Stefan P Schmid,Kjell Jorner
Stefan P Schmid
General reaction conditions are a long-standing goal in chemical synthesis, as such conditions facilitate library synthesis and a broad substrate scope. However, despite their importance, the generality of reaction conditions is mostly an a...
Vladislav Slama,Ursula Rothlisberger
Vladislav Slama
Paracyclophanes (PCPs) offer tunable electronic and optical properties through through-space interactions, yet their excited states, especially charge-transfer (CT) states, are difficult to model accurately. We present a computational frame...
Tristan Michael Cofer,Pierre Mateo,Christelle Aurélie Maud Robert
Tristan Michael Cofer
Glycosylation is a widespread modification of plant specialized metabolites (PSMs), yet O-linked oligosaccharide chain formation remains poorly explored. Beyond mono-glycosylation, a subset of PSMs occurs as di-, tri-, or higher oligosaccha...
Histidine-derived N-heterocyclic Carbenes in Metal Peptide Conjugates for Abiotic Catalysis [0.03%]
组蛋白来源的N-杂环卡宾金属肽缀合物非生物催化中的作用
Francisca Figueiredo,Martin Albrecht
Francisca Figueiredo
Histidinium (Hum), a N,N'-dimethylated variant of histidine, serves as a non-canonical amino acid that provides an N-heterocyclic carbene (NHC) binding site for metal coordination. This amino acid therefore allows for combining peptides and...
Jennifer Kuziola,Eva Hevia
Jennifer Kuziola
Fluoroarenes are important motifs in modern synthesis, yet regioselective C-H functionalization while preserving strong C-F bonds remains a significant challenge. Building on recent studies from our group, here we describe the potential of ...
Mathilde Vincent,Jonathan Hall
Mathilde Vincent
Proteolysis-targeting chimeras (PROTACs) are an emerging therapeutic modality that enable the degradation of target proteins via the endogenous ubiquitin-proteasome pathway. We are applying this concept to the degradation of RNA-binding pro...
Owen Kanisius,Michel Rickhaus
Owen Kanisius
Porphyrinoids are a well-established class of molecules, with research ranging from biological applications to light-harvesting nanorings and qubits. Recently, curved variants have received increased attention. Bending them out of planarity...
Luis E Llanes-Montesino,Gonzalo Angulo,Jiangtao Zhao et al.
Luis E Llanes-Montesino et al.
We report striking photophysical behaviour of Au25(PET)18 (PET = 2-phenylethanethiol) nanoclusters in both anionic and neutral forms. Using broad spectral coverage and tuneable excitation, steady-state, and time-resolved measurements reveal...
Trialkylsulfonium Ligands for the Robust Surface Passivation of Lead Halide Perovskite Nanocrystals [0.03%]
用于铅卤钙钛矿纳米晶的坚固表面钝化的三烷基锍配体
Oleksandr Kolomiiets,Maryna Bodnarchuk,Maksym Kovalenko
Oleksandr Kolomiiets
This study introduces a structurally diverse library of long-chain trialkylsulfonium ligands designed to provide surface stabilization of lead halide perovskite nanocrystals (LHP NCs). We evaluate the influence of ligand structure on bindin...
Beyond the Chemical Recycling of Polymethacrylates: Depolymerization of Polymethacrylamides [0.03%]
甲基丙烯酸盐化学循环之外：甲基丙烯酰胺的解聚
Victoria Lohmann,Athina Anastasaki
Victoria Lohmann
Over the past years, depolymerization has become a focal point of polymer research aiming at improving chemical recycling of various polymer classes. Herein, we present the purely thermal depolymerization of polymethacrylamides made by reve...