On Replacing Poly(ethylene oxide) in Solid Block Copolymer Electrolytes by Poly(glycidyl methyl ether): Morphology and Ionic Conductivity [0.03%]
用聚环氧乙烷作为固相嵌段共聚物电解质的研究及其离子电导率和形态学研究
Ioannis Tzourtzouklis,Tobias Gäb,Marianna Spyridakou et al.
Ioannis Tzourtzouklis et al.
A new family of block copolymer electrolytes, where the "soft" block is synthesized via anionic ring opening copolymerization of ethylene oxide (EO) and glycidyl methyl ether (GME) and the "hard" block is glassy polystyrene (PS), overcomes ...
Phase Coexistence in Thermoresponsive PNIPAM Hydrogels Triggered by Mechanical Forces [0.03%]
机械力触发的温敏PNIPAM水凝胶相共存
Noy Cohen
Noy Cohen
Poly-(N-isopropylacrylamide) (PNIPAM) is a temperature-responsive polymer that undergoes large volumetric deformations through a transition from a swollen to a collapsed state at a volume phase transition temperature (VPTT). Locally, these ...
María Del Mar Ramos-Tejada,Alberto Martín-Molina,Daniel Montesinos et al.
María Del Mar Ramos-Tejada et al.
Nanogels (as well as other polymer networks) can absorb nanoparticles that give them new properties and expand their application possibilities. The resulting hybrid entities constitute a kind of polymer nanocomposites, which have become an ...
Yinghao Li,Jing Lyu,Wenxin Wang
Yinghao Li
Intramolecular cyclization is a pervasive yet often ignored factor in step-growth polymerizations (SGPs), particularly under dilute conditions. While experimental studies have confirmed the significant impact of concentration on cyclization...
Vitrimeric Behavior Revealed by Fast Scanning Calorimetry in Branched Polyglycerol Networks Cross-Linked by Reversible Enamine Bonds [0.03%]
基于可逆烯胺键交联的支化聚甘油网络中的超高分子量动力学研究：快扫描 calorimetry 发现的 Vitrimer 行为
Vasiliki Maria Stavropoulou,Marta Aldecoa-Ortueta,Ester Verde-Sesto et al.
Vasiliki Maria Stavropoulou et al.
Dynamic covalent bonds formed by enamine have played a crucial role in the development of vitrimers by enabling their rearrangement and reprocessability. In this study, polymer networks obtained by cross-linking a β-ketoester-functionalize...
Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters [0.03%]
单体插入单体单元引发硫杂环酯的自由基聚合以制备可化学及热降解的聚硫酯塑料
Touseef Kazmi,Kyle S Hepburn,Qamar Nisa et al.
Touseef Kazmi et al.
Polythioesters are promising as sustainable materials with improved properties. But, despite the industrial importance of radical polymerization, polythioester homopolymers are not readily accessible through this method. Using dibenzo-[c,e]...
One-Time Network Rearrangement for Homogenization of Epoxy Resin Structures [0.03%]
用于环氧树脂结构同质化的一次性网络重组
Kazuma Kumamoto,Atsuomi Shundo,Satoru Yamamoto et al.
Kazuma Kumamoto et al.
Epoxy resins, which form highly cross-linked and permanent network structures by curing reactions between epoxy and amine compounds, are typically in a glassy state at room temperature. They are thus inherently brittle, a property that seve...
Impact of Stereocontrolled Polynorbornene Synthesis on Degradation Rate [0.03%]
立体控制多 norbornene 合成对其降解速率的影响
Britney Baez,Greyson Karis-Sconyers,Ethan Flanagan et al.
Britney Baez et al.
We synthesized a family of polynorbornenes with a wide range of cis/trans compositions by ring-opening metathesis polymerization (ROMP) with a variety of ruthenium catalysts and subjected these materials to ultrasonication as a proxy for me...
The Role of Water Volume Fraction on Water Adsorption in Anion Exchange Membranes [0.03%]
溶剂化水体积分数对阴离子交换膜吸水性的影响机制研究
Gervasio Zaldivar,Ruilin Dong,Joan M Montes de Oca et al.
Gervasio Zaldivar et al.
Water absorption plays a key role in the performance of polymeric anion exchange membranes. It influences important properties such as ionic conductivity and mechanical strength and alters their performance as solid electrolytes in hydrogen...
Ionization and Chain Size of Weak Polyelectrolytes in Semidilute Regime [0.03%]
半稀溶液中弱聚电解质的离子化程度及其链长度的影响
Lucie Nová,Miroslav Štěpánek,Iryna Morozova et al.
Lucie Nová et al.
We present the relations between chain size, correlation length, and degree of ionization for linear weak polyelectrolytes in the semidilute regime. In the semidilute regime, SAXS provides the correlation length(s), ξ, but cannot provide t...