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Hydrogen Radicals Enable an Alternative Kinetic Pathway for H2O2 Photosynthesis through Dual Redox Site Regulation of Proton-Coupled Electron Transfer

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Artificial photosynthesis offers a sustainable route for hydrogen peroxide (H2O2) production, yet its efficiency is fundamentally limited by the kinetic decoupling of proton-coupled electron transfer (PCET) during oxygen reduction. Here, we demonstrate that hy... ...