Quantum Dot Surface Engineering: Toward Inert Fluorophores with Compact Size and Bright, Stable Emission [0.03%]
量子点表面改性：向着惰性荧光团与紧凑尺寸和明亮、稳定发射迈进
Sung Jun Lim,Liang Ma,André Schleife et al.
Sung Jun Lim et al.
The surfaces of colloidal nanocrystals are complex interfaces between solid crystals, coordinating ligands, and liquid solutions. For fluorescent quantum dots, the properties of the surface vastly influence the efficiency of light emission,...
Elisa Bellomo,Kshetrimayum Birla Singh,Alberto Massarotti et al.
Elisa Bellomo et al.
A new paradigm in metallobiochemistry describes the activation of inactive metalloenzymes by metal ion removal. Protein tyrosine phosphatases (PTPs) do not seem to require a metal ion for enzymatic activity. However, both metal cations and ...
Lijuan Li,Linlin Li
Lijuan Li
The coordination chemistry of metal nitrosyls has expanded rapidly in the past decades due to major advances of nitric oxide and its metal compounds in biology. This review article highlights advances made in the area of multinuclear metal ...
Debashree Basudhar,Lisa A Ridnour,Robert Cheng et al.
Debashree Basudhar et al.
Small redox active molecules such as reactive nitrogen and oxygen species and hydrogen sulfide have emerged as important biological mediators that are involved in various physiological and pathophysiological processes. Advancement in unders...
Recent Developments in Hydrogen Evolving Molecular Cobalt(II)-Polypyridyl Catalysts [0.03%]
分子钴(II)(polypyridyl)催化氢化物的最新研究进展
N Queyriaux,R T Jane,J Massin et al.
N Queyriaux et al.
The search for efficient noble metal-free hydrogen-evolving catalysts is the subject of intense research activity. A new family of molecular cobalt(II)-polypyridyl catalysts has recently emerged. These catalysts prove more robust under redu...
The use of polyoxometalates in protein crystallography - An attempt to widen a well-known bottleneck [0.03%]
多金属氧酸盐在蛋白质晶体学中的应用-一种尝试拓宽一个众所周知的瓶颈问题的方法
Aleksandar Bijelic,Annette Rompel
Aleksandar Bijelic
Polyoxometalates (POMs) are discrete polynuclear metal-oxo anions with a fascinating variety of structures and unique chemical and physical properties. Their application in various fields is well covered in the literature, however little in...
Control and utilization of ruthenium and rhodium metal complex excited states for photoactivated cancer therapy [0.03%]
基于金属钌和铑配合物的激发态调控及其光活化抗肿瘤研究
Jessica D Knoll,Claudia Turro
Jessica D Knoll
The use of visible light to produce highly selective and potent drugs through photodynamic therapy (PDT) holds much potential in the treatment of cancer. PDT agents can be designed to follow an O2-dependent mechanism by producing highly rea...
Karin J Young,Lauren A Martini,Rebecca L Milot et al.
Karin J Young et al.
Light-driven water oxidation is an essential step for conversion of sunlight into storable chemical fuels. Fujishima and Honda reported the first example of photoelectrochemical water oxidation in 1972. In their system, TiO2 was irradiated ...
Marvin W Makinen,Marzieh Salehitazangi
Marvin W Makinen
Much emphasis has been given to vanadium compounds as potential therapeutic reagents for the treatment of diabetes mellitus. Thus far, no vanadium compound has proven efficacious for long-term treatment of this disease in humans. Therefore,...
The coordination chemistry and magnetism of some 3d-4f and 4f amino-polyalcohol compounds [0.03%]
一些3d-4f和4f氨基多元醇化合物的配位化学与磁性研究
Joseph W Sharples,David Collison
Joseph W Sharples
Triethanolamine, teaH3, and diethanolamine, RdeaH2, 3d-4f and 4f compounds demonstrate an enormous variety in their structure and bonding. This review examines the synthetic strategies to these molecules and their magnetic properties, whils...