Clyde W Cady,Robert H Crabtree,Gary W Brudvig
Clyde W Cady
In the last ten years, a number of advances have been made in the study of the oxygen-evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the natural system has come rapid advance in chemical models of this...
Matthew Jurow,Amanda E Schuckman,James D Batteas et al.
Matthew Jurow et al.
The proposal that molecules can perform electronic functions in devices such as diodes, rectifiers, wires, capacitors, or serve as functional materials for electronic or magnetic memory, has stimulated intense research across physics, chemi...
Stephen Ragsdale
Stephen Ragsdale
Charles G Riordan
Charles G Riordan
This review traces the development and application of the tris(thioether)borate ligands, tripodal ligands with highly polarizable thioether donors. Areas of emphasis include the basic coordination chemistry of the mid-to-late first row tran...
Amanda L Eckermann,Daniel J Feld,Justine A Shaw et al.
Amanda L Eckermann et al.
Redox-active self-assembled monolayers (SAMs) provide an excellent platform for investigating electron transfer kinetics. Using a well-defined bridge, a redox center can be positioned at a fixed distance from the electrode and electron tran...
Matthew R Hartings,Igor V Kurnikov,Alexander R Dunn et al.
Matthew R Hartings et al.
We report a quantitative theoretical analysis of long-range electron transfer through sensitizer wires bound in the active-site channel of cytochrome P450cam. Each sensitizer wire consists of a substrate group with high binding affinity for...
The tumor proteasome as a novel target for gold(III) complexes: implications for breast cancer therapy [0.03%]
金(III)复合物作为肿瘤蛋白酶体的新靶点及其对乳腺癌治疗的意义
Vesna Milacic,Q Ping Dou
Vesna Milacic
Although cisplatin plays a vital role in the treatment of several types of human cancer, its wide use is limited by the development of drug resistance and associated toxic side effects. Gold and gold complexes have been used to treat a wide...
Steven T Diver
Steven T Diver
This review provides an overview of ruthenium vinyl carbene reactivity as it relates to enyne metathesis. Methods for the synthesis of metathesis-active and metathesis-inactive complexes are also summarized. Some of the early hypotheses abo...
High Symmetry Dirhodium(II) Paddlewheel Complexes as Chiral Catalysts [0.03%]
手性催化剂的高对称性二 rhodium(II) 机构数据轮配合物
Jørn Hansen,Huw M L Davies
Jørn Hansen
The design and use of chiral dirhodium(II) paddlewheel complexes as catalysts for asymmetric metal carbenoid and metal nitrenoid reactions, and as Lewis acids have become areas of considerable interest during the past two decades. The metal...
Jyotishman Dasgupta,Gennady M Ananyev,G Charles Dismukes
Jyotishman Dasgupta
The light-driven steps in the biogenesis and repair of the inorganic core comprising the O(2)-evolving center of oxygenic photosynthesis (photosystem II water-oxidation complex, PSII-WOC) are reviewed. These steps, known collectively as pho...