Solventless and Metal-free Regioselective Hydrofluorination of Functionalized Alkynes and Allenes: An Efficient Protocol for the Synthesis of gem-Difluorides [0.03%]
无溶剂、无金属富马酸的选择性区域化氢氟化：合成丙二烯二氟化物的有效方案
Zhichao Lu,Bhvandip S Bajwa,Shiwen Liu et al.
Zhichao Lu et al.
The combination of two easily handled, highly acidic liquid HF complex reagents, DMPU-12HF and KHSO4-13HF, generated a highly acidic fluorination system that facilitated exclusive Markovnikov addition of HF to widely functionalized alkynes,...
Multifaceted Ion Exchange Resin-Supported Hydrogen Fluoride: A Path to Flow Hydrofluorination [0.03%]
多面性的离子交换树脂支撑的氢氟酸：流动相氢氟化物合成的新路径
Zhichao Lu,Bhvandip S Bajwa,Otome E Okoromoba et al.
Zhichao Lu et al.
Safer bio-based solvents to replace toluene and tetrahydrofuran for the biocatalyzed synthesis of polyesters [0.03%]
用于生物催化合成聚酯的更安全的生物基溶剂替代甲苯和四氢呋喃
Alessandro Pellis,Fergal P Byrne,James Sherwood et al.
Alessandro Pellis et al.
With increased awareness of environmental issues caused by traditional petrochemical processes, both academia and industry are making enormous efforts towards the development of sustainable practices using renewable biomass as a feedstock. ...
Electrodeposition of indium from the ionic liquid trihexyl(tetradecyl)phosphonium chloride [0.03%]
氯三己基十四烷基磷𬭩盐离子液体中铟的电沉积
Clio Deferm,João C Malaquias,Bieke Onghena et al.
Clio Deferm et al.
The electrochemical behavior of indium in the ionic liquid trihexyl(tetradecyl)phosphonium chloride (Cyphos IL 101) was studied. Cyphos IL 101 first had to be purified, as the impurities present in commercial Cyphos IL 101 interfered with t...
Bio-derived Production of Cinnamyl Alcohol via a Three Step Biocatalytic Cascade and Metabolic Engineering [0.03%]
利用生物催化的三步级联和代谢工程生物合成香兰醇的研究
Evaldas Klumbys,Ziga Zebec,Nicholas J Weise et al.
Evaldas Klumbys et al.
The construction of biocatalytic cascades for the production of chemical precursors is fast becoming one of the most efficient approaches to multi-step synthesis in modern chemistry. However, despite the use of low solvent systems and renew...
Citric Juice-mediated Synthesis of Tellurium Nanoparticles with Antimicrobial and Anticancer Properties [0.03%]
具有抗菌和抗肿瘤性能的柠檬汁素介导合成的碲纳米颗粒
David Medina Cruz,William Tien-Street,Bohan Zhang et al.
David Medina Cruz et al.
Bacterial infections and cancer are two of the most significant concerns that the current healthcare system should tackle nowadays. Green nanotechnology is presented as a feasible solution that is able to produce materials with significant ...
The identification and use of robust transaminases from a domestic drain metagenome [0.03%]
来自下水道元基因的稳健亚氨基酶的鉴定与应用
Leona Leipold,Dragana Dobrijevic,Jack W E Jeffries et al.
Leona Leipold et al.
Transaminases remain one of the most promising biocatalysts for use in chiral amine synthesis, however their industrial implementation has been hampered by their general instability towards, for example, high amine donor concentrations and ...
Automated and Accelerated Synthesis of Indole Derivatives on a Nano-Scale [0.03%]
纳米尺度吲哚衍生物的自动化和加速合成法
Shabnam Shaabani,Ruixue Xu,Maryam Ahmadianmoghaddam et al.
Shabnam Shaabani et al.
Automated, miniaturized and accelerated synthesis for efficient property optimization is a formidable challenge for chemistry in the 21st century as it helps to reduce resources and waste and can deliver products in shorter time frames. Her...
High-throughput screening of chemicals as functional substitutes using structure-based classification models [0.03%]
基于结构的分类模型在化学物质高通量筛选功能替代物中的应用
Katherine A Phillips,John F Wambaugh,Christopher M Grulke et al.
Katherine A Phillips et al.
Identifying chemicals that provide a specific function within a product, yet have minimal impact on the human body or environment, is the goal of most formulation chemists and engineers practicing green chemistry. We present a methodology t...
Enhanced separation performance of aqueous biphasic systems formed by carbohydrates and tetraalkylphosphonium- or tetraalkylammonium-based ionic liquids [0.03%]
基于四烷基磷𬭩或四烷基铵离子液体的碳水化合物两相体系的分离性能提升研究
Maria V Quental,Matheus M Pereira,Ana M Ferreira et al.
Maria V Quental et al.
Aiming at establishing more effective and sustainable separation processes, herein we propose the use of carbohydrates combined with tetralkylphosphonium- and tetralkylammonium-based ionic liquids (ILs) to form aqueous biphasic systems (ABS...