Lead-free solder alloys: Thermodynamic properties of the (Au + Sb + Sn) and the (Au + Sb) system [0.03%]
无铅焊料合金：(AU+Sb+Sn)和(Au+Sb)系统的热力学性质研究
Michael Hindler,Zhongnan Guo,Adolf Mikula
Michael Hindler
The thermodynamic properties of liquid (Au-Sb-Sn) alloys were studied with an electromotive force (EMF) method using the eutectic mixture of KCl/LiCl with addition of SnCl2 as a liquid electrolyte. Activities of Sn in the liquid alloys were...
S Fürtauer,E Tserenjav,A Yakymovych et al.
S Fürtauer et al.
Integral molar enthalpies of mixing were determined by drop calorimetry for Cu-Li-Sn at 1073 K along five sections xCu/xSn ≈ 1:1, xCu/xSn ≈ 2:3, xCu/xSn ≈ 1:4, xLi/xSn ≈ 1:1, and xLi/xSn ≈ 1:4. The integral and partial molar mixing ent...
Deviations from Ideal Sublimation Vapor Pressure Behavior in Mixtures of Polycyclic Aromatic Compounds with Interacting Heteroatoms [0.03%]
具有相互作用杂原子的多环芳烃混合物的理想升华蒸汽压行为偏差
Jillian L Goldfarb,Eric M Suuberg
Jillian L Goldfarb
Despite the relatively small atomic fraction of a given heteroatom in a binary mixture of polycyclic aromatic compounds (PAC), the inclusion of heteroatomic substituted compounds can significantly impact mixture vapor pressure behavior over...
Thermodynamic Analysis of Thermal Hysteresis: Mechanistic Insights into Biological Antifreezes [0.03%]
热迟滞的热力学分析：生物防冻剂的作用机制洞察
Sen Wang,Natapol Amornwittawat,Xin Wen
Sen Wang
Antifreeze proteins (AFPs) bind to ice crystal surfaces and thus inhibit the ice growth. The mechanism for how AFPs suppress freezing is commonly modeled as an adsorption-inhibition process by the Gibbs-Thomson effect. Here we develop an im...
Strategies for assessing proton linkage to bimolecular interactions by global analysis of isothermal titration calorimetry data [0.03%]
等温滴定量热法全球分析评估质子与双分子相互作用偶联的策略
Nathan P Coussens,Peter Schuck,Huaying Zhao
Nathan P Coussens
Isothermal titration calorimetry (ITC) is a traditional and powerful method for studying the linkage of ligand binding to proton uptake or release. The theoretical framework has been developed for more than two decades and numerous applicat...
Buffer Standards for the Physiological pH of N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycine (TRICINE) from T = (278.15 to 328.15) K [0.03%]
N-[2-羟基-1,1-双（羟甲基）乙基]甘氨酸（TRICINE）在T = (278.15至328.15) K下的生理pH缓冲标准
Rabindra N Roy,Lakshmi N Roy,Isaac B Henson et al.
Rabindra N Roy et al.
The pH values of two buffer solutions without NaCl and seven buffer solutions with added NaCl, having ionic strengths (I = 0.16 mol·kg(-1)) similar to those of physiological fluids, have been evaluated at 12 temperatures from T = (278.15 t...
Buffer standards for the physiological pH of the zwitterionic compound of 3-(N-morpholino)propanesulfonic acid (MOPS) from T = (278.15 to 328.15) K [0.03%]
3-（N-吗啉代）丙磺酸（MOPS）两性化合物生理pH缓冲标准值（T=278.15至328.15K）
Lakshmi N Roy,Rabindra N Roy,Kathleen A Allen et al.
Lakshmi N Roy et al.
This paper reports the pH values of five NaCl-free buffer solutions and eleven buffer compositions containing NaCl at I = 0.16 mol·kg(-1). Conventional pa(H) values are reported for sixteen buffer solutions with and without NaCl salt. The ...
Enthalpies of mixing of liquid systems for lead free soldering: Al-Cu-Sn system [0.03%]
无铅焊接的三元合金系液相混合焓熵研究-Al-Cu-Sn系统
Hans Flandorfer,Meryem Rechchach,A Elmahfoudi et al.
Hans Flandorfer et al.
The present work refers to high-temperature drop calorimetric measurements on liquid Al-Cu, Al-Sn, and Al-Cu-Sn alloys. The binary systems have been investigated at 973 K, up to 40 at.% Cu in case of Al-Cu, and over the entire concentration...
Solid vapor pressure for five heavy PAHs via the Knudsen effusion method [0.03%]
五种含有多环芳烃(PAHs)的固体蒸汽压测定
Jinxia Fu,Eric M Suuberg
Jinxia Fu
Polycyclic aromatic hydrocarbons (PAHs) are compounds resulting from incomplete combustion and many fuel processing operations, and they are commonly found as subsurface environmental contaminants at sites of former manufactured gas plants....
James W Rice,Eric M Suuberg
James W Rice
To characterize better the thermodynamic behavior of a binary polycyclic aromatic hydrocarbon mixture, thermochemical and vapor pressure experiments were used to examine the phase behavior of the {anthracene (1) + benzo[a]pyrene (2)} system...