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An Axially Chiral Pyridyno-allenophane in a 2:1 Edge-to-Face Silver(I) Sandwich Complex: Synthesis and Structural Characterization

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We synthesized and characterized silver-(I) complexes featuring chiral pyridyno-allenophanesa class of cyclophanes integrating pyridine, alkyne, and allene units within a macrocyclic framework. X-ray diffraction revealed a 1:1 (ligand:metal) complex stabiliz... ...