Sebastian Seitel,Lynn K R J Zank,Stephanie Ihmann et al.
Sebastian Seitel et al.
Amphiphilic polymer conetworks (APCNs) are highly interesting material for membranes, drug delivery, or tissue engineering since their heterogeneous structure and interactions allow for the control of the diffusion of molecules differing by...
Tuning Regioselectivity in Cyclopolymerization through Carbene Ligand Size Modulation in Molybdenum Imido Alkylidene Catalysts [0.03%]
通过碳基配体尺寸调控钼亚胺卡宾(id烯)催化剂环聚反应区域选择性
Koushani Kundu,Severin Haid,Patrick Probst et al.
Koushani Kundu et al.
Herein we report on the regioselectivity in cyclopolymerization of diethyl dipropargylmalonate (DEDPM) with a set of 22 different neutral and cationic molybdenum imido alkylidene catalysts bearing either a cyclic alkyl amino carbene (CAAC) ...
Morphological Changes in PEDOT:PSS under Electrolytes, Dopamine, and PEG-400 Exposure: A Molecular Simulation Perspective [0.03%]
电介质、多巴胺和PEG-400暴露下PEDOT：PSS的形态变化：分子模拟视角
Amali G Guruge,Hesam Makki,Alessandro Troisi
Amali G Guruge
Poly-(3,4-ethylenedioxythiophene):poly-(styrene sulfonate) (PEDOT:PSS) is a widely used conducting polymer, whose conductivity can be enhanced by incorporation of specific chemical components, whereas diffusion of water into the material ca...
Design, Scalable Synthesis, and Characterization of Poly(Oligourethane Methacrylate)s Bottlebrushes with Discrete, Sequence-Defined, and Stereocontrolled Side-Chains [0.03%]
具有离散、序列确定和立体控制侧链的聚（寡聚脲烷甲基丙烯酸酯）瓶刷状聚合物的设计、可扩展合成与表征
Siyasanga Mbizana,Jan Rutkowski,Krzysztof Zwoliński et al.
Siyasanga Mbizana et al.
Sequence and stereocontrol govern the sophisticated functionalities of biopolymers, such as proteins and nucleic acids. Unfortunately, although conventional polymerization methods are easy to perform, they often yield polymers with broad st...
Unraveling the Relevant Length and Time Scales of Elastomers in a High Strain Rate Test [0.03%]
高应变率下橡胶材料力学行为的分子模拟研究
Katherine M Evans,Dustin A Baird,Polette J Centellas et al.
Katherine M Evans et al.
This study uses a recently developed cavitation approach, laser-induced membrane expansion (LIME), to study the high strain rate mechanical properties of three elastomers: poly-(styrene-b-isoprene-b-styrene) (SIS), cross-linked linear polyd...
Reference-Free Quantitative Mass Spectrometry Enables Sequencing of Resist Copolymers and Reveals Sequence-Dependent Deprotection Sensitivity [0.03%]
无参考系定量质谱法可实现抗蚀剂共聚物的测序并揭示其脱保护敏感性取决于序列
Yusuke Hibi,Yasuyuki Nakamura,Shiho Uesaka et al.
Yusuke Hibi et al.
The influence of monomer sequence in resist polymers on line-edge roughness (LER) has long remained elusive in semiconductor lithography. Although the arrangement of degradable and nondegradable monomers should affect polymer solubility in ...
The RAFT-Mediated Synthesis of Poly(styrene- co-maleic acid) through Direct Copolymerization of Maleic Acid [0.03%]
RAFT直接共聚制备苯乙烯-马来酸无规共聚物及对其性能的研究
Michael-Phillip Smith,Lauren E Ball,Bert Klumperman
Michael-Phillip Smith
This work describes the reversible addition-fragmentation chain-transfer (RAFT)-mediated synthesis of poly-(styrene-co-maleic acid) (SMA). Various comonomer feeds were investigated to acquire tunable nonalternating SMA. The isolated copolym...
Induced Circularly Polarized Luminescence of Dynamically Racemic Luminophores Assisted by Formation of Helical Phase via Self-Assembly of Chiral Block Copolymers [0.03%]
手性嵌段共聚物自组装形成螺旋相诱导动态消旋发光材料的圆偏振发光
Chin-Cheng Kuo,Sheng-Wei Shao,Puhup Puneet et al.
Chin-Cheng Kuo et al.
This work aims to suggest a facile approach for induced circular dichroism (ICD) and induced circularly polarized luminescence (iCPL) of the optically inactive, dynamically racemic luminophore tris-(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,...
Access to Self-Assembled Poly(2-Oxazoline)s through Cationic Ring Opening Polymerization-Induced Self-Assembly (CROPISA) [0.03%]
通过阳离子开环聚合诱导自组装(CROPISA)获得自组装聚氧杂旋环烷（poly(2-oxazoline)s）的方法
James Lefley,Steven Huband,C Remzi Becer
James Lefley
Self-assembled block copolymers provide wide range of opportunities in encapsulation and release of active compounds in aqueous and nonaqueous systems. However, developing new polymeric systems that have the precise ratio of blocks and back...
Characterizing Hydrated Polymers via Dielectric Relaxation Spectroscopy: Connecting Relative Permittivity, State of Water, and Salt Transport Properties of Sulfonated Polysulfones [0.03%]
介电谱技术研究磺化聚砜的溶剂化行为及其与水结合状态和盐传输性质之间的关系
Sean M Bannon,Beatrice M Tremblay,Andrew Boudreau et al.
Sean M Bannon et al.
Sulfonated polysulfone is a promising membrane material for separation and energy generation processes that rely on membranes to control the rates of small-molecule (e.g., water and ions) transport. The interactions among water molecules, i...