbazone, H(2)L(1), [SnMe(2)(L)] (2), [SnBu(2)(L)] (3), and [SnPh(2)(L)] (4) are reported. The single-crystal X-ray st...
The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation [0.03%]
非血红素铁(III)配合物催化烃氧化的功能研究
Giorgos Bilis,Maria Louloudi
Giorgos Bilis
A detailed catalytic study of LFe(III)Cl (where L = 3-{2-[2-(3-hydroxy-1,3-diphenyl-allylideneamino)-ethylamino]-ethylimino}-1,3-diphenyl-propen-1-ol) for hydrocarbon oxidation was carried out, focusing on the role of solvent, atmospheric d...
Structurally diverse metal coordination compounds, bearing imidodiphosphinate and diphosphinoamine ligands, as potential inhibitors of the platelet activating factor [0.03%]
含有脒二磷酸盐和双膦胺配体的金属配合物作为潜在的活性物质参与抑制血小板活化因子
Alexandros B Tsoupras,Maria Roulia,Eleftherios Ferentinos et al.
Alexandros B Tsoupras et al.
Metal complexes bearing dichalcogenated imidodiphosphinate [R(2)P(E)NP(E)R(2)'](-) ligands (E = O, S, Se, Te), which act as (E,E) chelates, exhibit a remarkable variety of three-dimensional structures. A series of such complexes, namely, sq...
Measuring the cytochrome C nitrite reductase activity-practical considerations on the enzyme assays [0.03%]
测定细胞色素C一硝酸还原酶活性——关于酶分析的实用性考虑因素
Célia M Silveira,Stéphane Besson,Isabel Moura et al.
Célia M Silveira et al.
The cytochrome c nitrite reductase (ccNiR) from Desulfovibrio desulfuricans ATCC 27774 is able to reduce nitrite to ammonia in a six-electron transfer reaction. Although extensively characterized from the spectroscopic and structural points...