Synthesis, characterization and reactivity of a series of alkaline earth and rare earth iminophosphoranomethanide complexes [0.03%]
一系列碱土和稀土iminophosphoranomethanide配合物的合成、表征及反应性研究
Matthew P Stevens,Yu Liu,Elias Alexopoulos et al.
Matthew P Stevens et al.
Here we report the use of the methanide ligand {CH(SiMe3)P(Ph)2 = NSiMe3}- (NPC-H) in the stabilization of alkaline earth and rare earth organometallics and their potential use as synthetic precursors.
Base-Stabilized Gallium Sulfides and Selenides Supported by a Bis(oxazolinyl)(phenyl)methanide Ligand [0.03%]
由双噁唑烷甲烷负离子配体支撑的镓硫族化合物及稳定基底
Tao Ding,Ryo Nakano,Makoto Yamashita
Tao Ding
Gallylene supported by a bis(oxazolinyl)(phenyl)methanide (Boxm) ligand was synthesized and structurally characterized. The reaction of this gallylene with triphenylphosphine sulfide/selenide yielded dimeric gallium sulfide and selenide. Th...
Bi- and tridentate coordination behaviour of a novel bis(phosphinimino)methanide ligand [0.03%]
新型双(膦叶立德)甲烷化配体的二齿和三齿配位行为研究
Bastian B Burgert,Xiaofei Sun,Adrian Hauser et al.
Bastian B Burgert et al.
Herein, we report the synthesis of a novel ferrocenyl-functionalized bis(phosphinimino)methane ligand (CH2 (PPh2 NFc)2 ). Deprotonation of CH2 (PPh2 NFc)2 with KN(SiMe3 )2 gave the dimeric species [K{CH(PPh2 NFc)2 }]2 , which was further re...
Base-Stabilized Neutral Oxoborane and Thioxoborane Supported by a Bis(oxazolinyl)(phenyl)methanide Ligand [0.03%]
由双(氧唑啉基)(苯基)甲烷负离子配体支持的碱性氧化硼和硫氧化硼基础稳定化研究
Ryo Nakano,Ryotaro Yamanashi,Makoto Yamashita
Ryo Nakano
Base-stabilized neutral oxoborane and thioxoborane supported by a bis(oxazolinyl)(phenyl)methanide ligand have been synthesized and structurally characterized. While previous synthetic attempts of oxoborane ligated by β-diketiminate (NacNa...
Group 13 Heavier Carbene Analogues Stabilized by the Bulky Bis(4-benzhydryl-benzoxazol-2-yl)methanide Ligand [0.03%]
一组13 heavier碳烯类似物由庞大的双（4-茋基-苯并恶唑-2-基）甲烷𬭩配体稳定
Johannes Kretsch,Anne Kreyenschmidt,Timo Schillmöller et al.
Johannes Kretsch et al.
On the basis of the bulky bis(4-benzhydryl-benzoxazyl-2-yl)methane ligand (4-BzhH2Box2CH2), neutral monovalent group 13 complexes [M13(4-BzhH2Box2CH)] [M13 = Tl (1), In (2), or Ga (3)] have been synthesized by salt metathesis reaction of th...
Mixed Low-Valent Alanes from the Bis(4-methyl-benzoxazol-2-yl)methanide Ligand [0.03%]
来自双(4-甲基苯并噁唑-2-基)甲烷ide配体的混合低价铝化合物
Johannes Kretsch,Anne Kreyenschmidt,Timo Schillmöller et al.
Johannes Kretsch et al.
Within this work, an aluminum dihydride complex ([(4-MeBox2CH)AlH2]) (1) based on the bis(4-methyl-benzoxazol-2-yl)methanide ligand was synthesized and characterized by spectroscopic methods (NMR, ATR-IR, and fluorescence), DSC (differentia...
PNacPNacE: (E = Ga, In, Tl) - monomeric group 13 metal(i) heterocycles stabilized by a sterically demanding bis(iminophosphoranyl)methanide [0.03%]
由空间位阻型双[(膦杂)亚氨基]甲烷锂稳定的单核含金属正离子的13族金属环杂环化合物(PNacPNacE: E = Ga, In, Tl)
Christian P Sindlinger,Samuel R Lawrence,Shravan Acharya et al.
Christian P Sindlinger et al.
DFT studies on LE:, E = Al-Tl, were carried out and support the formulation as an anionic, N,N'-chelating methanide ligand coordinating to group 13 metal(i) cations. The HOMOs of the molecules for E = Al-In show a dominant contribution from a metal-based lone pair that is high in s-character.
Group 13 metal complexes containing the bis-(4-methylbenzoxazol-2-yl)-methanide ligand [0.03%]
含双(4-甲基苯并恶唑-2-基)甲烷𬭩配体的第13族金属配合物
David-R Dauer,Melchior Flügge,Regine Herbst-Irmer et al.
David-R Dauer et al.
To focus on the high importance of low-valent main group metal complexes, which can be applied to catalytic transformations, this article deals with the promising new ligand system (4-MeNCOC6H3)2CH2 (1). It is patterned on the well known na...
Multifunctional behavior by a Bis-(phosphinimino)methanide ligand: eta 2- vs eta 3-coordination vs Bronsted basicity [0.03%]
双(亚磷亚胺甲烷)负离子配体的多功能行为：η2与η3配位和路易斯碱性之间的转换
Christine Bibal,Maren Pink,Yegor D Smurnyy et al.
Christine Bibal et al.
The reaction of [(Cymene)RuCl2]2 with the chelate LiHC(PPh2NPh)2 occurs to remove both chloride ligands, to furnish a cationic Ru(II) complex with the monoanionic ligand bound eta3, through two N and an sp3 carbon. This cation is also produ...
Unprecedented co-ordination of the methanide ligand in [Ag2(PPh3)2(SPPh2CHPPh2CHCO2Me)]ClO4�4CH2Cl2 [0.03%]
Gimeno, Maria Concepci�n; Jones, Peter G.; Laguna et al.
Gimeno et al.