High Resolution FTIR Study on NH(2)Cl Molecule: Inversion and Anharmonicity [0.03%]
NH(2)Cl分子的高分辨FTIR研究：倒置和非谐性
Ei-ichi Masuko Ei,Saeko Shin,Yoshiaki Hamada
Ei-ichi Masuko Ei
The high-resolution FTIR absorption spectra of the NH(2)Cl molecule have been measured in the region 500-3600 cm(-1). The rotational structures of all the fundamental bands and a number of overtone and combination bands have been analyzed. ...
Rovibrational Study of the CH(2) Wagging Fundamental of Monofluoroacetonitrile [0.03%]
一氟乙腈的CH₂摇摆基频的转动-振动研究
A. Baldacci,P. Stoppa,A. Pietropolli Charmet et al.
A. Baldacci et al.
The vapor-phase infrared spectrum of monofluoroacetonitrile (CH(2)FCN) has been recorded at high resolution in the nu(4) band region (1363-1398 cm(-1)) using a tunable diode laser spectrometer. A detailed assignment of the rotational struct...
The Electronic Spectrum of Germanium Monosulfide: Rotational Structure in the A(1)Pi-X(1)Sigma(+) Transition in (70)GeS [0.03%]
锗单硫化物的电子光谱：A(1)π-X(1)σ+跃迁中７０GeS的转动结构
B. J. Shetty,Sunanda Krishnakumar,T. K. Balasubramanian
B. J. Shetty
The emission spectrum of the specific isotopomer (70)GeS was excited in a microwave (2450-MHz) discharge and the A(1)Pi-X(1)Sigma(+) transition (270-430 nm) was photographed under high resolution on a 10.6-m Ebert grating spectrograph. The ...
Mass Derivatives of Molecular Parameters and Distortions in r((2))(m) Structures [0.03%]
r(2)(m)构型分子参数的质量导数及变形效应
James K. G. Watson
James K. G. Watson
Expressions are derived for the derivatives of various molecular vibration-rotation parameters with respect to atomic masses. These are applied to determine an expression for the mass derivatives of the zero-point moments of inertia, and he...
Isamu Morino,Koichi M. T. Yamada
Isamu Morino
Pure rotational transitions of the SF radical in the ground electronic state, (2)Pi, have been measured in the millimeter- and submillimeter-wave region using a spectrometer equipped with backward wave oscillators as radiation sources. The ...
Brian J. Drouin,Charles E. Miller,Edward A. Cohen et al.
Brian J. Drouin et al.
Pure rotational transitions of the chlorine monoxide radical have been observed up to v=2 in the X(1) (2)Pi(3/2) and X(2) (2)Pi(1/2) states and transitions of the (35)Cl(18)O isotopomer have been observed in natural abundance. Additionally,...
Critical Evaluation of the Prediction of the Dissociation Energy and the Energy Spectrum of the Ground State of KRb by the Reduced Potential Curve Method [0.03%]
评价利用简化势能曲线方法预言KRb分子解离能和基态光谱的问题
O. Bludský,F. Jen&cbreve;
O. Bludský
The estimates of the value of the dissociation energy and the energy spectrum of the KRb molecule made previously (O. Bludský, M. Ju&rbreve;ek, V. Spirko, B. A. Brandt, and F. Jen&cbreve;, 1995, J. Mol. Spectrosc. 169, 555-582) are compare...
Laser-Induced Fluorescence Spectrum of the Orbitally Forbidden &Btilde;'(2)Delta-&Xtilde;(2)Sigma(+) Transition of SrCCH [0.03%]
SrCCH中禁戒轨道&Btilde;'(2)Δ-&Xtilde;(2)Σ+跃迁的激光诱导荧光光谱
Gregory M. Greetham,Andrew M. Ellis
Gregory M. Greetham
Experimental and Theoretical Study of the Electronic States and Spectra of TeH and TeLi [0.03%]
实验和理论研究碲化氢和碲化锂的电子态及光谱
K. D. Setzer,E. H. Fink,A. B. Alekseyev et al.
K. D. Setzer et al.
Gas-phase emission spectra of the hitherto unknown free radical TeLi have been measured in the NIR range with a Fourier-transform spectrometer. The emissions were observed from a fast flow system in which tellurium vapor in argon carrier ga...
High-Resolution Spectroscopy and Analysis of the nu(3) and nu(4) Fundamentals of Monoisotopic (70)GeF(4) [0.03%]
70GeV4单同位素分子ν(3)和ν(4)基频的高分辨光谱与分析
V. Boudon,H. Bürger,E. B. Mkadmi
V. Boudon
The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of (70)GeF(4). The FTIR spectra of the two infrared active fundamentals, namely the nu(4) (bending) and nu(3) (stretching) modes, were rec...