Carbon Dioxide Solubilities in Decanoic Acid-Based Hydrophobic Deep Eutectic Solvents [0.03%]
十酸基氢ophobic深吴质溶剂中的二氧化碳溶解度
Lawien F Zubeir,Dannie J G P van Osch,Marisa A A Rocha et al.
Lawien F Zubeir et al.
The solubility of CO2 in hydrophobic deep eutectic solvents (DESs) has been measured for the first time. Six different hydrophobic DESs are studied in the temperature range from 298 to 323 K and at CO2 pressures up to 2 MPa. The results are...
Solubility of the Proteinogenic α-Amino Acids in Water, Ethanol, and Ethanol-Water Mixtures [0.03%]
蛋白基因型α-氨基酸在水、乙醇及乙醇-水混合物中的溶解度
Nathan A Bowden,Johan P M Sanders,Marieke E Bruins
Nathan A Bowden
The addition of organic solvents to α-amino acids in aqueous solution could be an effective method in crystallization. We reviewed the available data on the solubility of α-amino acids in water, water-ethanol mixtures, and ethanol at 298....
Measurement and Correlation of the Viscosity of 1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)-3-pentanone [0.03%]
1,1,1,2,2,4,5,5,5-非甲基九氟-4-(三氟甲基)-3-戊酮的黏度测量及关联式研究
Chenyang Wen,Xianyang Meng,Marcia L Huber et al.
Chenyang Wen et al.
The Paris Agreement on climate change, in which many nations have agreed to limit greenhouse gas emissions, has spurred interest in developing working fluids with low global warming potential (GWP) that can satisfy environmental concerns an...
Measurement and Correlation of the Thermal Conductivity of trans-1-Chloro-3,3,3-trifluoropropene (R1233zd(E)) [0.03%]
跨1-氯-3,3,3-三氟丙烯(R1233zd(E))的导热系数的测量及关联式研究
Richard A Perkins,Marcia L Huber,Marc J Assael
Richard A Perkins
New experimental data on the thermal conductivity of trans-1-chloro-3,3,3-trifluoropropene (R1233zd(E)) are reported that allow the development of wide-range correlations. These new experimental data, covering a temperature range of 204 K t...
Approaches for calculating solvation free energies and enthalpies demonstrated with an update of the FreeSolv database [0.03%]
自由能和溶剂化焓的计算方法及FreeSolv数据库的更新
Guilherme Duarte Ramos Matos,Daisy Y Kyu,Hannes H Loeffler et al.
Guilherme Duarte Ramos Matos et al.
Solvation free energies can now be calculated precisely from molecular simulations, providing a valuable test of the energy functions underlying these simulations. Here, we briefly review "alchemical" approaches for calculating the solvatio...
Aqueous biphasic systems composed of ionic liquids and acetate-based salts: phase diagrams, densities and viscosities [0.03%]
由离子液体和醋酸盐组成的水基双相系统:相图、密度和粘度
Maria V Quental,Helena Passos,Kiki A Kurnia et al.
Maria V Quental et al.
Ionic-liquid-based aqueous biphasic systems (IL-based ABS) have been largely investigated as promising extraction and purification routes. In this context, the determination of their phase diagrams and the physical properties of the coexist...
Bubble-Point Measurements of n-Propane + n-Decane Binary Mixtures with Comparisons of Binary Mixture Interaction Parameters for Linear Alkanes [0.03%]
正丙烷和正癸烷二元混合物的泡点测量及比较线性烷烃的二元相互作用参数
Elisabeth Mansfield,Ian H Bell,Stephanie L Outcalt
Elisabeth Mansfield
To develop comprehensive models for multicomponent natural gas mixtures, it is necessary to have binary interaction parameters for each of the pairs of constituent fluids that form the mixture. The determination of accurate mixture interact...
Correcting "static" measurements of vapor pressure for time dependence due to diffusion and decomposition [0.03%]
由于扩散和分解导致的因时间变化而修正“静态”测量的蒸汽压
Robert F Berg
Robert F Berg
The static method for measuring vapor pressure assumes that the sample is pure and that its temperature is steady and uniform. In practice, the measured pressure may be time dependent due to evaporative cooling after pumping on the sample, ...
Apparatus to measure the vapor pressure of slowly decomposing compounds from 1 Pa to 105 Pa [0.03%]
一种测量缓慢降解化合物蒸汽压的装置(范围在1帕到10^5帕)
Robert F Berg
Robert F Berg
This article describes an apparatus and method for measuring vapor pressures in the range from 1 Pa to 105 Pa. Its three distinctive elements are : (1) the static pressure measurements were made with only a small temperature difference betw...
Investigation of Changes in Tetracycline Repressor Binding upon Mutations in the Tetracycline Operator [0.03%]
四环素操作子突变对四环素阻遏蛋白结合的影响研究
Dan S Bolintineanu,Katherine Volzing,Victor Vivcharuk et al.
Dan S Bolintineanu et al.
The tetracycline operon is an important gene network component, commonly used in synthetic biology applications because of its switch-like character. At the heart of this system is the highly specific interaction of the tet repressor protei...