Synthesis of Nanoporous Iminodiacetic Acid Sorbents for Binding Transition Metals [0.03%]
纳米多孔亚胺二乙酸配体吸附剂的合成用于结合过渡金属
Brad Busche,Robert Wiacek,Joseph Davidson et al.
Brad Busche et al.
Iminodiacetic acid (IDAA) forms strong complexes with a wide variety of metal ions. Using self-assembled monolayers in mesoporous supports (SAMMS) to present the IDAA ligand potentially allows for multiple metal-ligand interactions to enhan...
Paul J Riedel,Navamoney Arulsamy,Mark P Mehn
Paul J Riedel
Manganese(II) chloride reacts with trimethylsilyl triflate (TMS(OTf) where OTf = (-)OSO(2)CF(3)) in a 1:1 mixture of acetonitrile and tetrahydrofuran, and after recrystallization affords the linear coordination polymer [Mn(II)(CH(3)CN)(2)(O...
Acid-catalyzed disproportionation of oxoiron(IV) porphyrins to give oxoiron(IV) porphyrin radical cations [0.03%]
通过酸催化将含氧铁(IV)卟啉分解成含氧铁(IV)自由基阳离子
Zhengzheng Pan,Martin Newcomb
Zhengzheng Pan
Disproportionation of oxoiron(IV) porphyrin (Compound II) to oxoiron(IV) porphyrin radical cation (Compound I) was studied in three P450 model systems with different electronic structures. Direct conversion of Compound II to Compound I has ...
Binding and selectivity aspects of an expanded azamacrocycle for anions [0.03%]
扩环aza大环的阴离子结合与选择性方面的研究
Kalpana R Dey,Toyketa Horne,Frank R Fronczek et al.
Kalpana R Dey et al.
An expanded azamacrocycle L, containing four secondary and two tertiary amines was synthesized, and its binding ability towards chloride, bromide, iodide, sulfate, nitrate and perchlorate were determined by (1)H NMR titrations in D(2)O at p...
Organometallic ruthenium complexes with thiosemicarbazone ligands: Synthesis, structure and cytotoxicity of [(eta-p-cymene)Ru(NS)Cl] (NS = 9-anthraldehyde thiosemicarbazones) [0.03%]
含噻二唑酮配体的有机金属钌配合物：[(希-p-环己烯基)鲁米(NS)氯](NS=安息香醛噻二唑酮)的合成、结构和细胞毒性
Floyd A Beckford,Gabriel Leblanc,Jeffrey Thessing et al.
Floyd A Beckford et al.
A series of half-sandwich arene-ruthenium complexes of the type [(eta(6)-p-cymene) Ru(thiosemicarbazone)Cl](+) have been synthesized and their biological activity investigated. The first structurally characterized arene-ruthenium half-sandw...
Oral Administration versus Intra-peritoneal Injection of Pb Affects Its Concentration in Selected Rat Tissues [0.03%]
口服给药与腹腔注射铅对其在大鼠选择性组织中浓度的影响
Gregory E Steinbaugh,Richard W Taylor,Douglas R Pfeiffer
Gregory E Steinbaugh
Synthesis and Characterization of a Novel Gd(III)-Cu(II) Dinuclear Adduct [0.03%]
新型Gd(III)-Cu(II)二核加合物的合成与表征
Greg Brewer,Cynthia Brewer,W Robert Scheidt et al.
Greg Brewer et al.
Two novel Gd(III)-Cu(II) dinuclear complexes have been prepared by the acid-base reaction between Gd(hfa)(3) and Cu(2,2-oxomac) (1, Cu(2,2-oxomac)Gd(hfa)(3)) and between Gd(hfa)(3) and Cu(3,2-oxomac) (2, Cu(3,2-oxomac)Gd(hfa)(3)). These com...