Radical approaches for C(sp3)-N bond cleavage in deaminative transformations [0.03%]
去胺转化中断裂C(sp3)−N键的全新方法学研究进展
Je Uk Kim,Eun Song Lim,Ji Yeon Park et al.
Je Uk Kim et al.
Amines are versatile and widely available functional groups that serve as key building blocks in organic synthesis, particularly in pharmaceutical development. The deaminative functionalization of amines, where the C-N bond of amine is clea...
Long-term Oncological Outcomes of Partial Gland Cryoablation of Localized Prostate Cancer with Median Follow-up of 7 Years: A Single-institution Experience [0.03%]
中位数随访7年的前列腺癌部分腺体冷冻消融长期肿瘤学结局：单中心经验
Sriram Deivasigamani,Srinath Kotamarti,Mahdi Mottaghi et al.
Sriram Deivasigamani et al.
Background and objective: Traditional radical approaches to treat clinically localized prostate cancer (PCa) have largely been effective oncologically, but associated with complications and decline in functional outcomes, arguably making them unsuitable in all cases for treatment.
Challenges in the Management of Pediatric Pancreatic Hydatid Disease: A Systematic Review of the Literature and Our Clinical Experience [0.03%]
儿囊虫病的管理挑战：文献系统综述和临床经验
Suresh Kumar Thanneeru,K Priyesh Sankar,Pramod K Sharma et al.
Suresh Kumar Thanneeru et al.
Both the conservative surgical (92.86%) and radical approaches (7.14%) have been described with favorable results (85.71%). One patient managed with the conservative surgical approach developed a pancreatic leak. No recurrence was reported. PHD in children is rare....Both conservative and radical approaches can be effective, but caution is needed for potential pancreatic leaks after the conservative approach due to ductal communication.
Gokul R Krishnan,Syam Vikram,Deepak Damodaran et al.
Gokul R Krishnan et al.
The landscape of breast cancer surgery has journeyed a well-trodden path, transitioning from radical approaches to conservatism and ultimately finding a balance in rationalized radical conservatism. This evolution signifies a significant paradigm shift in breast cancer management.
Revisiting the Mechanistic Pathway of Gas-Phase Reactions in InN MOVPE Through DFT Calculations [0.03%]
通过DFT计算重新审视InN金属有机蒸汽相沉积气体反应的机理路径
Xiaokun He,Nan Xu,Yuan Xue et al.
Xiaokun He et al.
When the H radical approaches MMInNH2, MMIn:NH3 rather than MMInHNH2 will generate and this is followed by the elimination of CH4 via two parallel paths. Considering the abundance of H2 in the environment, this work also examines the reactions between H2 and XMIn.
Asymmetric Functionalization Harnessing Radical-Mediated Functional-Group Migration [0.03%]
利用自由基介导的官能团迁移的非对称化反应
Fushan Chen,Zhu Cao,Chen Zhu
Fushan Chen
A wide diversity of radical approaches harnessing functional-group migration (FGM) have been devised to enhance both synthetic efficiency and molecular complexity.
Catalytic asymmetric photocycloaddition reactions mediated by enantioselective radical approaches [0.03%]
手性催化剂介导的对映选择性自由基加成反应在光环加成中的应用
Yanli Yin,Mengdi You,Xiangtao Li et al.
Yanli Yin et al.
The use of olefins in the construction of cyclic compounds represents a powerful strategy for advancing the pharmaceutical industry. Photocycloaddition has attracted significant interest from chemists due to its ability to exploit simple an...
The experiences of cardiovascular surgeons and nurses with mutual support through interprofessional collaboration in the intensive care unit [0.03%]
心血管外科医师和护士通过多学科协作相互支持在重症监护病房中的体验
Hümeyra Dener,Melih Elçin
Hümeyra Dener
Background: The World Health Organization (WHO) emphasizes the need for radical approaches in its Global Patient Safety Action Plan, particularly in terms of interprofessional and multidisciplinary approaches.
Camila Sotomayor,Natalia Reyes,Eduardo Briceño et al.
Camila Sotomayor et al.
Conservative techniques, including capitonnage, partial cystectomy, puncture, and aspiration, have been described, while radical approaches such as pericystectomy and liver resection demonstrate superior management of the residual cavity and reduced recurrence rates.
Case Reports
Cureus. 2024 Oct 17;16(10):e71674. DOI:10.7759/cureus.71674 2024
[Safety-driven radical approaches in routine thyroid surgery: roles and challenges] [0.03%]
[以安全为主导的常规甲状腺手术中微切口与经口甲状腺手术的作用及挑战]
Zoltán Farsang,Róbert Jaskó,Erzsébet Révész et al.
Zoltán Farsang et al.
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