Barium and Radium Complexation with Ethylenediaminetetraacetic Acid in Aqueous Alkaline Sodium Chloride Media [0.03%]
乙二胺四乙酸在氢氧化钠氯化钠水溶液中的钡和镭配位反应研究
Artem V Matyskin,Niklas L Hansson,Paul L Brown et al.
Artem V Matyskin et al.
The speciation of Ra2+ and Ba2+ with EDTA was investigated at 25 °C in aqueous alkaline NaCl media as a function of ionic strength (0.2-2.5 mol·L-1) in two pH regions where the EDTA4- and HEDTA3- species dominate. The stability constants ...
Effect of Base-Acid Properties of Mixtures of Ethanol with Water on the Enthalpy of Solution of Cyclic Ethers in these Mixtures at T = 298.15 K [0.03%]
乙醇-水混合物的酸碱性质对 cyclic ether 类化合物在该混合物体系中于温度 T=298.15K 的溶解焓的影响研究
Małgorzata Jóźwiak
Małgorzata Jóźwiak
The enthalpies of solution of the cyclic ethers 1,4-dioxane, 12-crown-4 and 18-crown-6 in mixtures of ethanol and water have been measured within the whole mole fraction range at T = 298.15 K. The enthalpy of solvation has been calculated. ...
Michael H Abraham,William E Acree Jr
Michael H Abraham
We have used equations for partition coefficients of compounds from water and the gas phase to various solvents to obtain descriptors for pentane-2,4-dione and 21 of its derivatives. These descriptors can then be used to estimate further pa...
Dimerization Constants from Acoustic Measurements: Solutions of Benzene, Cyclohexylamine and Aniline in Cyclohexane [0.03%]
声学测量二聚化常数：苯，环己胺和苯胺在环己烷中的溶液
Andrzej Burakowski,Jacek Gliński
Andrzej Burakowski
A model assuming that the formation of dimers determines the acoustic properties of liquid mixtures, in the inert solvent cyclohexane, was applied to describe the observed dependences of sound speed on composition. The dimerization constant...
Composition of Surface Layer at the Water-Air Interface and Micelles of Triton X-100 + Rhamnolipid Mixtures [0.03%]
Triton X-100 和鼠李糖脂混合体系水气界面吸附层及胶束的组成
Diana Mańko,Anna Zdziennicka,Bronisław Jańczuk
Diana Mańko
Measurements of the surface tensions, densities and viscosities of aqueous solutions of Triton X-100 (TX-100) and rhamnolipid (RL) mixtures, at constant concentration of RL or TX-100, were carried out. The measured values of the surface ten...
Structure of a Hydrated Sulfonatotitanyl(IV) Complex in Aqueous Solution and the Dimethylsulfoxide Solvated Titanyl(IV) Ion in Solution and Solid State [0.03%]
水溶液中硫酸根氧钛(Ⅳ)配合物的结构及N，N-二甲基 sulfoxide溶剂化氧钛(Ⅳ)离子的溶液和固态结构
Daniel Lundberg,Ingmar Persson
Daniel Lundberg
The coordination chemistry of oxotitanium(IV) or titanyl(IV), TiO2+, has been studied in solution by X-ray methods. The titanyl(IV) ion hydrolyzes easily in aqueous systems to solid titanium dioxide as long as it is not stabilized through c...
Analysis of Mesoscopic Structured 2-Propanol/Water Mixtures Using Pressure Perturbation Calorimetry and Molecular Dynamic Simulation [0.03%]
基于压力扰动 calorimetry 和分子动力学模拟的 meso 结构 2-propanol/water 混合物分析研究
Jordan W Bye,Colin L Freeman,John D Howard et al.
Jordan W Bye et al.
In this paper we demonstrate the application of pressure perturbation calorimetry (PPC) to the characterization of 2-propanol/water mixtures. PPC of different 2-propanol/water mixtures provides two useful measurements: (i) the change in hea...
Anais Graff,Etienne Barrez,Philippe Baranek et al.
Anais Graff et al.
An experiment based on electrochemical reactions and pH monitoring was performed in which nickel ions were gradually formed by oxidation of a nickel metal electrode in a solution of boric acid. Based on the experimental results and aqueous ...
A Simple Densimetric Method to Determine Saturation Temperature of Aqueous Potassium Chloride Solution [0.03%]
一种简单的密度法测定氯化钾水溶液饱和温度的方法
Wojciech Bogacz,Mohsen H Al-Rashed,Marcin Lemanowicz et al.
Wojciech Bogacz et al.
The precise control of crystallization is a key issue in providing a high quality crystalline product. It has to be achieved by, among other means, a proper choice of the solution processing temperature, which is determined on the basis of ...
Molecular Dynamics Evaluation of Dielectric-Constant Mixing Rules for H2O-CO2 at Geologic Conditions [0.03%]
地质条件下水和二氧化碳混合体系中介电常数估算的分子动力学研究
Raymond D Mountain,Allan H Harvey
Raymond D Mountain
Modeling of mineral reaction equilibria and aqueous-phase speciation of C-O-H fluids requires the dielectric constant of the fluid mixture, which is not known from experiment and is typically estimated by some rule for mixing pure-component...