Controlling the Melting Temperatures and Ion Dynamics of Carboxy-Functionalized Ionic Liquids [0.03%]
含羧基离子液体的熔点及其离子动力学的研究与控制
Alexander E Khudozhitkov,Lasse Hunger,Loai Al Sheakh et al.
Alexander E Khudozhitkov et al.
We measured the 2H spectra of carboxy-functionalized ionic liquids [Py-(CH2)n-COOD][NTf2] with alkyl chains n = 1,2,4,5,6,7,9 by means of NMR solid-state spectroscopy. The change from the broad Pake patterns in the glassy state to the narro...
Effect of Water-DMSO Binary Solvent Mixture on the Behavior of an Intrinsically Disordered Protein, β-Casein [0.03%]
水和二甲基亚砜复合溶剂对固有无序蛋白β-酪蛋白行为的影响
Saurabh Rai,Debanggana Shil,Bijan Kumar Paul et al.
Saurabh Rai et al.
The study of protein behavior in water-dimethyl sulfoxide (DMSO) solvent mixture is of great interest in biophysical research, as DMSO is a widely used cosolvent in various experimental assays. However, investigating the behavior of intrins...
Investigation of Li-Ion Hopping in Ionic-Liquid-Incorporated Methyl Cellulose/Carboxymethyl Cellulose Solid Polymer Electrolyte: A Molecular Simulation Insight [0.03%]
基于分子模拟的含离子液体甲基纤维素/羧甲基纤维素固体聚合物电解质锂离子传导机制研究
Kensuke Ishida,Aditya Wibawa Sakti,Sun Theo Constan Lotebulo Ndruru et al.
Kensuke Ishida et al.
Solid polymer electrolytes (SPEs) of cellulose and its derivatives are known for their use in next-generation Li-ion battery electrolytes, as they are safe and environmentally friendly. Incorporating an ionic liquid into its polymeric mixtu...
Probing the Role of Small Molecules and Amino Acids in Protein Adsorption on Gold Nanoparticles: A Thermodynamic and Mechanistic Insight [0.03%]
探究小分子和氨基酸在金纳米粒子上蛋白质吸附中的作用：热力学及机理研究
Pinki Mahur,Kamini Mishra
Pinki Mahur
A molecular-level understanding of amino acid and small-molecule adsorption onto gold nanosurfaces is essential for designing nanomaterials with tailored biointerfacial properties. Till now, the interactions of gold nanoparticles (GNPs) wit...
Chemical and Region Equilibria with Heterogeneous Fluids Using Classical Density Functional Theory [0.03%]
基于经典密度泛函理论的非均相流体中的化学和区域平衡研究
Igor P S Pereira,Iuri S V Segtovich,Marcelo Castier et al.
Igor P S Pereira et al.
Classical density functional theory has played an important role in adsorption calculations. However, until now, this tool has not been used for adsorption calculations in reactive systems. In this work, a formulation is proposed for minimi...
Analyzing Coherence Effects in Multisite Electronic Excitation Transport Using the Incoherent Born-Markov Rate Model [0.03%]
利用非相干Born-Markov速率模型分析多站点电子激发传输中的相干效应
Amit Kumar Upadhyay,Karthik Sasihithlu
Amit Kumar Upadhyay
The role of quantum coherence in enabling efficient electronic excitation transport (EET) within light-harvesting complexes remains an open question. A recent study introduced an incoherent Born-Markov (incoherent BM) rate model for a three...
Choline Chloride as a Protective Osmolyte: Comparative Stabilization of HP36, Trp-Cage, and GB1 Against Urea Denaturation [0.03%]
氯化胆碱作为保护渗透调节物抵抗尿素变性稳定HP36、Trp-Zipper和GB1蛋白质
Pooja Nanavare,Rajarshi Chakrabarti
Pooja Nanavare
Proteins undergo structural perturbations in the presence of denaturants such as urea, which destabilizes the native fold of the proteins. While protecting osmolytes stabilize proteins against denaturants like urea, the molecular mechanism ...
15N NMR Signal Amplification by Reversible Exchange of [15N3]Ornidazole Antibiotic [0.03%]
含[15N3]奥硝唑抗生素的可逆交换放大15N核磁共振信号
Anna P Yi,Nikita V Chukanov,Mohammad S H Kabir et al.
Anna P Yi et al.
Hyperpolarization techniques provide a dramatic enhancement of the sensitivity of magnetic resonance spectroscopy and imaging. Signal amplification by reversible exchange in shield enables alignment transfer to heteronuclei (SABRE-SHEATH) i...
Synergistic Interplay of Stimulatory Cofactors in the Activation of Adenylyl Cyclase Isoform 1 [0.03%]
激活腺苷酸 cyclase 同工酶 1 的刺激辅助因子的协同作用
Tongtong Li,Shreya Krishnan,Talon Hicks et al.
Tongtong Li et al.
Adenylyl Cyclase isoform 1 (AC1), responsible for synthesizing the signaling molecule cyclic adenosine monophosphate (cAMP), is key in synaptic plasticity, long-term chronic pain syndromes, osteosarcoma-associated pain, and drug abuse. The ...
Shear and Structural Relaxation in Superconcentrated Lithium Bis(trifluoromethanesulfonyl)amide Aqueous Solutions [0.03%]
超高浓度双三氟甲烷磺酰胺锂水溶液的剪切和结构松弛行为研究
Yuta Seike,Keiji Yasuda,Tsuyoshi Yamaguchi et al.
Yuta Seike et al.
Superconcentrated aqueous electrolyte solutions have been actively studied since the first report on lithium-ion batteries operating with superconcentrated aqueous solutions of lithium salt. One of the drawbacks of superconcentrated electro...