Probing Nanorod Assembly and Dynamics in Polymer Nanocomposites in Equilibrium and Shear [0.03%]
聚合物纳米复合材料在平衡态和剪切下的纳米线组装及动力学行为探究
Phillip A Taylor,Ting Ge,Thomas C O&#x;Connor et al.
Phillip A Taylor et al.
Coarse-grained molecular dynamics simulations are used to examine the structure and dynamics of nanorod assemblies in polymer melts under equilibrium and simple shear. We show that as the concentration of nanorods increases, there is a tran...
Effect of Ionomer-Solvent Interactions in PFSA Dispersions: Dispersion Morphology [0.03%]
PFSA分散液中离子体-溶剂相互作用的影响：分散形貌
Melissa Novy,Denis Duchesne,Gregg Dahlke et al.
Melissa Novy et al.
Alcohol-water solvent systems are commonly used to disperse perfluorosulfonic acid ionomers (PFSAs) for the fabrication of proton-exchange membranes, catalyst layers, and thin films. The profound effect of PFSA chemical structure, concentra...
Highly Thermally Stable and Miscible CO2‑Based Block Copolymers by the Combination of Ring-Opening and RAFT Copolymerizations through Mediated Hydrogen Bonding Interactions [0.03%]
基于开环和RAFT共聚的CO2基嵌段共聚物的高热稳定性和混溶性研究
Yen-Ling Kuan,Yu-Chun Chiu,Yun-Sheng Ye et al.
Yen-Ling Kuan et al.
In this study, the chain end of a reversible addition-fragmentation chain transfer (RAFT) polymerization agent of poly-(cyclohexene carbonate) (PCHC) was synthesized via the ring-opening copolymerization of CO2 and cyclohexene oxide (CHO) b...
Emergence of Frank-Kasper Phases from Chemically Simple Block Copolymer: Poly(ethylene oxide)- block-polyisoprene and Its Dry-Brush Blends [0.03%]
来自化学简单的嵌段共聚物的弗兰克-卡斯帕相的出现：聚（环氧乙烷）-聚异戊二烯及其干刷混合物
Zi-En Huang,Yung-Chuan Chuang,Yung-Chen Lin et al.
Zi-En Huang et al.
The Frank-Kasper (FK) phases, also known as tetrahedrally close-packed structures, represent a unique class of ordered morphologies characterized by large unit cells with multiple nonequivalent lattice sites. To date, only a limited number ...
Rui Sun,Yossef A Elabd
Rui Sun
Solid-state multiblock copolymers with two distinct chemistries are well explored and reveal that three-dimensional (3D) continuous network morphologies result in the highest ion conductivities, morphology factors (normalized ion conductivi...
Rational Design of New Biocompatible Near-Infrared Conjugated Polymer Nanoparticles for Biomedical Applications [0.03%]
用于生物医学应用的新型生物相容性近红外聚合物纳米粒子的合理设计
Aristea Pavlou,Athanasios Katsouras,Maria Markou et al.
Aristea Pavlou et al.
Conjugated polymer nanoparticles (CPNs) have gained significant attention as promising nanomaterials for cancer theranostics, particularly in fluorescence imaging and therapy, where early detection and image-guided surgery are crucial for e...
Halil Ibrahim Coskun,Rushik Radadiya,Gorkem Yilmaz et al.
Halil Ibrahim Coskun et al.
The effect of halogen type in dual-catalyzed photoinduced atom transfer radical polymerization (photoATRP) of methyl acrylate (MA) and methyl methacrylate (MMA) was systematically investigated under green LED irradiation (λ ∼ 527 nm) usin...
Nitroarene-Mediated Photo-oxidative Deconstruction and Upcycling of Unsaturated Rubber Waste [0.03%]
硝基芳烃介导的不饱和废橡胶光氧化解聚及高值化利用
Mengdong Guo,Zefeng Wang,Roberto Obregon et al.
Mengdong Guo et al.
Transforming waste polymers into materials with improved properties offers a compelling strategy for advancing the sustainable use of polymers, echoing the Chinese proverb: "Blue comes from indigo but surpasses it in blueness." Herein, we r...
Competing Effects of Network Architecture and Composition on Polydomain Liquid Crystal Elastomers [0.03%]
网络架构和组成对多域液晶弹性体的相互竞争的影响
David Taeyeun Yang,Callie W Zheng,Chun Lam Clement Chan et al.
David Taeyeun Yang et al.
Main-chain liquid crystal elastomers (LCEs) are synthesized to investigate the interplay of the composition and network structure on LCE nematic-to-isotropic (N-I) transitions. We focus on networks synthesized from liquid crystalline oligom...
Time-Dependent Structure Assessment of Conjugated Polymer Aggregates in Solution by Single-Molecule Fluorescence Spectroscopy [0.03%]
利用单分子荧光光谱评估溶液中共轭聚合物聚集体的结构及其时间依赖性变化
Esther Schäfer,Michael Sommer,Maria Ott
Esther Schäfer
Monitoring and understanding the aggregation kinetics of n-type polymers provide strategies to favorably control aggregation and thereby optimize conjugated polymers ink shelf life, printability, and thin-film properties. Here, the in situ ...