The Energy Levels of the nu(5)/2nu(9) Dyad of HNO(3) from Millimeter and Submillimeter Rotational Spectroscopy [0.03%]
基于毫米和亚毫米波旋转光谱的HNO₃的ν(5)/2ν(9)双峰的能量水平
Douglas T. Petkie,Thomas M. Goyette,Paul Helminger et al.
Douglas T. Petkie et al.
In this paper we show that the rotational structure of the nu(5)/2nu(9) infrared band near 11 &mgr;m can be synthesized to high accuracy from pure rotational measurements in the millimeter- and submillimeter-wave region. The analysis uses a...
The Gas-Phase Electric Dipole Moments of the Symmetric Top Tertiary Butyl Molecules (t)BuX, X=F, Cl, Br, I, CN, and NC [0.03%]
三甲基乙基分子(t)BuX，X=F，Cl，Br，I，CN和NC的气相电偶极矩（其中为对称陀螺拓扑结构）
Z. Kisiel,E. Bialkowska-Jaworska,O. Desyatnyk et al.
Z. Kisiel et al.
The electric dipole moments of symmetric top tertiary butyl derivatives were determined from Stark effect measurements made with cavity Fourier transform microwave spectroscopy under conditions of supersonic expansion. The resulting values ...
Real Atmosphere Laboratory Measurements of the 118-GHz Oxygen Line: Shape, Shift, and Broadening of the Line [0.03%]
118GHz氧原子特征谱线的实验室实测：谱线型式、频移和增宽
M. Yu. Tretyakov,V. V. Parshin,V. N. Shanin et al.
M. Yu. Tretyakov et al.
For the first time the 118-GHz line of the oxygen molecule was investigated in the laboratory under a real atmosphere. The experiment was carried out by modern resonator spectroscopy methods on the laboratory air at atmospheric pressure. Th...
High-Resolution Infrared and Millimeter-Wave Study of D(3)SiF: The Ground and v(3)=1 States of the (29)Si and (30)Si Species, and the v(3)=v(6)=1 and v(3)=2 States of D(3) (28)SiF [0.03%]
D3SiF的高分辨红外与毫米波研究：（29）Si和（30）Si两同位素物种基态以及v3=1状态，D3（28）SiF分子的v3=v6=1和v3=2状态
N. Ben Sari-Zizi,H. Najib,J. Demaison et al.
N. Ben Sari-Zizi et al.
The nu(3) band of D(3)SiF near 890 cm(-1) recorded with a resolution of 2.4x10(-3) cm(-1) has been explored for the (29)Si and (30)Si isotopic species. Moreover, the nu(3)+nu(6)-nu(6) and 2nu(3)-nu(3) bands for the main (28)Si isotopomer ha...
The Submillimeter-Wave Spectrum and Quantum Chemical Calculations of Glyoxylic Acid [0.03%]
glyoxylic酸的亚毫米波光谱及量子化学计算
B. Bakri,J. Demaison,L. Margulès et al.
B. Bakri et al.
Glyoxylic acid is a possible candidate for interstellar detection. Many transitions of the submillimeter wave spectrum of the ground vibrational state of its most stable conformer have been measured for the first time. These transitions hav...
Diode-Laser Measurements of Absolute Line Intensities in the nu(1) Band of Cyanogen Chloride [0.03%]
利用二极管激光器测量氯化氰ν(1)带的绝对线强度
Jacques Walrand,Marc Lengelé,Ghislain Blanquet et al.
Jacques Walrand et al.
With a tunable diode-laser spectrometer, absolute line intensity measurements have been made in the spectrum of cyanogen chloride in the vicinity of 710 cm(-1). The intensity of the fundamental nu(1) band has been found to be 6.088 cm(-2) a...
Analytical Evaluation of the Maxwell-Boltzmann Velocity Average in Pressure-Broadened Half-Width Calculations [0.03%]
Maxwell-Boltzman速度平均的分析评价在压力展宽半宽度计算中的应用
Robert R. Gamache
Robert R. Gamache
For the first time the half-width within the complex Robert-Bonamy (CRB) formalism is calculated without making the mean relative thermal velocity approximation. The application is to the nitrogen-broadened half-width of the 500.4-GHz trans...
N(2)-Broadening for Methyl Chloride at Low Temperature by Diode-Laser Spectroscopy [0.03%]
低温下氯化甲基的N(2)展宽的激光光谱学研究
Jean-Pierre Bouanich,Ghislain Blanquet,Jean-Claude Populaire et al.
Jean-Pierre Bouanich et al.
Using a tunable diode-laser spectrometer, we have measured N(2)-broadening coefficients of 87 individual rovibrational lines in the P and R branches of the nu(3) band of methyl chloride (CH(3)(35)Cl) at 203.2 K. These lines with J values ra...
The Fourier Transform Emission Spectrum of the A(3)Pi(0)-X(1)Sigma(+) Band System of InCl [0.03%]
铟氯分子A(^3Π)_0-X(^1Σ_)~+跃迁系的傅里叶变换发射光谱
M. D. Saksena,M. N. Deo
M. D. Saksena
For the first time, the emission spectrum of A(3)Pi(0)-X(1)Sigma(+) band system of InCl molecule has been recorded on BOMEM DA8 Fourier transform spectrometer at an apodized resolution of 0.025 cm(-1). The rotational structure of 1-0, 2-1, ...
The v(6)=2 States of the Four C(3v)-Symmetry Isotopomers of FClO(3) [0.03%]
FClO(3)的四个C(3v)对称同位素异构体的v(6)=2态
G. Graner,K. Burczyk
G. Graner
High-resolution infrared spectra of the four isotopomers of FClO(3) of C(3v) symmetry have been analyzed in order to obtain data on overtones of the nu(6) vibrational mode. For v(6)=2, two different approaches have been used. The component ...