CO2 Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes [0.03%]
2-(甲氨基)吡啶配位的铝烷基配合物对二氧化碳的捕获
Timothy W Yokley,Hrishikesh Tupkar,Nathan D Schley et al.
Timothy W Yokley et al.
A set of novel, easily synthesized aluminum complexes, Al[κ2-N,N-2-(methylamino)pyridine]2R (R = Et, iBu) are reported. When subjected to 1 atm of CO2 pressure, each hemilabile pyridine arm dissociates and facilitates cooperative activatio...
Sergei I Kozhushkov,Manuel Alcarazo
Sergei I Kozhushkov
This minireview aims to cover the developments over the past two decades in the chemistry of sulfonium salts. Specifically, insight is provided into the synthetic strategies available for the preparation of these compounds, the different re...
A Structural Model for the Iron-Nitrosyl Adduct of Gentisate Dioxygenase [0.03%]
儿茶酸单加氧酶铁-一氧化氮配合物的结构模型
Atanu Banerjee,Jia Li,Amy L Speelman et al.
Atanu Banerjee et al.
We present the synthesis, properties, and characterization of [Fe(T1Et4iPrIP)(NO)(H2O)2](OTf)2 (1) (T1Et4iPrIP = Tris(1-ethyl-4-isopropyl-imidazolyl)phosphine) as a model for the nitrosyl adduct of gentisate 1,2-dioxygenase (GDO). The furth...
(Electro-)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex [0.03%]
基于铼钳形配合物的电/化学氮气活化及断裂反应
Richt S van Alten,Florian Wätjen,Serhiy Demeshko et al.
Richt S van Alten et al.
The splitting of N2 into well-defined terminal nitride complexes is a key reaction for nitrogen fixation at ambient conditions. In continuation of our previous work on rhenium pincer mediated N2 splitting, nitrogen activation and cleavage u...
Orbital Decomposition of the Carbon Chemical Shielding Tensor in Gold(I) N-Heterocyclic Carbene Complexes [0.03%]
金(I)N-杂环卡宾配合物中碳化学屏蔽张量的轨道分解
Maria A Izquierdo,Francesco Tarantelli,Ria Broer et al.
Maria A Izquierdo et al.
The good performance of N-heterocyclic carbenes (NHCs), in terms of versatility and selectivity, has called the attention of experimentalists and theoreticians attempting to understand their electronic properties. Analyses of the Au(I)-C bo...
Henrik Flötotto,Tim Secker,Paul Kögerler et al.
Henrik Flötotto et al.
Bistable spin crossover complexes such as [Fe{HB(pz)3}2] (pzH = pyrazole) show promise for sensor applications and electrically-controlled data storage units, but exploiting their potential hinges on their integration into a functional envi...
Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies [0.03%]
铁桥式氢化物中插入二氧化碳的机理和动力学研究
Dae Ho Hong,Leslie J Murray
Dae Ho Hong
The reduction of CO2 to formic acid by transition metal hydrides is a potential pathway to access reactive C1 compounds. To date, no kinetic study has been reported for insertion of a bridging hydride in a weak-field ligated complex into CO...
The Potential of the Diphosphorus Complex [Cp2W2(CO)4(η2-P2)] as an Organometallic Connecter in Supramolecular Chemistry [0.03%]
二磷配合物[Cp2W2(CO)4(η2-P2)]作为超分子化学中的有机金属连接体的潜力
Mehdi Elsayed Moussa,Pavel A Shelyganov,Brian Wegley et al.
Mehdi Elsayed Moussa et al.
For the first time, the tetrahedral diphosphorus complex [Cp2W2(CO)4(µ,η2:η2-P2)] (Cp = C5H5) (3) is used as a connecter in supramolecular chemistry. The treatment of 3 with CuI halides leads to the formation of the new one-dimensional (...
Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study [0.03%]
利用铑羰基片段研究钳型配体的给电子性质：实验与计算相结合的案例研究
Gemma L Parker,Samantha Lau,Baptiste Leforestier et al.
Gemma L Parker et al.
Metal carbonyls are commonly employed probes for quantifying the donor properties of monodentate ligands. With a view to extending this methodology to mer-tridentate "pincer" ligands, the spectroscopic properties [ν(CO), δ 13C, 1 J RhC] o...
Influence of the Ionic Liquid on the Activity of a Supported Ionic Liquid Phase FeII Pincer Catalyst for the Hydrogenation of Aldehydes [0.03%]
离子液体对负载型离子液体相FeII夹片催化剂醛氢化活性的影响
Zita Csendes,Julian Brünig,Nevzat Yigit et al.
Zita Csendes et al.
The catalytic hydrogenation of different aldehydes to the corresponding alcohols was investigated using an FeII hydride pincer complex as catalyst in the supported ionic liquid phase (SILP) reaction mode. Two different ionic liquids of the ...