Study of tert-butyl bromide hydrolysis in the 1-propanol/water system using the fundamental thermodynamic equation of chemical reactivity [0.03%]
基于化学反应热力学方程研究1-丙醇/水介质中叔丁基溴的水解反应
Floyd L Wiseman,Dane W Scott
Floyd L Wiseman
In previous work we have demonstrated the viability of the fundamental thermodynamic equation of chemical reactivity and have outlined the procedure for analyzing intrinsic activation parameters using this equation. We have recently develop...
Defect chemistry manipulation by heavy ion irradiation in Y-doped CeO2 solid solutions [0.03%]
重离子辐照掺Y的CeO2固溶体缺陷化学态的研究
R Mohun,T Cordara,J McCloy et al.
R Mohun et al.
A combination of experimental methods is used to study the effect of trivalent cation doping and radiation stability of Y-doped CeO2 with dopant content ranging from 0-15 wt%. X-ray diffraction reveals that Y-incorporation leads to long-ran...
A low-cost and high-rate Na4Fe3(PO4)2P2O7@C cathode material directly used in lithium-ion batteries [0.03%]
低成本且高倍率钠电正极Na4Fe3(PO4)2P2O7@C直接用于锂离子电池中
Zonghui Yi,Hui Zhang,Zhiyuan Cheng et al.
Zonghui Yi et al.
Due to its large channels that facilitate the rapid migration of Li+, Na4Fe3(PO4)2P2O7 is considered an affordable high-rate cathode material for LIBs. Na4Fe3(PO4)2P2O7@C was obtained using a simple spray-drying method with low-cost Na and ...
Amnon Stanger,Jordi Poater,Yirong Mo
Amnon Stanger
We investigated the aromatic properties of a set of fifteen cyclic 2π-electron systems and nine 6π-electron charged and neutral systems composed of second-, third-, and fourth-row elements. Three criteria for assessing aromaticity were ap...
High-pressure tuning of electronic structures, stability and mechanical properties of plutonium oxides: a DFT+U study [0.03%]
高压下电子结构、稳定性和力学性能的调控：DFT+U研究Pu的氧化物
Xiaolin Zhang,Minzhuo Xiong,Jinxing Cheng et al.
Xiaolin Zhang et al.
Plutonium (Pu) exhibits exceptionally complex fundamental physical properties, rendering its oxidation and corrosion behaviors a key research focus. Its valence electrons (especially 5f electrons) lie at the boundary of localization and del...
Chang Liu,Zhongjie Han,Rui Ma et al.
Chang Liu et al.
The complex chemical and biophysical characteristics of biomembranes are influenced by the asymmetric distribution of specific lipids. In vitro, the introduction of lysophosphatidylcholine (LPC) into one leaflet of lipid bilayers is frequen...
Host-guest interaction of NO and NO+ species with calixerenes: dissecting the impact of conformational and confinement effects [0.03%]
硝基和一氧化氮与杯状芳香烃的主客体相互作用：揭示构象及限域效应的影响
Hadiya Mecheri Abdulla,Pookkottu K Sajith,Subodh S Khire et al.
Hadiya Mecheri Abdulla et al.
Calixarenes have emerged as a promising molecular platform for the sensing of nitric oxide (NO), due to their characteristic host-guest interaction capabilities. Understanding the noncovalent interactions present in NO-bound calixarene comp...
Quantitative 29Si NMR spectroscopy of ordered mesoporous silicas: revisiting Q3/ Q4 ratios and surface hydroxylation in SBA-15 and MCM-41 [0.03%]
有序介孔硅酸盐的定量固体核磁共振谱学研究：SBA-15和MCM-41中的Q3/Q4比值及其表面羟基化问题的新认识
Valentina V Sobornova,Ilya A Khodov
Valentina V Sobornova
This study highlights a method for analyzing the structural features of mesoporous silicates (MCM-41, MCM-48, SBA-15, and SBA-16) using 29Si NMR spectroscopy, with a focus on the distribution of Qn (n = 0-4) silicon environments. This appro...
Monolayer Sc2NF2 and Sc2NO2 electrodes for bilayer MoS2: achieving symmetric and excellent performances [0.03%]
用于双层MoS₂的单层Sc₂NF₂和Sc₂NO₂电极：实现对称且优异的性能
Hong Li,Xiaotian Hu,Pengyang Liu et al.
Hong Li et al.
Achieving n- and p-type symmetric and excellent two-dimensional Schottky barrier field-effect transistors (SBFETs) remains a significant challenge, particularly when employing a homogeneous channel. The electrode contact properties for bila...
2D correlation SERS of organic ions using AuNP films at electrified soft interfaces [0.03%]
用于电化学软界面的AuNP膜的有机离子的二维相关SERS光谱
Madjid Tarabet,Yinxi Zou,Dyia Syaleyana Md Shukri et al.
Madjid Tarabet et al.
This study reports the formation of gold nanoparticle (AuNP) films by electrochemical assembly at the polarized water|trifluorotoluene interface (ITIES) and their use as SERS substrates whose activity can be tuned by the interfacial potenti...