Synthesis of Secondary Boronates via Deaminative Cross-Coupling of Alkyl Nitroso Carbamates and Boronic Acids [0.03%]
亚硝基碳酰胺与硼酸的去氨交叉偶联反应合成二级硼酸酯
Shashwati Paul,M Kevin Brown
Shashwati Paul
A strategy for transition metal-free cross-coupling of alkyl nitroso-carbamates and boronic acids is reported. The N-nitroso carbamates are easily prepared from the corresponding amine in two simple steps. This method allows for the synthes...
Daniele Leonori,Varinder K Aggarwal
Daniele Leonori
This Minireview highlights advances in the Suzuki-Miyaura cross-coupling of secondary boron reagents for the creation of C-C bonds with control of stereochemistry. It also includes non-transition-metal coupling of secondary and tertiary bor...