Modulator Driven Formation of a Very Complex Self-Catenated Zinc Metal-Organic Framework [0.03%]
一种新颖调控剂驱动构建的复杂索合锌金属有机骨架化合物
Alan Braschinsky,Davide M Proserpio,Toby J Blundell et al.
Alan Braschinsky et al.
Solvothermal reaction of N,N'-bis-(5-isophthalic acid)-naphthalenediimide (H4BINDI) with zinc-(II) nitrate hexahydrate in dimethylformamide (DMF) in the presence of trifluoroacetic acid as a modulator gives rise to a self-catenated Metal-or...
Hydrophobicity of Rare Earth Oxides: Contrasting Perspectives and Emerging Insights [0.03%]
稀土氧化物的疏水性：不同视角和最新见解
Jayna K Patel,Ivan P Parkin,Claire J Carmalt
Jayna K Patel
The wettability of rare earth oxides (REOs) including the lanthanide series, scandium, and yttrium has become a subject of increasing interest and debate. While many studies report hydrophobic behavior with high water contact angles, emergi...
Growth of Bulk Hexagonal Boron Nitride from a Lithium Flux [0.03%]
锂熔剂法生长六角氮化硼bulkhexagonalboron nitride)晶体
Nathan Stoddard,Florian Metzger,Tenzin Sherpa et al.
Nathan Stoddard et al.
The hexagonal polymorph of boron nitride (hBN) is a material of great interest for electronic and optoelectronic applications. There is a demand for large-area single crystals both as a bulk material and as a source of 2D monolayers for qua...
Influence of Nanobubbles on the Early Stages of Calcium Carbonate Formation [0.03%]
纳米气泡对碳酸钙形成早期阶段的影响
Talie Zarei,Elmar C Fuchs,Luewton L F Agostinho et al.
Talie Zarei et al.
The mineralization process of calcium carbonate (CaCO3) is essential in both environmental and industrial applications, since it is a ubiquitous biomineral and a primary component of scale deposits in hard water systems. In this study, we e...
The Potential of Microwave Radiation and Mechanochemistry in the Formation of Purine Alkaloids Cocrystals Using Pyromellitic Acid as a Coformer: Synthesis, Structural, Spectroscopic, Thermal Analysis, and Biological Properties [0.03%]
以均苯四甲酸为共晶形成剂的嘌呤生物碱共晶体的微波辐射和机械化学合成、结构、光谱、热性能及生物学性质研究潜在价值
Weronika Cal,Mateusz R Gołdyn,Oliwia Grupa et al.
Weronika Cal et al.
Cocrystallization provides an efficient approach to modifying a wide range of physicochemical properties of active pharmaceutical ingredients (APIs), including solubility, dissolution rate, melting point, and hygroscopicity. Therefore, the ...
M M Jansen,W H J Peeters,D Lamon et al.
M M Jansen et al.
Crystal phase control of III-V semiconductor nanowires grown by the vapor liquid solid mechanism has emerged as a new frontier in nanomaterials in the 2010s. Of particular interest is the ability to grow the metastable wurtzite crystal, whi...
Controlled Crystallization of Nanocrystalline Apatite via Vapor Diffusion on Bacterial Cellulose Membranes Obtained from Mango Waste [0.03%]
基于芒果废弃物的细菌纤维素膜上通过蒸汽扩散控制纳米晶体磷灰石的结晶生长
Isabel Navarro-Zabarburú,Amparo Iris Zavaleta,Susana Calderón-Toledo et al.
Isabel Navarro-Zabarburú et al.
Hybrid bacterial cellulose (BC)-calcium phosphate apatite (Ap) composite was successfully synthesized via the sitting drop vapor diffusion crystallization method. The BC matrix was produced using the bacterial strain Komagataeibacter sp. SU...
Heteroepitaxial Growth of α‑Ga2O3 by MOCVD on a‑, m‑, r‑, and c‑Planes of Sapphire [0.03%]
在蓝宝石a-、m-、r-和c面外延生长α-Ga2O3薄膜
Khai D Ngo,Indraneel Sanyal,Matthew D Smith et al.
Khai D Ngo et al.
Ga2O3 thin films were deposited simultaneously on (112̅0) a-plane, (101̅0) m-plane, (0001) c-plane, and (011̅2) r-plane sapphire substrates using metal-organic chemical vapor deposition (MOCVD) and characterized by X-ray diffraction (XRD...
Evaluation of Azobenzene Ethers Carrying a Perhalogenated Moiety as Halogen Bond Donors by Cocrystallization with Nitrogen-Containing Acceptors [0.03%]
通过与含氮受体共晶化评价携带全卤素供体的重氮苯醚作为卤键供体的能力
Filip Kučas,Lidija Posavec,Nikola Bedeković et al.
Filip Kučas et al.
In this work, we synthesized three novel 4-iodotetrafluorophenoxy-azobenzene ethers, which contain different substituents (X = -H, -Cl, -CN) on the opposite side of the molecule in relation to the perhalogenated moiety carrying the iodine a...
Crystallographic Snapshots of Pre- and Post-Lanthanide Halide HydrolysisReaction Products Captured by the 4‑Amino-1,2,4-triazole Ligand [0.03%]
4-氨基-1,2,4-三氮唑配体捕获的镧系卤化物水解反应前后的晶体学快照及反应产物
Volodymyr Smetana,Geetha Bolla,Ethan A Hiti et al.
Volodymyr Smetana et al.
Reactions of lanthanide-(III) chloride salts with 4-amino-1,2,4-triazole (4-NH2-1,2,4-Triaz) in azole melts have led to the isolation of both hydrolysis and nonhydrolysis products in the same synthesis, with the inclusion of a variety of li...