Application of Rhodococcus jostii RHA1 glycolate oxidase as an efficient accessory enzyme for lignin conversion by bacterial Dyp peroxidase enzymes [0.03%]
Rhodococcus jostii RHA1 甘酸氧化酶在细菌型Dyp型过氧化物酶体系降解木质素中的应用研究
Awatif Alruwaili,Goran M M Rashid,Timothy D H Bugg
Awatif Alruwaili
Lignin oxidation by bacterial dye-decolorizing peroxidase enzymes requires hydrogen peroxide as a co-substrate, an unstable and corrosive oxidant. We have identified a glycolate oxidase enzyme from Rhodococcus jostii RHA1 that can couple ef...
Rapid Synthesis of Metal Nanoparticles Using Low-Temperature, Low-Pressure Argon Plasma Chemistry and Self-Assembly [0.03%]
低温低压氩等离子体化学及自组装快速合成金属纳米颗粒技术
Marjan Darwish,Camila Mafla-Gonzalez,Belmin Kolenovic et al.
Marjan Darwish et al.
The synthesis of metal nanoparticles has become a priority for the advancement of nanotechnology. In attempts to create these nanoparticles, several different methods: chemistry, physics, and biology, have all been used. In this study, we r...
Peroxidase-induced C-N bond formation via nitroso ene and Diels-Alder reactions [0.03%]
过氧化物酶诱导的通过亚硝基烯和狄尔斯-阿尔德反应的C-N键形成
Christina Jäger,Bernhard J Gregori,Juhana A S Aho et al.
Christina Jäger et al.
The formation of new carbon-nitrogen bonds is indisputably one of the most important tasks in synthetic organic chemistry. Here, nitroso compounds offer a highly interesting reactivity that complements traditional amination strategies, allo...
Improving the sustainability of the ruthenium-catalysed N-directed C-H arylation of arenes with aryl halides [0.03%]
含卤素芳烃参与的钌催化芳烃N导向C-H芳香族化反应的改进及可持续性研究
Michael T Findlay,Ashley S Hogg,James J Douglas et al.
Michael T Findlay et al.
Direct C-H functionalisation methodologies represent an opportunity to improve the overall 'green' credentials of organic coupling reactions, improving atom economy and reducing overall step count. Despite this, these reactions frequently r...
Venturi-based rapid expansion of supercritical solution (Vent-RESS): synthesis of liposomes for pH-triggered delivery of hydrophilic and lipophilic bioactives [0.03%]
基于文丘里效应的超临界溶液快速膨胀技术(Vent-RESS)合成pH响应型脂质体用于亲疏水生物活性分子的传输释放
Apratim Jash,Amy Krueger,Syed S H Rizvi
Apratim Jash
Multivitamin-loaded and surface-modified liposomes tailored for simultaneous intestinal delivery of both lipophilic and hydrophilic bioactives were synthesized from sunflower phosphatidylcholine (SFPC). Liposomes (SL) were generated with th...
'Chemistry at the speed of sound': automated 1536-well nanoscale synthesis of 16 scaffolds in parallel [0.03%]
“以声音的速度进行化学合成”：平行合成16个骨架的1536孔板纳米级自动化合成
Li Gao,Shabnam Shaabani,Atilio Reyes Romero et al.
Li Gao et al.
Screening of large and diverse libraries is the 'bread and butter' in the first phase of the discovery of novel drugs. However, maintenance and periodic renewal of high-quality large compound collections pose considerable logistic, environm...
Unravelling and overcoming the challenges in the electrocatalytic reduction of fructose to sorbitol [0.03%]
揭示并克服电催化还原果糖制山梨醇的挑战
Jordi Creus,Matteo Miola,Paolo P Pescarmona
Jordi Creus
In this work, we present a comprehensive study of the electrocatalytic reduction of fructose to sorbitol and mannitol, in a mild alkaline medium (pH = 11.3), with a Cu wire as the cathode. Particular attention was paid to the reaction mecha...
Metal-free cysteamine-functionalized graphene alleviates mutual interferences in heavy metal electrochemical detection [0.03%]
无金属半胱胺功能化石墨烯缓解重金属电化学检测间的相互干扰作用
Qiuyue Yang,Emily P Nguyen,David Panáček et al.
Qiuyue Yang et al.
Heavy metal pollutants are of great concern to environmental monitoring due to their potent toxicity. Electrochemical detection, one of the main techniques, is hindered by the mutual interferences of various heavy metal ions in practical us...
Net-zero transition of the global chemical industry with CO2-feedstock by 2050: feasible yet challenging [0.03%]
到2050年通过CO2原料实现全球化工行业的净零转型：可行但具有挑战性
Jing Huo,Zhanyun Wang,Christopher Oberschelp et al.
Jing Huo et al.
Carbon capture, utilization and storage (CCUS) have been projected by the power and industrial sectors to play a vital role towards net-zero greenhouse gas emissions. In this study, we aim to explore the feasibility of a global chemical ind...
High yield production of 1,4-cyclohexanediol and 1,4-cyclohexanediamine from high molecular-weight lignin oil [0.03%]
来自高分子量木质素油的1,4-环己二醇和1,4-环己二胺的高产率生产
Xianyuan Wu,Mario De Bruyn,Julia Michaela Hulan et al.
Xianyuan Wu et al.
The complete utilization of all lignin depolymerization streams obtained from the reductive catalytic fractionation (RCF) of woody biomass into high-value-added compounds is a timely and challenging objective. Here, we present a catalytic m...