Computer Simulation of Ion-Selective Membrane Electrodes and Related Systems by Finite-Element Procedures [0.03%]
有限元方法在离子选择性电极及有关体系计算机模拟中的应用研究进展
W E Morf,E Pretsch,N F De Rooij
W E Morf
A simple but powerful numerical simulation for analyzing the electrochemical behavior of ion-selective membranes and liquid junctions is presented. The computer modeling makes use of a finite-element procedure in the space and time domains,...
Memory Effects of Ion-Selective Electrodes: Theory and Computer Simulation of the Time-Dependent Potential Response to Multiple Sample Changes [0.03%]
离子选择性电极的记忆效应：多次更换样品情况下时变势响应的理论及计算机模拟
Werner E Morf,Ernö Pretsch,Nicolaas F de Rooij
Werner E Morf
A straightforward theoretical description of the time-dependent response of ion-selective membrane electrodes to multiple sample changes is presented. The derivation makes use of an approximation for the ion fluxes in the membrane, and of t...
Electrochemistry in Media of Exceptionally Low Polarity: Voltammetry with a Fluorous Solvent [0.03%]
极性异常低介质中的电化学：氟化溶剂伏安法
Eric J Olson,Paul G Boswell,Bradley L Givot et al.
Eric J Olson et al.
This work demonstrates the first cyclic voltammetry in a perfluorocarbon solvent without use of a cosolvent. The novel electrolyte tetrabutylammonium tetrakis[3,5-bis(perfluorohexyl)phenyl]borate (NBu(4)BArF(104); 80 mM) allows for voltamme...
Interpretation of chronopotentiometric transients of ion-selective membranes with two transition times [0.03%]
具有两个过渡时间的离子选择性膜的时变电势的解释
Justin M Zook,Sándor Bodor,Róbert E Gyurcsányi et al.
Justin M Zook et al.
Passing currents through ion-selective membranes has contributed to the development of a variety of novel methods. In this work, chronopotentiometric (CP) transients with two transition times (breakpoints) are presented for the first time, ...
Cyclic Voltammetry at Shallow Recessed Microdisc Electrode: Theoretical and Experimental Study [0.03%]
浅凹进式微盘电极的循环伏安法的理论与实验研究
Jidong Guo,Ernő Lindner
Jidong Guo
This study focuses on the cyclic voltammetry behavior at shallow recessed microdisc electrode, particularly on the transition from cottrellian behavior to steady state behavior. Diffusion to the inlaid and recessed microdisc electrode is si...
Carbon Fiber/Epoxy Composite Ring-disk Electrode: Fabrication, Characterization and Application to Electrochemical Detection in Capillary High Performance Liquid Chromatography [0.03%]
碳纤维/环氧树脂复合环盘电极的制备、表征及其在毛细管高压液相色谱中的应用
Xiaomi Xu,Stephen G Weber
Xiaomi Xu
Carbon fiber/epoxy composite materials, which are manufactured using the pultrusion process, are commercially available in various shapes and sizes at very low cost. Here we demonstrate the application of such a material as an electrochemic...
Scanning Electrochemical Microscopy of One-Dimensional Nanostructure: Effects of Nanostructure Dimensions on the Tip Feedback Current under Unbiased Conditions [0.03%]
一维纳米结构的扫描电化学显微镜：纳米结构尺寸对零偏条件下针尖反馈电流的影响
Hui Xiong,Jiyeon Kim,Eunkyoung Kim et al.
Hui Xiong et al.
Scanning electrochemical microscopy (SECM) is developed as a powerful approach to electrochemical characterization of individual one-dimensional (1D) nanostructures under unbiased conditions. 1D nanostructures comprise high-aspect-ratio mat...
Electrochemical Dopamine Detection: Comparing Gold and Carbon Fiber Microelectrodes using Background Subtracted Fast Scan Cyclic Voltammetry [0.03%]
黄金和碳纤维微电极的多巴胺检测：使用背景扫描快速循环伏安法进行比较研究
Matthew K Zachek,Andre Hermans,R Mark Wightman et al.
Matthew K Zachek et al.
Electrochemical detection is becoming increasingly important for the detection of biological species. Most current biological research with electrochemical detection is done with carbon fiber electrodes due to their many beneficial properti...
The Rotating Ring-Disk Electrochemistry of the Copper(II) Complex of Thyrotropin-releasing Hormone [0.03%]
thyrotropin释放激素的铜（II）配合物的旋转圆盘电化学研究
Rong Meng,Stephen G Weber
Rong Meng
Thyrotropin-releasing Hormone (TRH) forms an electroactive Cu(II) complex in aqueous solution. Rotating ring-disk electrochemistry reveals oxidation at the disk electrode and reduction at the ring electrode. The plot of limiting current vs....