Proposal of a reaction mechanism for the thermal carbonation of ethylene oxide by CO2 in ionic liquids [0.03%]
José Muñoz-Espinoza,Carlos Cárdenas,Renato Contreras
José Muñoz-Espinoza
We revisit a possible mechanism for the thermal conversion of the title reaction, which appears to be driven by solvent effects by the ionic liquid (IL) dihydroxyethyldiethyl ammonium bromide Net2HE2Br. The effect of the solvent is discusse...
Revealing the relationship between Cu valence and product selectivity in CO2 electrolysis [0.03%]
揭示CO2电解中Cu价态与产物选择性之间的关系
Jinghao Lu,Lili Yang,Chuanhui Zhang et al.
Jinghao Lu et al.
Realizing the evolution of Cu valence state in the electrocatalytic CO2 reduction reaction (eCO2RR) is crucial to maintain active sites, optimize reaction conditions and product selectivity and understand reaction mechanism and kinetics.
Gas-phase Curtius and Wolff rearrangement reactions investigated by tandem-MS, IR ion spectroscopy and theory [0.03%]
串联质谱、红外光离子和理论计算研究气相的卡廷和沃尔夫重排反应
Wacharee Harnying,Hui-Chung Wen,Jonathan Martens et al.
Wacharee Harnying et al.
We show that this is fully consistent with the reaction mechanism predicted by quantum-chemical calculations. All IRIS data interpretation rests on computed linear IR spectra of ion structures identified by computational analysis based on DFT calculations with CCSD(T)-F12b energies.
A Laser Synthesis Strategy to Boost Oxygen Evolution Kinetics on Stainless Steel-Based Catalyst via Dual-Metal Segmentally Coordinated Reaction Centers for Efficient Alkaline Water Splitting [0.03%]
通过双金属分段配位反应中心策略促进不锈钢基催化剂析氧反应动力学的激光合成策略用于高效碱性水分解
Jiayi Xu,Rui Pan,Haotian Li et al.
Jiayi Xu et al.
First-principles calculations also reveal that the reaction mechanism of the as-prepared catalyst is affiliated with the oxide path mechanism dominated by the exposed (220) crystal facet, and dual-metal segmentally coordinated reaction centers effectively reduce the oxygen evolution energy barriers,
Catalytic Activation of Acceptor-Acceptor Bicyclobutanes Enabled by Lewis Base Catalysis [0.03%]
路易斯碱催化的接受体-接受体环丁烷的催化活化
Jin-Lan Zhou,Xuan Zhan,Heng-Xian He et al.
Jin-Lan Zhou et al.
The reaction mechanism and the origins of the chemoselectivity were investigated by means of density functional theory calculations.
Xylopyranose Ring-Opening by Single and Double Proton Transfers Under Pyrolysis Conditions [0.03%]
热解条件下(xylo)吡喃糖环的单质子和双质子转移开环反应
Jacopo Lupi,Bernardo Ballotta,Leandro Ayarde-Henríquez et al.
Jacopo Lupi et al.
Keywords: automated reaction mechanism discovery; gas‐phase thermochemistry; hemicellulose; multi‐path canonical variational transition state theory (MP‐VTST); multi‐structural torsional method (MS‐T). © 2025 The Author(s).
Maillard Reaction: Mechanism, Influencing Parameters, Advantages, Disadvantages, and Food Industrial Applications: A Review [0.03%]
美拉德反应的研究进展：机制、影响因素、优缺点及在食品工业中的应用
Leina El Hosry,Vanessa Elias,Vanessa Chamoun et al.
Leina El Hosry et al.
The Maillard reaction is a complex chemical reaction that occurs between nucleophilic groups, such as thiolates or amino groups primarily from amino acids, peptides, proteins, and carbonyl groups, particularly from reducing sugars. The pH v...
The Mechanism of Boron-Carbon Bond Formation in the DA Reaction of the Pyridine Adduct of Borabenzene with Acetylene: A Topological Analysis of the ELF Function and Catastrophe Theory [0.03%]
硼碳成键过程的拓扑分析：用于苯基硼倍半碳环吡啶配合物与乙炔进行亲电加成反应的ELF理论和突变理论研究
Slawomir Berski
Slawomir Berski
A possible qualitative influence on the overall picture of the reaction mechanism is suggested by the results obtained using the CAM-B3LYP and B2PLYP functionals, particularly in phases VI and VII.
Cobalt Doping of Na2VTi(PO4)3 Enables a High-Energy NASICON-Type Cathode Material for Sodium-Ion Batteries [0.03%]
钴掺杂的Na2VTi(PO4)3使NASICON型钠离子电池正极材料具有高能量特性
Yu Zhang,Mengyao Wang,Hao Fan et al.
Yu Zhang et al.
In situ X-ray diffraction discloses a solid solution reaction mechanism for NCTVP, while the galvanostatic intermittent titration technique demonstrates fast Na+ diffusion kinetics. NCTVP also demonstrates high capacity and good cyclability in full cells.
One-Pot Regioselective Functionalization of Quinone Imine Ketals: Direct Access to ortho-Substituted Anilines from Arylamines [0.03%]
一锅式喹啉亚胺酮的选择性官能团化：从芳胺直接制备间位氨基苯甲醛肟 Schiff 碱
Naveen Yadav,Rina Mahato,Smritikana Pal et al.
Naveen Yadav et al.
The control experiments provide insight into the reaction mechanism and the origin of ortho-selectivity.
耗时 0.19706 秒，为您在
48229835
条记录里面共找到 10000 篇文章 [XML]