Regioisomeric Control of Chemiexcitation Efficiency in Lophine Silylperoxides through Reaction-Path Topology and Excited-State Accessibility
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This study investigates the chemiluminescence (CL) of silylperoxides derived from lophines and their associated high-energy intermediates (HEIs), specifically 1,2-dioxetanes. Three regioisomeric silylperoxides (D1-3), differing in the position of the -O- group... ...