Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts [0.03%]
吩噻嗪、二氢吩嗪和菲氧嗪：贵金属光氧化还原催化剂的可持续替代品
Daniel A Corbin,Chern-Hooi Lim,Garret M Miyake
Daniel A Corbin
The application of photoredox catalysis to atom-transfer radical polymerization (ATRP) has resulted in the development of strongly reducing organic photoredox catalysts (PCs) that are some of the most reducing catalysts known. The objective...
Sameera Senaweera,Jimmie D Weaver
Sameera Senaweera
Functionalized polyfluorinated aromatics have become an important group of molecules for pharmaceutical and industrial applications. However, facile access to such valuable molecules remains an unmet challenge. In this review, we present an...
Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations [0.03%]
亲双烯体手性磷配体：不对称环化反应中的高效和多功能催化剂
Yumei Xiao,Hongchao Guo,Ohyun Kwon
Yumei Xiao
Recent advances in chiral-phosphine-catalyzed asymmetric annulation reactions; including annulations of allenes, alkynes, Morita-Baylis-Hillman (MBH) carbonates, and ketenes; and their applications in the synthesis of bioactive molecules an...
Brian W Michel,Matthew S Sigman
Brian W Michel
Catalytic C-C Bond Formation and the Hendricksonian Ideal: Atom- and Redox-Economy, Stereo- and Site-Selectivity [0.03%]
催化C-C键形成与亨德里克森理想：原子经济、氧化还原经济、立体选择性及位点选择性
Inji Shin,T Patrick Montgomery,Michael J Krische
Inji Shin
Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered Rings [0.03%]
铜、银和金催化的迁移环异构化反应形成含杂原子的五元环化合物
Alexander S Dudnik,Natalia Chernyak,Vladimir Gevorgyan
Alexander S Dudnik
Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity [0.03%]
不对称N-杂环卡宾(NHC)催化酰基阴离子反应活性研究
Harit U Vora,Tomislav Rovis
Harit U Vora
"Designer"-Surfactant-Enabled Cross-Couplings in Water at Room Temperature [0.03%]
室温下水介质中“定制表面活性剂”促进的交叉偶联反应
Bruce H Lipshutz,Subir Ghorai
Bruce H Lipshutz
New methodologies are discussed that allow for several commonly used transition-metal-catalyzed coupling reactions to be conducted within aqueous micellar nanoparticles at ambient temperatures. ...
Iterative Cross-Couplng with MIDA Boronates: Towards a General Platform for Small Molecule Synthesis [0.03%]
迭代交叉偶联MIDA硼酸酯：用于小分子合成的通用平台构想
Eric P Gillis,Martin D Burke
Eric P Gillis
Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and Imines [0.03%]
基于催化氢化和转移氢化的C-C键形成反应：卡宾基化合物和亚胺的烯丙化、烯基化及烯醇负离子加成反应
Ryan L Patman,John F Bower,In Su Kim et al.
Ryan L Patman et al.