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Gallylene-Mediated C-C Bond Activation of Diphenylcyclopropenone and Chalcogen Atom Insertion into a Ga-C Bond

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We report the synthesis and structural characterization of a gallacyclobutenone. The gallacyclobutenone was synthesized via C-C bond oxidative addition of cyclopropenone to a Ga-(I) species bearing a phenalenyl-based bidentate ligand. Density functional theory... ...