Engineering stable cd-based metal-organic framework photocatalysts via ligand pre-metallization and polynuclear clusters: enhanced charge separation for ciprofloxacin degradation [0.03%]
基于配体预金属化和多核簇的工程稳定Cd基MOF光催化剂：增强电荷分离用于环丙沙星降解
Xiao-Huan Liang,Yuan Chen,Ao-Gang Liu et al.
Xiao-Huan Liang et al.
To address environmental remediation challenges from ciprofloxacin (CIP), this study pioneers a ligand pre-metallization strategy diverging fundamentally from conventional post-synthetic approaches. By pre-constructing Fe-N4 coordination in...
Amine-functionalized covalent organic frameworks for high-performance carbon dioxide capture [0.03%]
用于高性能二氧化碳捕获的胺功能化共价有机框架
Feifan Zhao,Feiyan Xu,Hermenegildo García et al.
Feifan Zhao et al.
Covalent organic frameworks (COFs) have garnered significant interest as advanced platforms for carbon capture, utilization, and storage, owing to their high surface area, tunable porosity, and excellent chemical stability. However, their p...
Vapor-phase fluorination to regulating oxygen content of silicon anode materials [0.03%]
硅基负极材料的氟化控氧技术
Zhuang Ma,Qi Zhang,Yin Yang et al.
Zhuang Ma et al.
SiOx is a high-potential candidate material for silicon (Si) derived anodes, owing to its high specific capacity and commendable cycling performance. However, the irreversible formation of phases during lithiation results in low Initial Cou...
Efficient electrosynthesis of ammonia from nitrate reduction over the perylene-3,4,9,10-tetracarboxylic diimide-based heterostructure [0.03%]
基于苝-3,4,9,10-四甲酸二酐的异质结构电合成铵离子 councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill ammonium councill
Hongjun Fang,Fang Fang,Hongsheng Yang et al.
Hongjun Fang et al.
Electrochemical NO3- reduction reaction (eNO3-RR) has shown a promising prospect in both nitrate pollutant removal and NH3 production. However, the lack of novel electrocatalysts hinders its application. Herein, the perylene-3,4,9,10-tetrac...
Synergistic cation-anion regulation of active water within inner Helmholtz plane enables ultra-stable aqueous Zn ion batteries [0.03%]
阴阳协同调控内亥姆霍兹层活化水实现超稳定锌离子电池
Xuemei He,Chaohe Zheng,Min Li et al.
Xuemei He et al.
The issues related to corrosion, dendrite growth, and hydrogen evolution reaction (HER) of the Zn anode in aqueous environments have significantly obstructed the practical implementation of aqueous zinc ion batteries (AZIBs). Herein, the st...
Flexible and durable programmable EMI shielding via shape memory layered EP foam induced by supercritical CO₂ [0.03%]
通过超临界CO₂诱导形状记忆层状EP泡沫实现的灵活且耐用的可编程EMI屏蔽
Shaokang Song,Zhen Zhang,Mingyu Hao et al.
Shaokang Song et al.
The growing prevalence of electromagnetic technologies has highlighted the critical need for adaptive shielding materials in modern communication systems. However, traditional composites are unable to cope with the dynamic electromagnetic e...
Water-stable MAPbBr3@PbBrOH QDs confined by metal-organic framework for photodegradation of wastewater [0.03%]
由金属有机骨架限制的水稳定MAPbBr3@PbBrOH量子点用于废水光降解
Yidi Wang,Yang Wang,Ziqi Wang et al.
Yidi Wang et al.
While the metal halide perovskite materials are emerging as potentially promising photocatalysts, they still suffer from the intrinsic instability, seriously hampering their further practical applications. In this study, a perovskite-based ...
Orienting dendrite resistant behavior via heteroatom regulation toward high areal capacity zinc metal anode [0.03%]
通过异原子调节定向抑制枝晶实现高面积容量的锌金属负极
Ruiyu Zhu,Xi Ren,Liyan Tian et al.
Ruiyu Zhu et al.
Aqueous zinc-ion batteries (AZIBs) have garnered significant attention in energy storage fields due to their inherent advantages of abundant reserves, intrinsic safety, and high volumetric energy density. However, their practical implementa...
Organic oxidation-assisted hydrogen production: glycerol electroreforming to formate on nickel diselenide nanoparticles [0.03%]
有机氧化辅助制氢：镍硒化物纳米颗粒上甘油电重整制甲酸反应研究
Longcheng Yang,Yi Ma,Jing Yu et al.
Longcheng Yang et al.
The energy efficiency of water electrolysis is limited by the sluggish kinetics of the anodic oxygen evolution reaction (OER), which simultaneously produces a low-value product, oxygen. A promising strategy to address this challenge is to r...
CuCl as a Mg2+ reservoir for in situ interface layer engineering and highly stable Mg plating/stripping [0.03%]
氯化铜作为镁二次电池原位界面层的Mg²⁺储库及高性能镁金属阳极
Yuanxiang Zhang,Tianlong Huang,Maosheng Cui et al.
Yuanxiang Zhang et al.
Although rechargeable magnesium batteries (RMBs) represent a promising post‑lithium energy storage technology, the formation of a non-conductive Mg2+ passivation layer on Mg anodes remains a significant challenge. Here, we develop a novel ...