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In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I) [0.03%] 作为 Rh(I) 配位的双齿配体对天然存在的手性二烯烃((R/S)-香芹酮)的追求
Zaskia Bezuidenhout,Andreas Roodt Zaskia Bezuidenhout
Bis-rhodium-mu-chlorido dinuclear complexes with natural occurring limonene-type enantiomeric diene nucleophiles, (S)- and (R)-carvone [SCar and RCar], are presented and their single crystal structures reported. Utilizing the diolefinic bon...