Piercing Molecular Graphenes: Precision Synthesis and Photophysics of NBN-Edged Porous Molecular Carbons [0.03%]
穿孔分子石墨烯：NBN边缘多孔分子碳的精准合成与光物理性质研究
Yang Yu,Asier Izu,José M Marín Beloqui et al.
Yang Yu et al.
Bottom-up solution-phase synthesis of atomically precise porous nanographenes is a challenging endeavor. In particular, molecular carbons with multiple pores and heteroatoms remain unknown. Herein, we report three porous molecular carbons (...
Surface-Controlled TiO2 Nanocrystals with Catalytically Active Single-Site Co Incorporation for the Oxygen Evolution Reaction [0.03%]
表面控制的TiO2纳米晶体用于单原子位点Co掺杂以催化析氧反应
Chang Liu,Soonho Kwon,Perrin Godbold et al.
Chang Liu et al.
This study highlights the synergy between theoretical calculations and precision synthesis in the development of more effective catalysts.
Single Nanoparticle Collision Electrocatalysis Driven by Ultrafast High-Temperature Precision Synthesis [0.03%]
基于超快高温精密合成的单纳米粒子碰撞电催化
Lixia Yang,Yuanhua Tu,Xiangyi Shan et al.
Lixia Yang et al.
Here, using PtxRu1-x alloys as a model system, we propose an innovative strategy that combines ultrafast high-temperature precision synthesis with ultrasonic exfoliation....This study, for the first time, integrates ultrafast precision synthesis with single NP electrocatalysis, providing a new framework for the development of highly efficient catalysts.
Precision Synthesis of a Single Chain Polymorph of a 2D Solid within Single-Walled Carbon Nanotubes [0.03%]
单壁碳纳米管中二维固体单链多晶材料的精准合成
Griffin M Milligan,Sirisak Singsen,Sydney To et al.
Griffin M Milligan et al.
The discovery and synthesis of atomically precise low-dimensional inorganic materials have led to numerous unusual structural motifs and nascent physical properties. However, access to low-dimensional van der Waals (vdW)-bound analogs of bu...
Machine learning accelerated analysis of microwave-assisted synthesis parameters on calcium carbonate particles [0.03%]
机器学习加速微波辅助合成参数对碳酸钙粒子的影响分析
Junnan Song,Jorge García-Balduz,Tangyu Yang et al.
Junnan Song et al.
However, precision synthesis is challenging due to bulk crystallization effects, which makes it difficult to predict the outcomes of chemical synthesis.
Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization [0.03%]
超分子聚合中分层有序介观结构的二级成核策略研究
Sougata Datta,Hiroki Itabashi,Takuho Saito et al.
Sougata Datta et al.
Here we illustrate how secondary nucleation can be combined with the well-established precision synthesis of supramolecular polymers to realize precise control over hierarchical structures in the mesoscopic regime.
Directed synthesis of N1/N3-histidine modified by 2-hydroxyethylthioethyl and identification in sulfur mustard-exposed plasma [0.03%]
N1/N3组氨酸被2-羟乙基硫乙基修饰的定向合成及二氯硫酸酯暴露血浆中的鉴定
Long Wen,Zhibin Shu,Li Pan et al.
Long Wen et al.
This work not only establishes a precision synthesis platform for biomarkers but also elucidates HFIP's unique role in imidazole regioselectivity, offering insights for medicinal chemistry and HD toxicology.
Optimization of the Surfactant Ratio in the Formation of Penta-Twinned Seeds for Precision Synthesis of Gold Nanobipyramids with Tunable Plasmon Resonances [0.03%]
用于可调表面等离振子共振的金纳米双锥精确合成的五联晶种形成的表面活性剂比例优化
Au Lac Nguyen,Quinn J Griffin,Ankai Wang et al.
Au Lac Nguyen et al.
The synthesis of high-purity gold nano bipyramids (Au NBPs) with a narrow size distribution and tunable plasmon resonances is of great significance for plasmon resonance-related applications. However, the synthesis Au NBP approach involves ...
Expediting Glycospace Exploration: Therapeutic Glycans via Automated Synthesis [0.03%]
加速糖空间探索：通过自动化合成实现治疗性糖链
Ryan Gilmour,James Suri
Ryan Gilmour
This rapidly expanding, multifaceted field of scientific endeavor has effectively merged synthetic chemistry with technology and engineering to expedite the precision synthesis of target glycans.
Assembly of Diverse Allenes via Activator-Free Palladium-Catalyzed Regioselective γ-Arylation of Propargylamines with Boronic Acids [0.03%]
无需活化剂的钯催化丙炔胺与硼酸的选择性γ-芳基化串联反应及多样的烯丙烯衍生物的合成
Yan Sun,Ya Pan,Tao Zhao et al.
Yan Sun et al.
Controlling the reaction selectivity to achieve a precision synthesis is a constant concern for chemists. Here, we report a palladium-catalyzed deaminative coupling of propargylamines with arylboronic acids to generate allene skeletons.
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