Highly Efficient Suzuki-Miyaura Polymerization Enabled by Direct Transmetalation with Boronic Esters [0.03%]
直接利用硼酸酯进行转金属化催化的高效Suzuki-Miyaura聚合反应
Haigen Xiong,Yu Lu,Qijie Lin et al.
Haigen Xiong et al.
The Suzuki-Miyaura cross-coupling reaction plays a pivotal role in the construction of carbon-carbon bonds, utilizing low-toxicity and readily available organoboron substrates. However, competitive protodeboronation of arylboronic acids has...
Publisher Correction: General room-temperature Suzuki-Miyaura polymerization for organic electronics [0.03%]
出版更正：通用室温Suzuki-Miyaura聚合用于有机电子器件
Haigen Xiong,Qijie Lin,Yu Lu et al.
Haigen Xiong et al.
Published Erratum
Nature materials. 2024 Mar;23(3):439. DOI:10.1038/s41563-024-01824-0 2024
General room-temperature Suzuki-Miyaura polymerization for organic electronics [0.03%]
通用的室温Suzuki-Miyaura聚合反应在有机电子学中的应用
Haigen Xiong,Qijie Lin,Yu Lu et al.
Haigen Xiong et al.
π-Conjugated polymers (CPs) have broad applications in high-performance optoelectronics, energy storage, sensors and biomedicine. However, developing green and efficient methods to precisely synthesize alternating CP structures on a large ...
Room Temperature Anhydrous Suzuki-Miyaura Polymerization Enabled by C-S Bond Activation [0.03%]
C-S键活化 enabled 室温无水 Suzuki-Miyaura 聚合反应
Xuan Wen,Wenbin Xie,Yawen Li et al.
Xuan Wen et al.
The Suzuki-Miyaura cross-coupling is one of the most important and powerful methods for constructing C-C bonds. However, the protodeboronation of arylboronic acids hinder the development of Suzuki-Miyaura coupling in the precise synthesis o...
Efficient Bottom-Up Preparation of Graphene Nanoribbons by Mild Suzuki-Miyaura Polymerization of Simple Triaryl Monomers [0.03%]
通过简单的三芳基单体的温和铃木- Miyaura缩聚法高效自下而上制备石墨烯纳米带
Gang Li,Ki-Young Yoon,Xinjue Zhong et al.
Gang Li et al.
Herein an efficient bottom-up solution-phase synthesis of N=9 armchair graphene nanoribbons (GNRs) is described. Catalyzed by Pd(PtBu3 )2 , Suzuki-Miyaura polymerization of a simple and readily available triaryl monomer provides a novel GNR...